Abstract
Electronic phenomena in solids can be correlated to the evolution of different parameter, Dq/B, b, U.
For modifying such parameters, two ways are investigated : (i) the increase of the valence state n+ of the Mn+ transition metal, (ii) the use of high pressures, both leading to a shrinking of the bond. Some examples as spin transition, charge-transfer, insulator→mietal transition and disproportionation phenomenon are described in oxygen lattices.
A discussion between these two -routes is presented on the basis of the variation of the n+ distance.
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Demazeau, G. (2001). Stabilization of Unusual Oxidation States of Transition Metals in Oxygen Lattices: Correlations with the Induced Electronic Phenomena. In: Hochheimer, H.D., Kuchta, B., Dorhout, P.K., Yarger, J.L. (eds) Frontiers of High Pressure Research II: Application of High Pressure to Low-Dimensional Novel Electronic Materials. NATO Science Series, vol 48. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0520-3_1
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