Abstract
The kinetics and thermodynamics properties of insertion compounds for battery applications are investigated by means of several electrochemical methods. The impedance technique is particularly appealing, and it is used widely, because of two particular features. It is a small signal technique, which means that we may investigate the system at different steady states without affecting significantly the stationary potential. And it is a frequency-resolved technique, which enables one to separate the processes that occur at different time scales (from few mHz up to the kHz).
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References
Bisquert, J., Garcia-Belmonte, G., Bueno, P.R. et al. (1998), “Impedance of constant phase element (CPE)-blocked diffusion in film electrodes”, J. Electroanal. Chem. 452, 229–234.
Bisquert, J., Garcia-Belmonte, G., Fabregat-Santiago, F. et al. (1999), “Theoretical models for ac impedance of diffusion layers exhibiting low frequency dispersion”, J. Electrocutai. Chem. 475, 152–163.
Bisquert, J. (2001), “Theory of the ac impedance of electron diffusion and recombination in a thin layer”, J. Phys. Chern. B to be published.
Bisquert, J. and Compte, A. (2001), “Theory of the electrochemical impedance of anomalous diffusion”, J. Electroanal. Chem. 499, 112–120.
Dyre, J.C. and Schroder, T.B. (2000), “Universality of ac conduction in disordered solids”, Rev. Mod. Phys. 72, 873–888.
Fabregat-Santiago, F., Garcia-Belmonte, G., Bisquert, J. et al. (2001), “Dynamic processes in the coloration of WO3 by lithium insertion”, J. Electrochem. Soc. 148, E302–E309.
Ho, C., Raistrick, I.D. and Huggins, R.A. (1980), “Application of a-c techniques to the study of lithium diffusion in tungsten trioxide films”, J. Electrochem. Soc. 127, 343–350.
Kudo, T. and Hibino, M. (1996) “Consideration on the potential-compensation relationships observed with amorphous intercalation systems as LixWO3”, Solid State Ionics 84, 65–72.
McKinnon, W.R. (1995). “Insertion electrodes I: Atomic and electronic structure of the hosts and their insertion compounds”, in Solid State Electrochemistry (P.G. Bruce, ed.), pp. 163–198, Cambridge University Press, Cambridge.
Stromme Mattson, M. (1998), “Cation intercalation in sputter-deposited W oxide films”, Phys. Rev. B 58, 11015–11022.
Vorotyntsev, M.A., Daikhin, L.I. and Levi, M.D. (1994), “Modelling the impedance properties of electrodes coated with electroactive polymer films”, J. Electroanal. Chem. 364, 37–47.
Vuillemin, B. and Bohnke, O. (1994), “Kinetics study and modelling of the electrochromic phenomenon in amorphous tungsten trioxide thin films in acid and lithium electrolytes”, Solid State Ionics 68, 257–267.
Weppner, W. (1995), “Principles of main experimental methods”, in The CRC Handbook of Solid State Electrochemistry (P. J. Gellings and H. J. M. Bouwmeester, eds.), pp. 295–327, CRC Press, Boca Raton, Florida.
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© 2002 Springer Science+Business Media Dordrecht
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Bisquert, J. (2002). Impedance of Diffusion of Inserted Ions Simple and Advanced Models. In: Julien, C., Pereira-Ramos, J.P., Momchilov, A. (eds) New Trends in Intercalation Compounds for Energy Storage. NATO Science Series, vol 61. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0389-6_23
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DOI: https://doi.org/10.1007/978-94-010-0389-6_23
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