Abstract
Substituted hexa-peri-hexabenzocoronenes (HBC) belong to the family of molecules which are able to self assemble in discotic columnar liquid crystalline (LC) mesophases [1]. High mobility of charge carriers both in LC and solid phase [2] makes them interesting from a point of view of developing molecular electronic devices e.g. light emitting diodes (LEDs) or field effect transistors (FETs). Studies on preparation of samples with suitable supramolecular structures are of a primary importance for such potential applications. In this communication, results concerning the structure and morphology of the HBC-C12 (HBC substituted with R=n-C12H25) solidified from a solution on various substrates and as a component in polymer composites are presented.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Ito, S., Wehmeier, M., Brand, J.D., Kübel, C., Epsch, R., Rabe, J.P., Müllen, K. (2000) Synthesis and self-assembly of functionalized hexa-peri-hexabenzocoronenes, Chem. Eur.J., 6, 4327–4342.
van de Craats, A.M., Varman, J.M., Müllen, K. Geerts, Y. and Brand, J.D. (1998) Rapid charge transport along self-assembling graphitic nanowires, Adv.Mater., 10, 36–38.
Herwig, P, Kayser, C.W., Müllen, K., Spiess, H.W. (1996) Columnar mesophases of a alkylated hexa-peri-hexabenzocoronenes with remarkably large phase widths., Adv.Mater., 8, 510–13.
Biasutti, M.A, Rommens, J., Vaes, A., De Feyter, S., De Schryver, F.D., Hervig, P., Mullen, K. (1997) Photophysical Properties of a New Class of Discotic LC Compounds: Hexa (Dodecyl) Hexa Peri Benzyl Coronene, Bull.Soc.Chem.Belg., 106 659–664.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2002 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Tracz, A. et al. (2002). Micro-Fibers of Hexa (Alkyl) Hexa-peri-Hexabenzocoronene. In: Graja, A., Bułka, B.R., Kajzar, F. (eds) Molecular Low Dimensional and Nanostructured Materials for Advanced Applications. NATO Science Series, vol 59. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0349-0_39
Download citation
DOI: https://doi.org/10.1007/978-94-010-0349-0_39
Publisher Name: Springer, Dordrecht
Print ISBN: 978-1-4020-0578-7
Online ISBN: 978-94-010-0349-0
eBook Packages: Springer Book Archive