Abstract
This review summarises the most interesting approaches in the polymerisation of alkynes and the ring opening metathesis polymerisation of cyclic olefins catalysed by seven-coordinate tungsten(II) and molybdenum(II) compounds. Special attention is given to the catalytically active intermediate compound formed in the reaction of the metal complex and the organic substrate (alkyne or cyclic olefin) and to the reaction mechanism.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Krausz, P., Garnier, F., and Dubois, J.E. (1975) J. Am. Chem. Soc. 97, 437–438.
Agapiou, A. and McNeils, E. (1975) J. Organomet. Chem. 99, C47–C48.
Agapiou, A. and McNeils, E. (1975) J. Chem. Soc. Chem. Commun. 187.
Krausz, P., Gamier, F., and Dubois, J.E. (1976) J. Organomet. Chem. 108, 197–202.
Tanielian, C., Kieffer, R., Harfouch, A. (1977) Tetrahedron Lett. 52, 4589–4592.
Krausz, P., Garnier, F., and Dubois, J.E. (1978) J. Organomet. Chem. 146, 125–134.
Krausz, P., Guillerez, J., Gamier, F. (1978) J. Organomet. Chem. 161, 97–108.
Krausz, P., Gamier, F. and Dubois, J.E. (1979) J. Organomet. Chem. 170, 195–201.
Krausz, P., Gamier, F., Rudler, H. (1980) J. Organomet. Chem. 186, 77–83.
Tanielian, C., Kieffer, R., Harfouch, A. (1981) J. Mol. Catal. 10, 269–284.
Borowczak, D., Szymańska-Buzar, T and Ziółkowski, J.J. (1982) React. Kinet. Catal. Lett. 20, 389–393.
Borowczak, D., Szymańska-Buzar, T and Ziółkowski, J.J. (1984) J. Mol. Catal. 27, 355–365.
Masuda, T., Higashimura, T. (1986) Adv. Polym. sci. 81, 121–165.
Imamoglu, Y., Zumreoglu, B., Amass, A. J. (1986) J. Mol. Catal. 36, 107–114.
Szymańska-Buzar, T. and Ziółkowski, J.J. (1987) J. Mol. Catal. 43, 161–170.
Zumreoglu-Karan, B., Bozkurt, C., Imamoglu, Y. (1992) Polym. J. 24, 25–29.
Schilder, P.G.M., Stufkens, D.J., Oskam, A., Mol, J.C. (1992) J. Organomet. Chem. 126, 351–359.
Gita, B., Sundararajan, G. (1993) Tetrahedron Lett. 34, 6123–6126.
Tamura, K., Masuda, T., Higashimura, T. (1994) Polymer Bull. 32, 289–296.
Szymanska-Buzar, T. (1997) J. Mol. Catal., A: Chem. 123, 113–122.
Zareie, M.H., Kavakli, C., Salih, B., Piskin, E. (1997) J. Mol. Catal. A: Chem. 118, 195–203.
Gita, B., Sundararajan, G. (1997) J. Mol. Catal. A: Chem. 115, 79–84.
Gita, B., Manivanhan, R., Sundararajan, G. (2000) J. Organomet. Chem. 601, 16–21.
Szymanska-Buzar, T., Downs, A.J., Greene T.M., and Wood, M.A.K. (1991) J Organomet. Chem. 419, 151–162.
Szymańska-Buzar, T., Győr, M., Rockenbauer, A., and Sümegi, L. (1986) React. Kinet. Catal. Lett. 32, 407–412.
Cotton, F.A., Falvello, L.R., Meadows, J.H. (1985) Inorg. Chem. 24, 514–517.
Szymańska-Buzar, T. (1988) Inorg. Chim. Acta 145, 231–233.
Szymańska-Buzar, T. (1989) J. Organomet. Chem. 375, 85–89.
Bencze, L., Ivin, K.J., Rooney, J. (1980) J. Chem..Soc. Chem. Comm. 834–835.
Bencze, L., Kraut-Vass, A. (1984) J.Organomet.Chem. 270, 211–220.
Bencze, L., Kraut-Vass, A. Prókai, L. (1985) J.Chem.Soc.Chem.Comm. 911–912.
Bencze, L., Szalai, G., Hamilton, J.G., Rooney, J.J. (1997) J.Mol.Catal. A: Chem., 115, 193–197.
Szymańska-Buzar, T. (1991) J.Mol.Catal., 68, 177–186.
Szymańska-Buzar, T., Głowiak, T. (1995) J.Organomet.Chem., 489, 207–214.
Szymańska-Buzar, T., Głowiak, T. (1998) J.Organomet.Chem. 564, 143–153.
Szymańska-Buzar, T., Głowiak, T., Czeluśniak, I. (2000) Inorg.Chem.Comm. 3, 102–104.
Szymańska-Buzar, T. (1994) J.Mol.Catal., 43, 137–147.
Szymańska-Buzar, T. (1995) J.Organomet.Chem. 492, 241–246.
Szymańska-Buzar, T., Głowiak, T. (1998) Polyhedron, 17, 3419–3426.
Szymańska-Buzar, T., Głowiak, T. (1999) J. Organomet. Chem. 575, 98–107.
Szymańska-Buzar, T., Czeluśniak, I. (2000) J. Mol. Catal. A: Chem. 160, 133–143.
Szymańska-Buzar, T., Głowiak, T., Czeluśniak, I. Manuscript in preparation.
Szymańska-Buzar, T., Głowiak, T. (1996) J. Organomet. Chem. 523, 63–74.
Szymanśka-Buzar, T., Głowiak, T., Czeluśniak, I. (1999) J. Organomet. Chem. 585, 215–224.
Czeluśniak, I., Gńowiak, T., Szymańska-Buzar, T. (2000) Inorg. Chem. Comm. 3, 285–288.
Masuda, T., Sasuki, N., and Higashimura, T. (1975) Macromolecules 717–721.
Yeh, W.-Y., Peng, S.-M., Lee, G.-H. (1993) J. Chem. Soc. Chem. Comm. 13, 1056–1057.
Szymanska-Buzar, T., Glowiak, T. (1997) Polyhedron 16, 1599–1603.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2002 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Szymańska-Buzar, T. (2002). Polymerisation of Cyclic Olefins and Alkynes by Sevencoordinate Tungsten (II) and Molybdenum (II) Compounds. In: Khosravi, E., Szymanska-Buzar, T. (eds) Ring Opening Metathesis Polymerisation and Related Chemistry. NATO Science Series, vol 56. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0373-5_30
Download citation
DOI: https://doi.org/10.1007/978-94-010-0373-5_30
Publisher Name: Springer, Dordrecht
Print ISBN: 978-1-4020-0559-6
Online ISBN: 978-94-010-0373-5
eBook Packages: Springer Book Archive