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Liquid-Liquid Phase Equilibria in Binary Mixtures Under Negative Pressure

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Liquids Under Negative Pressure

Part of the book series: NATO Science Series ((NAII,volume 84))

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Abstract

Several binary or multicomponent solutions exhibit liquid-liquid phase transition; i.e. changing the temperature and/or pressure and/or concentration etc., the initially homogeneous liquid can split into two or more liquid phases. In this paper we would like to give examples where the extension of liquid-liquid solubility branches below p=0 gives us new information about the studied binary and quasi-binary mixtures.

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References

  1. Imre, A., Van Hook, W.A. (1998) Liquid-liquid equilibria in polymer solutions at negative pressure, Chem. Soc.Rev., 27, 117–123

    Article  Google Scholar 

  2. Imre, A.R, Melnichenko, G., Van Hook, W.A. and Wolf, B.A. (2001) On the effect of pressure on the phase transition of polymer blends and polymer solutions: Oligostyrene-n-alkane systems, Phys. Chem. Chem. Phys., 3, 1063–1066

    Article  Google Scholar 

  3. Imre, A.R., Van Hook, W.A. and Wolf, B.A. (2002) Liquid-liquid phase equilibria in polymer solutions and polymer mixtures, Macromolecular Symposia, in press

    Google Scholar 

  4. Imre, A.R., Kraska, T. and Yelash, L.V. (2002) The effect of pressure on the liquid-liquid phase equilibrium of two polydisperse polyalkylsiloxane blends, Phys.Chem.Chem. Phys, 4, 992–1001

    Article  Google Scholar 

  5. Timmermans, J. and Lewin, J. (1953) A forgotten theory: the “negative saturation curve” Discuss. Faraday Soc., 15, 195–201

    Article  Google Scholar 

  6. Rebelo, L.P.N., Visak, Z..P. ans Szydlowski, J., this book, next paper

    Google Scholar 

  7. Smeller, L. (2002) Pressure-temperature phase diagrams of biomolecules, Biochim. Biophys. Acta, 1595, 11–29

    Article  Google Scholar 

  8. Machin, W.D. (1998) A simple method for the generation of negative pressure in liquids, Can. J. Chem., 76, 1578–1580

    Google Scholar 

  9. Kim, S.B., Ma, J. and Chan, M.H.W. (1993) Phase diagram of 3He-4He mixture in aerogel, Phys. Rev. Lett., 71, 2268–2271

    Article  ADS  Google Scholar 

  10. Flory, P.J. (1953) Principles of Polymer Chemistry, Cornell University Press, Ithaca.

    Google Scholar 

  11. Wolf, B.A. and Blaum, G. (1976) Pressure Influences on the True Cosolvency — Measured and Calculated Solubility Limits of Polystyrene in Mixtures of Acetone and Diethylether, Makromol. Chem., 177, 1073–1088

    Article  Google Scholar 

  12. Imre, A., Van Hook, W.A. (1994) Polymer-Solvent Demixing Under Tension. Isotope and Pressure Effects on Liquid-Liquid Transitions. VII. Propionitrile-Polystyrene Solutions at Negative Pressure, J. Polym. Sci. B., 32, 2283–2287

    Article  Google Scholar 

  13. Rebelo, L.P.N., Visak, Z.P. and Szydlowski, J. (2002) Metastable critical lines in (acetone+polystyrene) solutions and the continuity of solvent-quality states, Phys. Chem. Chem. Phys., 4, 1046–1052

    Article  Google Scholar 

  14. Hosokawa, H., Nakata, M. and Dobashi, T. (1993) Coexistence curve of polystyrene in methylcyclohexane. VII. Coexistence surface and critical double point of binary system in T-p-space, J. Chem. Phys., 98, 10078–10084

    Article  ADS  Google Scholar 

  15. Wells, P.A., de Loos, Th. W. and Kleintjens, L.A. (1993) Pressure pulsed induced critical scattering: spinodal and binodal curves for the system polystyrene + methylcylcohexane, Fluid Phase Eq., 83, 383–390

    Article  Google Scholar 

  16. Vanhee, S., Kiepen, F., Brinkmann, D., Borchard, W., Koningsweld, R. and Berghmans, H. (1994) The System Methylcyclohexane/Polystyrene. Experimental Critical Curves, Cloud-Point and Spinodal Isopleths, and their Description with a Semi-phenomenological Treatment, Macromol Chem. Phys., 195, 759–780

    Article  Google Scholar 

  17. Imre, A.R., Melnichenko, G. and Van Hook, W.A. (1999) Liquid-liquid equilibria in polystyrene solutions: the general pressure dependence, Phys. Chem. Chem. Phys., 1, 4287–4292

    Article  Google Scholar 

  18. Imre, A.R., Melnichenko, G. and Van Hook, W.A. (1999) A Polymer-Solvent System with Two Homogeneous Double Critical Points: Polystyrene (PS)/(n-heptane+methylcyclohexane), J. Polym. Sci. B., 37, 2747–2753

    Article  Google Scholar 

  19. Rebelo, L.P.N., Visak, Z.P., de Sousa, H.C., Szydlowski, J., de Azevedo, R.G., Ramos, A.M., Najdanovic-Visak, V., da Ponte, M.N. and Klein, J. (2002) Double critical phenomena in (water plus Polyacrylamides) solutions, Macromolecules, 35, 1887–1895

    Article  ADS  Google Scholar 

  20. Rebelo, L.P.N. and Van Hook, W.A.(1993) An unusual phase diagram: the polystyrene/acetone system in its hypercritical region; near tricritical behavior in a pseudo-binary solution, J. Polym. Sci. B., 31, 895–8

    Article  Google Scholar 

  21. Schneider, G. M. (1972) Phase behavior and critical phenomena in fluid mixtures under pressure, Ber. Bunsen Ges., 76, 325–331

    Google Scholar 

  22. Narayanan, T. and Kumar, A. (1994) Reentrant phase transitions in multicomponent liquid mixtures, Phys. Rep., 249, 135–218

    Article  ADS  Google Scholar 

  23. Schneider, G.M. (2002) Aqueous solutions at pressures up to 2 GPa: gas-gas equilibria, closed loops, high-pressure immiscibility, salt effects and related phenomena, Phys. Chem. Chem. Phys., 4, 845–852

    Article  Google Scholar 

  24. Otake, K., Karaki, R., Ebina, T., Yokoyama, C. and Takahashi, S. (1993) Pressure Effects on the Aggregation of PolylN-isopropylacrylamide) and Poly(N-isopropylacrylamide-co-acrylic acid) in Aqueous Solutions, Macromolecules, 26, 2194–2197

    Article  ADS  Google Scholar 

  25. de Azevedo, R. G., Rebelo, L.P.N., Ramos, A.M., Szydlowski, J., de Sousa, H.C. and Klein, J. (2001) Phase behavior of (polyacrylamides+water) solutions: concentration, pressure and isotope effects, Fluid Phase Eq., 185, 189–198

    Article  Google Scholar 

  26. Imre, A.R. and Wolf, B.A., unpublished result

    Google Scholar 

  27. Heremans, K. and Smeller, L. (1998) Protein structure and dynamics at high pressure, Biochim. Biophys. Acta, 1368, 353–370

    Article  Google Scholar 

  28. Whittingham, T.A. (2001) Estimated fetal cerebral ultrasound exposures from clinical examinations, Ultrasound Med. Bioi, 27, 877–882

    Article  Google Scholar 

  29. Bailey, M.R., Blackstock, D.T., Cleveland, R.O. and Crum, L.A. (1998) Comparison of electrohydraulic lithotripters with rigid and pressure-release ellipsoidal reflectors. I. Acoustic fields, J. Acoust. Soc. Am., 104, 2517–2524

    Article  ADS  Google Scholar 

  30. Ludwig, H., Scigalla, W. and Sojka, B. (1996) Pressure and temperature inactication of microorganisms, in. J.L. Markley, D.B. Northrop and CA. Royer (eds.), High Pressure Effects in Molecular Biophysics, Oxford University Press, New York, 346–363

    Google Scholar 

  31. Gelb, L.D., Gubbins, K.E., Radhakrishnan, R. and Sliwinska-Bartkowiak, M. (1999) Phase separation in confined systems, Rep. Prog. Phys., 62, 1573–1659

    Article  ADS  Google Scholar 

  32. Machin. W.D. and Stuckless, J.T. (1985) Capillary-condensed Water in Silica Gel, J. Chem. Soc. Faraday Trans., 81, 597–600

    Article  Google Scholar 

  33. Zhang, J., Liu, G. and Jonas, J. (1992) Effects of Confinement on the Glass Transition Temperature of Molecular Liquids, J. Phys. Chem., 96, 3478–3480

    Article  Google Scholar 

  34. Jackson, C.L. and McKenna, G.B. (1996) Vitrification and Crystallization of Organic Liquids Confined to Nanoscale Pores, Chem. Mater., 8, 2128–2137

    Article  Google Scholar 

  35. Hohenberger, Th., König, R. and Pobell, F. (1998) Phase Separation of Liquid 3He-4He Mixtures in Porous Vycor Glass, J. Low Temp. Phys., 110, 579–584

    Article  ADS  Google Scholar 

  36. Falicov, A. and Berker, A.N. (1995) Correlated Random-Chemical-Potential Model for the Phase Transitions of Helium Mixtures in Porous Media, Phys. Rev. Lett., 74, 426–429

    Article  ADS  Google Scholar 

  37. Pricaupenko, L. and Treiner, J. (1995) Phase separation of Liquid 3He-4He Mixtures: Effect of Confinement, Phys. Rev. Lett., 74, 430–433

    Article  ADS  Google Scholar 

  38. Maris, H. and Balibar, S. (2000), Negative Pressures and Cavitation in Liquid Helium, Physics Today, 53, 29–34

    Article  Google Scholar 

  39. Lilly, M.P. and Hallock, R.B. (1998) Compressibility of 4He Liquid Confined in Nuclepore, J. Low Temp. Phys., 110, 555–560

    Article  ADS  Google Scholar 

  40. Yorozu, S., Hiroi, M., Fukuyama, H., Akimoto, H., Ishimoto, H. and Ogawa, S. (1992) Phase separation curve of 3He-4He mixtures under pressure, Phys. Rev. B, 45, 12942–12948

    Article  ADS  Google Scholar 

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Author information

Authors and Affiliations

  1. Materials Department, KFKI Atomic Energy Research Institute, 1525 Budapest, POB. 49, Hungary

    Attila R. Imre

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  1. Attila R. Imre
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Editors and Affiliations

  1. Materials Department, KFKI Atomic Energy Research Institute, Budapest, Hungary

    A. R. Imre

  2. Department of Physics, Brown University, Providence, RI, USA

    H. J. Maris

  3. Centre for Complex Fluids Processing, Department of Chemical and Biological Process Engineering, University of Wales, Swansea, UK

    P. R. Williams

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© 2002 Springer Science+Business Media Dordrecht

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Imre, A.R. (2002). Liquid-Liquid Phase Equilibria in Binary Mixtures Under Negative Pressure. In: Imre, A.R., Maris, H.J., Williams, P.R. (eds) Liquids Under Negative Pressure. NATO Science Series, vol 84. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0498-5_8

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  • DOI: https://doi.org/10.1007/978-94-010-0498-5_8

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-1-4020-0896-2

  • Online ISBN: 978-94-010-0498-5

  • eBook Packages: Springer Book Archive

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