Abstract
Since the launch in 1990 of the first commercial lithium-ion batteries based on LiCoO2 cathode materials, a considerable progress has been accomplished in the field of the solid state chemistry and electrochemistry of lithium-manganese spinels, which are thought to be alternative cathode materials. In order to improve the cycling stability of lithiummanganese spinels, the partial replacement of Jahn-Teller Mn3+ ions by transition metal ions or electrochemically inactive metal ions has been successfully applied.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Sanchez, L.and Tirado, J.-L. (1997) Synthesis and Electrochemical Characterization of a New Li-Co-Mn-O Spinel Phase for Rechargeable Lithium Batteries, J. Electrochem. Soc. 144, 1939.
Arora, P., Popov, B.N., and White, R.E. (1998) Electrochemical Investigations of Cobalt-Doped LiMn2O4 as Cathode Material for Lithium-Ion Batteries, J. Electrochem. Soc. 145, 807.
Hosoya, H., Ikuta, H., and Wakihara, M. (1998) Single Phase Region of Cation Substituted Spinel LiMyMn2-yO4-δ (M=Cr, Co and Ni) and Cathode Property for Lithium Secondary Battery, Solid Slate Ionics 111, 153.
Kawai, H., Nagata, M., Kageyama, H., Tukamoto, H., and West, A.R. (1999) 5V Lithium Cathodes Based on Spinel Solid Solutions Li2Co1+xMn3.xO8:-1 ≤ x ≤ 1, Electrochimica Acta 45, 315.
Kawai, P.-H., Nagata, M., Tukamoto, H., and West, A.R. (1998) A New Lithium Cathode LiCoMnO4: Towards Practical 5 V Lithium Batteries, Electrochem. Solid-State Lett. 1, 212.
Strobel, P., Ibarra Palos, A., Anne, M., and Le Cras, F. (2000) Structural, Magnetic and Lithium Insertion Properties of Spinel-type Oxides Li2Mn3MO8 (M=Mg, Co, Ni, Cu), J. Mater. Chem., 10, 429.
Stoyanova, R., Gorova, M., and Zhecheva, E. (2000) EPR of Mn4+ in Spinels Li1+xMn2-xO4 with 0≤x≤1, J. Phys. Chem. Solids 61, 609.
Stoyanova, R., Zhecheva, E., and Gorova, M; (2000) EPR Evidence on Short-range Co/Mn Order in LiCoMnO4 spinels, J. Mater. Chem. 10, 1377.
Zhecheva, E., Stoyanova, R., Gorova, M., Lavela, P., and Tirado, J.-L. (2001) Co/Mn Distribution and Electrochemical Intercalation of Li into Li[Mn2-yCoy]O Spinels, 0≤x≤ 1, Solid State Ionics 140, 19.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2002 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Zhecheva, E., Stoyanova, R., Lavela, P., Tirado, J.L. (2002). Short-Range Co/Mn Ordering and Electrochemical Intercalation of Li into Li[Mn2-yCoy]O4 SPINELS, 0<y≤1. In: Julien, C., Pereira-Ramos, J.P., Momchilov, A. (eds) New Trends in Intercalation Compounds for Energy Storage. NATO Science Series, vol 61. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0389-6_33
Download citation
DOI: https://doi.org/10.1007/978-94-010-0389-6_33
Publisher Name: Springer, Dordrecht
Print ISBN: 978-1-4020-0595-4
Online ISBN: 978-94-010-0389-6
eBook Packages: Springer Book Archive