Abstract
During the last ten years, a number of three- and low-dimensional organic-inorganic hybrid semiconductors based on metal halide units have been prepared and (for some reviews see [1–3]). It has been found that these compounds could be used as elements in nonlinear optical devices [4], light emitting diodes [5], optical microcavities [6] and as channels in thin-film field effect transistors [7]. Mainly, the structural, optical and related properties of compounds, crystallized or deposited on substrates from their solutions in several solvents, have been reported [1–3, 8–14]. There is only little information on properties of hybrid compounds obtained from melts [12]. Very recently, a number of compounds have been prepared from melts and characterized crystallographically [15]. The compounds [CH3C6H4CH2NH3]2SnI4, [CH3C6H4CH2NH3]2PbI4, [CH3C6H4CH2NH3]2PbBr4, [CH3C6H4CH2NH3]2PbCl4, [C6H5(CH2)2NH3]2PbI4, [C6H5(CH2)4NH3]2PbI4, [C4H9NH3]2PbBr4, have been prepared from melts into glass tubes and found to be two-dimensional (2D) compounds, i.e., isostructural to those obtained from solutions.
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References
Ishihara, T. (1995) in T. Ogawa and Y. Kanemitsu (eds.), Optical Properties of Low-Dimensional Materials, World Science, Singapore, pp. 288–339.
Papavassiliou, G.C. (1997) Progr. Solid State Chem. 25, 125.
Mitzi, D.B. (1999) Progr. Inorg. Chem. 48, 1.
Kondo, T., Iwamoto, S., Hayase, S., Tanaka, K., Ishi, I, Mizuno, M, Ema, K. and Ito, R. (1998) Sol. State Commun. 105, 503.
Hattori, T., Taira, T., Era, M., Tsutsui, T. and Saito, S. (1996) Chem. Phys. Lett. 254, 103; Gebauer, T. and Schmid, G. (1999) Z Anorg. Allg. Chem. 625, 1124; Chondroudis, K. and Mitzi, D.B. (1999) Chem. Mater. 11, 3028.
Fujita, T., Sato, Y., Kuitani, T. and Ishihara T. (1998) Phys. Rev. B 57, 12428.
Kagan, C.R., Mitzi D.B. and Dimitrakopoulos C.D. (1999), Science 286, 945.
Mousdis, G.A., Papavassiliou, G.C, Raptopoulou, C.P. and Terzis, A. (2000) J. Mater. Chem. 10, 515; Papavassiliou, G.C, Mousdis, G.A., Terzis, A. and Raptopoulou, C.P. (1999), Z Naturforsch. 54b, 109.
Papavassiliou, G.C, Mousdis, G.A., Raptopoulou, C.P. and Terzis, A. (1999) Z Naturforsch. 54b, 1405.
Papavassiliou, G.C, Mousdis, G.A., Raptopoulou, C.P. and Terzis, A. (2000) Z. Naturforsch. 55b, 536.
Papavassiliou, G.C, Mousdis, G.A., Koutselas, I.B., Raptopoulou, C.P., Terzis, A., Kanatzidis, M.G. and Axtell III, E.A. (1998)Adv. Mater. Opt. Electron. 8, 263; Papavassiliou, G.C, Mousdis, G.A. and Koutselas, I.B. (1999) Adv. Mater. Opt. Electron. 9, 265; (2001) Ibid., in press.
Papavassiliou, G.C, and Koutseias, I.B. (1995) Synth. Metals 71, 1713; Papavassiliou, G.C, Patsis, A.D., Lagouvardos, D.J. and Koutselas, I.B. (1993) Ibid. 55-57, 3889.
Papavassiliou, G.C, Mousdis, G.A. and Koutselas, I.B. (2001) Synth. Metals 121, 1339; (2001) Chem. Monthly 132, 113; (2001) Int. J. Modern Phys. B, in press.
Braun, M., Tuffentsammer, W., Wachtel, H. and Wolf, H.C (1999) Chem. Phys. Lett. 303, 157; (1999) 307, 373; Era, M, Maeda, K. and Tsutsui, T. (1998) Ibid. 296, 417; Mitzi, D.B., Chondroudis, K. and Kagan, C.R. (1999) Inorg. Chem. 38, 6246.
Papavassiliou, G.C, Terzis, A. Mousdis, G.A. and Papaioannou, G.J., Private Commun.
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Papavassiliou, G.C., Koutselas, I.B., Mousdis, G.A., Papaioannou, G.J. (2002). Some Organic-Inorganic Hybrid Semiconductors Obtained from Melts. In: Graja, A., Bułka, B.R., Kajzar, F. (eds) Molecular Low Dimensional and Nanostructured Materials for Advanced Applications. NATO Science Series, vol 59. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0349-0_40
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