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New Trends in Intercalation Compounds for Energy Storage pp 523–530Cite as

Synthesis, Structure and Electrochemical Properties of LiNi0.5-xAlxCo0.5O2 Oxides (0≤x≤0.3)

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Part of the book series: NATO Science Series ((NAII,volume 61))

Abstract

LiCo1-xMxO2 materials, having the layered α-NaFeO2 type structure, are promising cathodes for advanced lithium batteries. Their good performance is very much conditioned by the presence of a good lamellar structure that needs to be stable enough to stand many charge/discharge cycles. In our case, we focus on LiCo1-xMxO2 samples (M=Ni, A1) prepared by a low temperature route: we synthesize them by a sol-gel method using succinic acid as chelating agent. We study the details of their crystallographic structure by XRD, we analyse their chemical composition by ICP and get information about the morphology of the powders by SEM. Also, we carry out a study of their local structure by means of FTIR spectroscopies. Finally, we show the results of the electrochemical studies of the Li//LiNi0.5-xAlxCo0.5O2 prepared cells

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References

  • Ceder, G., Chiang, Y-M., Sadoway, D.R., Aydinol, M.K., Jang, Y-I, and Huang, B. (1998) “Identification of cathode materials for lithium batteries guided by first-principles calculations”, Nature 392, 694–696.

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  • Julien, C. (2000) in C. Julien and Z. Stoynov (eds.) “Design considerations for lithium batteries”, NATO-ASI Sereies, Ser. 3-85, Materials for Lithium-Ion Batteries Kluwer Academic Publishers, The Netherlands, pp. 1–20.

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  • Rougier, A., Saadoune, I., Gravereau, P., Willmann, P., and Delmas, C. (1996) “Effect of cobalt substitution on cationic distribution in LiNi1-yCoyO2 electrode materials”, Solid State Ionics 90, 83–90.

    Article  Google Scholar 

  • Wang, G.X., Zhong, S., Bradhurst, D.H., Dou, S.X., and Liu, H.K. (1999) “LiAlδNi1-δO2 solid Solutions as cathodic materials for rechargeable lithium batteries”, Solid State Ionics 116, 271–277.

    Article  Google Scholar 

  • Zhong, Q. and von Sacken, U. (1995) “Crystal structures and electrochemical properties of LiAlyNi1-yO2 solid solution”, J. Power Sources 54, 221–223.

    Article  Google Scholar 

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Author information

Authors and Affiliations

  1. Departamento de Química Fundamental, University of A Coruña, A Coruna, Spain

    A. Castro-Couceiro, S. Castro-García, M. A. Señarís-Rodríguez & C. Rey-Cabezudo

  2. LMDH, UMR 7603, Université Pierre et Marie Curie, Paris, France

    C. Julien

Authors
  1. A. Castro-Couceiro
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  2. S. Castro-García
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  3. M. A. Señarís-Rodríguez
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  4. C. Rey-Cabezudo
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  5. C. Julien
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Editor information

Editors and Affiliations

  1. Laboratoire des Milieux Désordonnés et Hétérogènes, Université Pierre et Marie Curie, Paris, France

    C. Julien

  2. CNRS/LESCO, Thiais, France

    J. P. Pereira-Ramos

  3. Central Laboratory of Electrochemical Power Sources, Sofia, Bulgaria

    A. Momchilov

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© 2002 Springer Science+Business Media Dordrecht

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Castro-Couceiro, A., Castro-García, S., Señarís-Rodríguez, M.A., Rey-Cabezudo, C., Julien, C. (2002). Synthesis, Structure and Electrochemical Properties of LiNi0.5-xAlxCo0.5O2 Oxides (0≤x≤0.3). In: Julien, C., Pereira-Ramos, J.P., Momchilov, A. (eds) New Trends in Intercalation Compounds for Energy Storage. NATO Science Series, vol 61. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0389-6_41

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  • DOI: https://doi.org/10.1007/978-94-010-0389-6_41

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-1-4020-0595-4

  • Online ISBN: 978-94-010-0389-6

  • eBook Packages: Springer Book Archive

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