Cadmium

  • Michael J. Scoullos
  • Gerrit H. Vonkeman
  • Iain Thornton
  • Zen Makuch
Part of the Environment & Policy book series (ENPO, volume 31)

Abstract

Cadmium is a Group lib element discovered in 1818 by Herman and Strohmeyer and named after the mythological hero Cadmus who founded Thebes in Greece. It was first extracted commercially in 1886 in Silesia. Its atomic weight is 112.41 (with natural isotopes ranging from 106 to 116). A soft, ductile, silver-white metal (described also as blue-white; Baud, 1962) with a distorted hexagonal structure. Its relative density is 8,642 g/ml3. Its melting point is at 321°C and its boiling point at 767 °C; a relatively ‘volatile’ metal. Cadmium is one of the rare elements in the earth’s crust having an average concentration of about 0.1 mgCd/kg (frequently in the region 100–500 ng/m3). Cadmium concentrations in seawaters near the coast have been reported to be within the range of 0.05 and more than 1 parts per billion (ppb) with an average of around 0.1 ppb (100 ng/m3). However, in the open sea the levels reported are from ≤ 0.01 to 0.05 ppb. Analyses in North Atlantic deep-sea sediments have shown average concentrations around 225 ppb while coastal sediments in polluted areas may be a few orders of magnitude higher. In freshwater, cadmium has the tendency to bind rather strongly to organic substances, especially in chlorophyll-containing plants. However, in the marine environment its predominant compounds are very labile ionic and chloro-complexes and tend to be associated with dissolved particulate phases.

Keywords

Welding Arsenic Shale Diesel Turkey 

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References

  1. —.
    Aichberger, K., unter Mitarbeit von Doberl, H., Eibelhuber, A., Froschauer, J., Hofer, G., 1995. Ergebnisse einer Untersuchung von Wirtschaftsdungern in Oberosterreich. Schriftenreihe der Abt. Umweltschutz 7/95; Hrsg. Amt der Oberosterreichischen Landesregierung, Linz.Google Scholar
  2. —.
    Aloupi, M., Angelidis, M., Scoullos, M., 2000. Spatial and temporal variability of composition of urban effluents in the island of Lesvos, Greece. Environment International, 26, 29–35.CrossRefGoogle Scholar
  3. -Argus Line, 1991. Environmental concerns spur trend to non-cadmium stabilizers. News-letter, Vol. IX, no.1.Google Scholar
  4. —.
    Argus, 2000. The behaviour of PVC in landfill. Study for the European Commission DG XI.E3 by Argus in association with Prof. Spillmann, Carl Bro (University Rostock) and Sigma Plan S.A.Google Scholar
  5. —.
    Baud, P., 1962. Cadmium. In: Nouveau Traite de Chimie minerale, (Eds.) Pascal, P., Vol. V. Masson et Cie editeurs, Paris.Google Scholar
  6. —.
    Bevington, C.F.P., 1984. Environment and the Quality of Life: Possibilities for the reduction of cadmium use and emission by development of new technologies. Metra Consulting, London.Google Scholar
  7. —.
    Blum, W.E.H., Wenzel, W.W., 1989. Bodenschutzkonzeption; Bodenzustandsanalyse und Konzepte fur den Bodenschutz in Österreich. Bundesministerium fur Land-und Forstwirtschaft, Wien.Google Scholar
  8. —.
    Blum W.E.H., 1996. Soil pollution by heavy metals — causes, processes, impacts and need for future actions. Mitt. D. Österr. Bodenkundlichen Ges., 54, 53–78.Google Scholar
  9. —.
    Bohland, J., Depkus, T., Kamm, K., Smigielski, K., 1998. Photovoltaics as hazardous materials: the recycling solution. Proceedings of the Second World Photovoltaic Conference, Vienna.Google Scholar
  10. —.
    Carcone, J., 1998. Nickel Cadmium — A technology in Transition. Proceedings of the 8th International NiCd Conference, Prague 21 & 22 September.Google Scholar
  11. —.
    CMC Engrais, 1986. Note on Phosphatic Fertilisers and Cadmium. Brussels.Google Scholar
  12. —.
    CMC Engrais, 1988. The Food Chain, Cadmium and Phosphate Fertilisers. Brussels.Google Scholar
  13. —.
    Coleman R. et al, 1979. Sources of Atmospheric Cadmium. EPA 450/5-79-006, US Environmental Protection Agency.Google Scholar
  14. —.
    Comu, J.P., 1995. The Ni−Cd battery: a must for the public transit. NiCad94. Proceedings of the Conference organised by ICdA. Geneva, Switzerland, p. 39–44.Google Scholar
  15. —.
    COWI, 2000. Draft report. Mass flow analysis of cadmium. Report prepared by COWI Consulting Engineers and Planners for the Danish Environmental Protection Agency, the Chemical Office.Google Scholar
  16. —.
    Dachler M., Kemmayer, I., 1997. Dungemittelaufwand in Österreich. In KOCHL, A.: Bodenschutz in Österreich. Bundesamt und Forschungszentrum fur Landwirtschaft, Wien.Google Scholar
  17. —.
    Dachler M, Bohm, K., Pfundtner, E., Roth, K., Sager, M., 1997. Information about Cadmium in Austria. BFL / Federal Office and Research Center for Agriculture, Vienna.Google Scholar
  18. —.
    Department of the Environment, 1980. Cadmium in the Environment and its Significance to Man. Pollution Paper No. 17. HMSO, London, UK.Google Scholar
  19. —.
    Descamps, J., 2000. Le cadmium, son marche en France et en Europe, son évolution. Le dossier cadmium, Paris, France.Google Scholar
  20. —.
    EEA, 2000. Dangerous substances in waste. European Environment Agency, technical report No 38.Google Scholar
  21. —.
    Energy, Transport and the Environment. Transnet, 1990.Google Scholar
  22. —.
    ERL 1990. Environmental Resources Limited Final Report of the study to evaluate the sources of human and environmental contamination by cadmium, ref No B6614-566-88.Google Scholar
  23. —.
    EUROMETAUX, 1999. Information Sheets Book.Google Scholar
  24. —.
    Feenstra, J.F., 1978. Control of Water Pollution due to cadmium discharged in the process of producing and using phosphate fertilisers. Vols. I and II, C.E.C.Google Scholar
  25. —.
    Fujimoto, K, 1998. Recycling of NiCd Batteries and other Portable Rechargeable Batteries in Japan, Prague 21 & 22 September.Google Scholar
  26. —.
    Goozner, R., Drinkard, W.F., Long, M.O., Byrd, CM., 1998. A process to recycle Thin Film PV materials. In: PV and the Environment, Keystone, Colorado, US.Google Scholar
  27. —.
    Hawken, P., Lovins, A.M, Lovins, L.H., 1999. Natural Capitalism. Little, Brown and Company Boston, New York, London, pp. 24–37.Google Scholar
  28. —.
    Heijblom, S. 1999 Gft-beleid onder controle? (Separate waste collection under control?). Master Thesis Univ. Utrecht, Dept. Env. Studies, 12 February 1999.Google Scholar
  29. —.
    Hialt and Huff, 1974. The environmental impact of cadmium: An Overview, Intern. J. Environmental Studies, 7, 227.Google Scholar
  30. —.
    Huppes, G., van derVoet, E., van der Naald, W.G.H., Vonkeman, G.H., Maxson, P., 1992. New market-oriented instruments for Environmental Policies. Graham and Trotman, London (ISBN 1-85333-623-8).Google Scholar
  31. —.
    Hutton, M., 1982. Cadmium in the Community. MARK Report No.28, Chelsea, London.Google Scholar
  32. —.
    Hutton M., Symon, C, 1985. The Environmental Significance of Cadmium in Phosphate Fertilisers: A European Perspective. International Fertiliser Conference Proceedings 1985 London.Google Scholar
  33. —.
    Hutton, M., 1995. Cadmium in the Netherlands and some other EU Member States: sources, environmental levels and exposure. European Commission, DG III.Google Scholar
  34. —.
    IFA, 1998. Mineral production and the environment. Part I. The fertilizers industry’s manufacturing process and environmental issues. International Fertilizer Industry Association, Paris, France.Google Scholar
  35. —.
    Jensen, A., Bro-Rasmussen, F., 1989. Review of environmental fate and exposure of cadmium in the European Environment. Final draft report submitted to the European Commission.Google Scholar
  36. —.
    Jensen, A., Bro-Rasmussen, F., 1992. Environmental Contamination in Europe. Reviews of Environmental Contamination and Toxicology, 125, p. 101–181.Google Scholar
  37. —.
    Jemelov A., 1974. Heavy metals, metalloids and synthetic organics. In: The Sea, Vol. 5, p. 799–815, (Eds.) Goldberg, E. John Wiley and Sons, New York (ISBN 0-471-31090-5).Google Scholar
  38. —.
    Journal of Power Sources, Vol. 51, 1994.Google Scholar
  39. —.
    Landner, L., Folke, J., Oberg, M.O., Mikaelsson, H., Aringberg-Laanatza, M., 1996. Cadmium in fertilizers. Consultants report prepared for the OECD cadmium workshop, Sweden, 16–20 October by the European Environmental Research Group Inc. on commission by the National Chemicals Inspectorate, Sweden.Google Scholar
  40. —.
    Lauber W., 1993: Cadmium in Österreich, AK-Information zur Umweltpolitik, Wien.Google Scholar
  41. —.
    Linck, P., 1998. Evolution of collection and recycling of Ni−Cd batteries in Europe and at SNAM in France. Proceedings of the 8th International NiCd Conference, Prague, 21 & 22 September.Google Scholar
  42. —.
    Llewellyn, T., 1994. Cadmium-Materials Flow. Bureau of mines. US Department of the Interior.Google Scholar
  43. —.
    Lund, R.E., Sheppard, R.E., 1964. J. Metals, 16, 724.Google Scholar
  44. —.
    MAFF, 1983. Survey of cadmium in food. First supplementary report. The 12th report of the steering group on food surveillance. HMSO, London.Google Scholar
  45. —.
    Maxson, P.A. and G.H. Vonkeman, 1992. Les métaux lourds dans les phosphates, Study for the European Commission, DG I, contract 021851 (19.12.91), Institute for European Environmental Policy, BrusselsGoogle Scholar
  46. —.
    Moolenaar S.W., Lexmond Th.M., 1998. Heavy-metal balances of agro-ecosystems in The Netherlands. Netherlands Journal of Agricultural Science, 46, 171–192.Google Scholar
  47. —.
    Morrow, H., 1998. The importance of Recycling to Life Cycle Analysis of Nickel Cadmium batteries. Proceedings of the 8th International NiCd Conference, Prague 21 & 22 September.Google Scholar
  48. —.
    Morrow, H., 1998. Cadmium, the issues and answers. ICdA publication.Google Scholar
  49. —.
    Morrow, H., Keating, J., 1999. Overview paper on effective recycling of Ni−Cd batteries. In: Proceedings of the OECD workshop on the effective collection and recycling of Nickel-Cadmium batteries, Lyon, September 1997, p. 23–34. Series on Risk Management No.8.Google Scholar
  50. —.
    Nilsson, R., 1985. Control of Toxic Substances in the Atmosphere: Cadmium. Report 3062 National Swedish Environmental Protection Board.Google Scholar
  51. —.
    Noreus, D., 2000. Substitution of rechargeable NiCd batteries. A report produced for European Commission / DG Environment. Stockholm University.Google Scholar
  52. —.
    Nriagu, J.O., 1980. Cadmium in the Atmosphere and in Precipitation. Cadmium in the Environment, Part I, Ecological Cycling, John Wiley & Sons, pp. 71–114.Google Scholar
  53. —.
    Nriagu, J.O., Pacyna, J.M., 1988. Quantitative Assessment of Worldwide Contamination of Air, Water and Soils by Trace Metals. Nature, 333, 134–139.CrossRefGoogle Scholar
  54. —.
    Nriagu, J.O., 1989. A Global Assessment of Natural Sources of Atmospheric Trace Metals. Nature, 338, 47–49.CrossRefGoogle Scholar
  55. —.
    OECD, 1994. Risk reduction monograph no. 5. Cadmium: Background and National Experience with reducing risk. Environment Monograph Series No. 104, Environment Directorate, Organisation for Economic Cooperation and Development, Paris.Google Scholar
  56. —.
    Pacyna, J.M., 1987. Atmospheric Emissions of Arsenic, Cadmium, Lead and Mercury from High Temperature Processes in Power Generation and Industry. In: Lead, Mercury, Cadmium and Arsenic in the Environment. Hutchinson, T.C. and Meema (Eds.), K.M. Wiley.Google Scholar
  57. —.
    Pacyna, J.M., 1996. Atmospheric emissions of heavy metals for Europe (improvements, updates, historical data and projections). A final report for the International Institute for Applied Systems Analysis (IIASA).Google Scholar
  58. —.
    Pearse, J., 1996. Cadmium: Some aspects of risk reduction. In: Publikatiereeks Stoffen, Veiligheid, Straling, Ministerie van Volkshuisvesting. Ruimtelijke Ordening en Milieubeheer, The Hague, The Netherlands.Google Scholar
  59. —.
    Prater, B.E., 1982. The Environmental Significance of Cadmium in UK Steel making Operations. Env. Technol. Letters 3.Google Scholar
  60. —.
    RAR 1999. Risk assessment cadmium. CAS-No.: 7440-43-9. Draft text.Google Scholar
  61. —.
    RAR 1999. Risk assessment cadmium oxide. CAS-No.: 1306-19-0. Draft report.Google Scholar
  62. —.
    RAR 2000. Risk assessment cadmium oxide as used in batteries. CAS-No.: 7440-43-9, 1306-19-0. Draft report.Google Scholar
  63. —.
    Rauhut, A., 1978. Industrial Emissions from Cadmium in the European Community. Sources, Levels and Control. Cadmium Association, London.Google Scholar
  64. —.
    Ros, J.P.M., Slooff, W., 1988. Integrated Criteria Document Cadmium. National Institute of Public Health and Environmental Protection. Report No. 758476004, Bilthoven.Google Scholar
  65. —.
    Roskill Information Services Ltd, 1990. The Economics of Cadmium. Roskill London, England, 7th ed., Aug., 325 pp. and Appendixes A and B.Google Scholar
  66. —.
    Roskill Information Services Ltd, 1995. Cadmium, market update, analysis and outlook. Roskill London.Google Scholar
  67. —.
    SAFT, 2000. Dossier requesting registration of Ni−Cd batteries on the list of exemptions (Appendix II) to the Directive on end of life vehicles (ELV).Google Scholar
  68. —.
    Sager, M., 1995. Possible trace metal load from fertilizers. Proceeding of the 2nd International IAWQ Specialized Conference and Symposia on Diffuse Pollution, Brno and Prague, Czech Republic.Google Scholar
  69. —.
    Sawell et al., 1988. Heavy Metal Leachability from Solid Waste Incinerator Ashes. Waste Man. and Res 6, 227–238 (ref. cited in: ERL, 1990).CrossRefGoogle Scholar
  70. —.
    Scoullos M. et al. 1990–2000. Metals in Saronic Gulf. MED-POL/UNEP (Series of annual technical reports prepared for the Greek Ministry for the Environment).Google Scholar
  71. —.
    Scoullos, M., Pavlidou A., 2000. Metal Speciation in a Brackish / Marine Interface System. Global Nest, 2, 255–264.Google Scholar
  72. —.
    Smith et al., 1980. Possible Means for Controlling Cadmium Levels in Phosphate Fertilisers; in Cadmium Seminar, Rosslyn, Virginia. Resource Use Committee. The Fertiliser Institute.Google Scholar
  73. —.
    Tenant, C.J., 1984. Cadmium in the Environment and High Risk Population Groups. PhD Thesis, Aston University.Google Scholar
  74. —.
    US EPA 1991. Methodology for assessing environmental releases of and exposure to municipal solid waste combustor residuals. Report EPA/600/8-91/031.Google Scholar
  75. —.
    USBM, 1998. US Bureau of Mines Cadmium. Ch. In Mineral Commodity Summaries.Google Scholar
  76. —.
    USGS, 1998. Mineral Commodity Summaries 1998. US Geological Survey.Google Scholar
  77. —.
    Vermaat, H., 1999 Het tweede leven van een batterij (The second life of a battery). Chemisch Weekblad 5 June 1999, p. 9.Google Scholar
  78. —.
    VMM, 1997. Evaluatie van de gehalten zware metalen in zwevende stof in Vlaanderen. Vlaamse Milieumaatschappij. BelgiumGoogle Scholar
  79. —.
    Vonkeman G. H., 1995. Environmental impacts of cadmium: possible policies and some of their economic implications. In: OECD, Paris (ed.) Sources of Cadmium in the Environment, pp. 126–140, ISBN 92-64-15343-8, 1996.Google Scholar
  80. —.
    VROM/DGM/SVS, 1996. Cadmium, some aspects of risk reduction. Report no. 32.Google Scholar
  81. —.
    Wells, E.O., 1998. Inc magazine, June.Google Scholar
  82. —.
    Wiaux, J.P., 1997. La reduction des flux en metaux lourds contenus dans les ordures menageres par le tri selectif des piles usagees. ICdA report.Google Scholar
  83. —.
    Wiaux, J.P., 2000a. The European Market for Portable and Industrial Ni−Cd batteries. ICdA report.Google Scholar
  84. —.
    Wiaux, J.P., 2000b. Review of the European Recycling Industry of Used Industrial and Portable Ni−Cd batteries. ICdA report.Google Scholar
  85. —.
    Wiaux, J.P., 2000c. Preliminary results summary. On: Targeted Risk Assessment Report on Cadmium (oxide) as used in Ni−Cd Batteries. ICdA report.Google Scholar
  86. —.
    Wiaux, J.P., 2000d. Analysis of potential reduction sources of cadmium emissions during its life cycle. ICdA report.Google Scholar
  87. —.
    Wiaux, J.P., 2000e. The collection of portable and industrial Ni−Cd batteries, market trends and collection efficiency evolution. ICdA report.Google Scholar
  88. —.
    World Metal Statistics, 1998. World Bureau of Metal Statistics.Google Scholar

Copyright information

© Springer Science+Business Media Dordrecht 2001

Authors and Affiliations

  • Michael J. Scoullos
    • 1
  • Gerrit H. Vonkeman
  • Iain Thornton
  • Zen Makuch
  1. 1.Division III Environmental and Marine Chemistry GroupUniversity of AthensAthensGreece

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