Skip to main content
SpringerLink
Log in

Synthesis and high-pressure behavior of C6N9H3•HCl: A graphitic material with a two-dimensional C-N network

  • Chapter
Frontiers of High Pressure Research II: Application of High Pressure to Low-Dimensional Novel Electronic Materials

Part of the book series: NATO Science Series ((NAII,volume 48))

  • 796 Accesses

Abstract

A novel carbon nitride compound, with storchiometry C6N9H4Cl and structurally related to the proposed graphitic phase of C3N4, has been synthesized at moderate pressures in a bulk well-crystallized form The new material was prepared through the polymerization of melamine based precursors in the presence of a liquid flux between 1.0-2.0 GPa and 500-550 °C m a piston cylinder device. Xray and electron diffraction measurements indicate a hexagonal space group (P63/m) with cell parameters of a = 8.4379(10) Å and c = 6.4296(2) Å. The composition was determined by bulk chemical analysis and confirmed by electron energy loss spectroscopy. Our structure model is consistent with the infrared and 13C NMR spectra. The cell parameters were obtained as a function of pressure to 34 GPa from energy dispersive X-ray diffraction measurements. The compressional behavior of the carbon nitride material is highly amsotropic and similar to that of graphitic carbon

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. M.L Cohen, Phys. Rev. B 32, 7988 (1985).

    Article  CAS  Google Scholar 

  2. A.Y. Liu and R.M Wentzcovitch, Phys. Rev. B 50, 10362 (1994).

    Article  CAS  Google Scholar 

  3. D.M. Teter and R.J. Hernley, Science 271, 53 (1996).

    Article  CAS  Google Scholar 

  4. J. Ortega and O.F. Sankey, Phys. Rev. B 51, 2624 (1995).

    Article  CAS  Google Scholar 

  5. J.E. Lowther, Phys. Rev. B 59, 11683 (1999).

    Article  CAS  Google Scholar 

  6. C. Niu, Y.Z. Lu and C.M. Lieber, Science 261, 334 (1993).

    Article  CAS  Google Scholar 

  7. K.M. Yu, M.I. Cohen, EE Haller, W.L. Hansen, AY. Liu and I.C. Wu, Phys. Rev. B 49, 5034 (1994).

    Article  CAS  Google Scholar 

  8. Z.-M. Ren, Y.-C. Du, Y. Qiu, J.-D. Wu, Z.F. Ying, X-X. Xiong and F.-M. Li, Phys. Rev. B 51, 5274 (1995).

    Article  CAS  Google Scholar 

  9. Z.J. Zhang, S. Fan and C.M. Lieber, Appl. Phys. Lett. 66, 3582 (1995).

    Article  CAS  Google Scholar 

  10. A.K.M.S. Chowduhry, D.C Cameron, M.S.J. Hashmi and J.M. Gregg, J. Mater Res. 14, 2359 (1999).

    Article  Google Scholar 

  11. J. Martin-Gil, F.J. Martin-Gil, M. Sarikaya, M. Qian, M. Jose-Yacaman, and A.J, Rubio, J. Appl. Phys. 81, 2555 (1997).

    Article  CAS  Google Scholar 

  12. D.W. He, F.X. Zhang, X.Y. Zhang, Z. C. Qin, M. Zhang, M., R.P. Liu, Y.F. Xu, W.K. Wang, J. Mater. Res. 13, 3458 (1998).

    Article  CAS  Google Scholar 

  13. J. Wang, J. Lei and R. Wang, Phys. Rev. B 58, 11890 (1998).

    Article  CAS  Google Scholar 

  14. J. Kouvetakis, A. Bandari, M. Todd,, B. Wilkens, and N. Cave, Chera Mater. 6, 811 (1994).

    Google Scholar 

  15. G. Demazeau, H. Montigaud, B. Tanguy, M. Birot and J. Dunogues, Rev. High Pressure Sci. Technol. 7, 1345 (1998).

    Article  CAS  Google Scholar 

  16. I. Alves, G. Demazeau, B. Tanguy and F. Weill, Solid State Commun. 109, 697 (1999).

    Article  CAS  Google Scholar 

  17. Z. Zhang, K. Leinenweber, M. Bauer, L.A.J. Garvie, P.F. McMillan and G.H. Wolf, J. Amer. Chem. Soc. (in press)

    Google Scholar 

  18. A. LeBail, H. Duroy and J.L. Fourquet, Mater. Res. Bull. 23, 447 (1988).

    Article  CAS  Google Scholar 

  19. A.C. Larson and R.B. von Dreele, General Structure Analysis System (1994).

    Google Scholar 

  20. L.A.J. Garvie, A.J. Craven and R. Brydson, Amer. Mineral. 79, 411 (1999).

    Google Scholar 

  21. T. Yagi, W. Utsumi, M. Yamakata, T. Kikegawa, O. Shimomura, Phys. Rev. B 46, 6031 (1992).

    Article  CAS  Google Scholar 

  22. AR. Katritzky and A.P. Ambler, Physical Methods in Heterocyclic Chemistry, Ed., A. R. Katritzky, A R Academic Press, New York and London, Vol. II 161 (1963).

    Google Scholar 

  23. G.C Levy, R.L. Lichter and G.L. Nelson, Carbon-13 Nuclear Resonance Spectroscopy, 2nd Ed, John Wiley and Sons (1980).

    Google Scholar 

  24. C.J. Pouchert, The Aldrich Library of NMR Spectra, 2nd ed., Aldrich Chemical Co., Milwaukee (1983).

    Google Scholar 

  25. Hanbook of Chemistry and Physics, 79th edition, Ed., D. R. Lide, CRC Press, Boca Raton, Florida (1998).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistryand Biochemistry, Arizona State University, Tempe, AZ, 85287, USA

    G. H. Wolf, M. Bauer, K. Leinenweber & Z. Zhang

  2. Materials Research Science and EngineeringCenter, ArizonaState Univ., Tempe, AZ, 85287, USA

    G. H. Wolf, M. Bauer, K. Leinenweber & Z. Zhang

  3. Department of Geological Sciences, Arizona State University, Tempe, AZ, 85287, USA

    L. A. J. Garvie

Authors
  1. G. H. Wolf
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. Bauer
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. K. Leinenweber
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. L. A. J. Garvie
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Z. Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Department of Physics, Colorado State University, Fort Collins, CO, USA

    Hans D. Hochheimer

  2. Institute of Physical and Theoretical Chemistry, Wroclaw University of Technology, Wroclaw, Poland

    Bogdan Kuchta

  3. Department of Chemistry, Colorado State University, Fort Collins, CO, USA

    Peter K. Dorhout

  4. Department of Chemistry, University of Wyoming, Laramie, WY, USA

    Jeffery L. Yarger

Rights and permissions

Reprints and permissions

Copyright information

© 2001 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

Wolf, G.H., Bauer, M., Leinenweber, K., Garvie, L.A.J., Zhang, Z. (2001). Synthesis and high-pressure behavior of C6N9H3•HCl: A graphitic material with a two-dimensional C-N network. In: Hochheimer, H.D., Kuchta, B., Dorhout, P.K., Yarger, J.L. (eds) Frontiers of High Pressure Research II: Application of High Pressure to Low-Dimensional Novel Electronic Materials. NATO Science Series, vol 48. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0520-3_3

Download citation

  • DOI: https://doi.org/10.1007/978-94-010-0520-3_3

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-1-4020-0160-4

  • Online ISBN: 978-94-010-0520-3

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation