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Effective Syntheses of Natural Compounds Using Ring Opening Metathesis as a Key Reaction

  • V. I. Bykov
  • A. R. Goletiani
  • T. A. Butenko
  • E. V. Egupova
  • E. Sh. Finkelshtein
Part of the NATO Science Series book series (NAII, volume 56)

Abstract

The olefin metathesis reaction is a convenient reaction for assembling complicated molecules containing hydrocarbon skeletons from simpler starting “blocks”. Many widespread constituents of naturally occurring compounds of both animal and vegetable origin are long chain linear or macrocyclic structures. Among them, for example, are insect sex pheromone components (linear functionalized unsaturated compounds), natural plant growth regulators (linear saturated long chain alcohols) and perfume ingredients (macrocyclic ketones, lactones), etc. As a rule their traditional syntheses contain many steps and demand rather complicated procedures.

Keywords

Pheromone Component Double Bond Position Terminal Double Bond Tetradecenyl Acetate Ring Opening Metathesis 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer Science+Business Media Dordrecht 2002

Authors and Affiliations

  • V. I. Bykov
    • 1
  • A. R. Goletiani
    • 1
  • T. A. Butenko
    • 1
  • E. V. Egupova
    • 1
  • E. Sh. Finkelshtein
    • 1
  1. 1.Topchiev Institute of Petrochemical SynthesisRussian Academy of SciencesMoscowRussia

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