Abstract
Several complexes containing transition metal (MnII and CuII) coordinated to two radicals as NITpPy or imi-pPy and polycyanide anions are presented. The X-ray crystal structures analysis reveale that these compounds present various dimensionalities ranging from discrete molecule (0D) to three dimensional (3D) network, depending on the μ coordination type of the cyanide ligands. The magnetic studies revealed intramolecular antiferromagnetic interactions for the Cu containing compounds while ferromagnetic interactions were observed for the Mn containing compounds. But all the compounds exhibit intermolecular antiferromagnetic interactions at very low temperature.
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Ouahab, L., Dasna, I., Golhen, S., Daro, N., Sutter, JP. (2002). Polymeric Magnetic Coordination Complexes: From Isolated (0-D) Molecules to 3-D Materials. In: Graja, A., Bułka, B.R., Kajzar, F. (eds) Molecular Low Dimensional and Nanostructured Materials for Advanced Applications. NATO Science Series, vol 59. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0349-0_19
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DOI: https://doi.org/10.1007/978-94-010-0349-0_19
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