Abstract
A systematic procedure based on norbornene, norbornadiene and their 7-methyl derivatives is described for the determination of the cis content, blockiness and tacticity of ring-opened metathesis polymers (ROMP). In this way the factors determining tacticities and stereoselectivities can be established and applied to the rapidly growing families of well-defined Schrock and Grubbs initiators.
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Amir-Ebrahimi, V., Hamilton, J.G., Rooney, J.J. (2002). Blockiness and Tacticity in Ring-Opened Metathesis Polymers. In: Khosravi, E., Szymanska-Buzar, T. (eds) Ring Opening Metathesis Polymerisation and Related Chemistry. NATO Science Series, vol 56. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0373-5_4
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DOI: https://doi.org/10.1007/978-94-010-0373-5_4
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