Abstract
In recent years the interest of molecular electronics in organic compounds able to produce electroactive organic thin films by Langmuir-Blodgett (LB) technique has considerably increased. Various amphiphilic tetrathiafulvalenes with long alkyl chains are considered to be very promising from this point of view [1]. But recent studies on LB films based on non-amphiphilic TTF derivatives [2–4] have demonstrated that the attachment of long-chain substituents is not a prerequisite for creating of conducting LB films of TTF-based CT complexes; it is interesting that some of them include thiobenzyl-moieties [e.g., 2]. In 1998 a new asymmetrically substituted TTF derivative, namely dibenzylthiodimethylthioTTF, was reported to form a stable monolayer in a mixture with arachidic acid [5]. For the same purposes we have synthesised a new group of TTFs with benzylthio substituents, fluorinated in various positions of a benzene ring, and investigated their π-donor ability [6].
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Abashev, G.G., Shklyaeva, E.V. and Plis, A. (2000), in preparation.
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Abashev, G.G., Shklyaeva, E.V., Tenishev, A.G., Sheremetev, A.B., Yudin, I.L. (2002). 2-Cyanoethylthio-1,3-Dithiole-2-Selone—New Precusors in Tetrathiafulvalene Synthesis. Tetrathiafulvalenes, Incorporating 1,3,4-Oxadiazole and Cyanoethyl Moieties. In: Graja, A., Bułka, B.R., Kajzar, F. (eds) Molecular Low Dimensional and Nanostructured Materials for Advanced Applications. NATO Science Series, vol 59. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0349-0_28
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DOI: https://doi.org/10.1007/978-94-010-0349-0_28
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