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Dynamics in Rod-Sphere Composite Liquids

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Structure and Dynamics of Polymer and Colloidal Systems

Part of the book series: NATO Science Series ((ASIC,volume 568))

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Abstract

We review experimental and theoretical work on model rod-sphere composite liquids, emphasizing the dynamics of the spheres and the rods. We first present a survey of experimental techniques that may be used to study composite liquids, and then a brief review of “depletion forces” in colloidal composites. We discuss translational motions of probe spheres in liquids consisting of solvent and entangled rods (polymer composite liquid) and rotational diffusion of probe rods in liquids composed of solvent and spheres (ceramic composite liquid). Possible scaling relations between rod and sphere diffusion coefficients and 1) size (length of rods, radius of spheres) 2) concentrations of the nondilute components and 3) viscosity of the background suspension are considered. Perspectives on further research and more fundamental theoretical approaches are given.

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  1. Department of Chemistry, Stanford University, Stanford, California, 94305-5080, USA

    R. Pecora

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  1. R. Pecora
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Editors and Affiliations

  1. LCPO-CNRS-ENSCPB-Bordeaux University I, Pessac, France

    Redouane Borsali

  2. Stanford University, Stanford, California, USA

    Robert Pecora

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Pecora, R. (2002). Dynamics in Rod-Sphere Composite Liquids. In: Borsali, R., Pecora, R. (eds) Structure and Dynamics of Polymer and Colloidal Systems. NATO Science Series, vol 568. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0442-8_3

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  • DOI: https://doi.org/10.1007/978-94-010-0442-8_3

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