Polymeric Magnetic Coordination Complexes: From Isolated (0-D) Molecules to 3-D Materials

  • L. Ouahab
  • I. Dasna
  • S. Golhen
  • N. Daro
  • J.-P. Sutter
Part of the NATO Science Series book series (NAII, volume 59)

Abstract

Several complexes containing transition metal (MnII and CuII) coordinated to two radicals as NITpPy or imi-pPy and polycyanide anions are presented. The X-ray crystal structures analysis reveale that these compounds present various dimensionalities ranging from discrete molecule (0D) to three dimensional (3D) network, depending on the μ coordination type of the cyanide ligands. The magnetic studies revealed intramolecular antiferromagnetic interactions for the Cu containing compounds while ferromagnetic interactions were observed for the Mn containing compounds. But all the compounds exhibit intermolecular antiferromagnetic interactions at very low temperature.

Keywords

Manganese Cyanide Coupler Indonesia CH3CN 

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Copyright information

© Springer Science+Business Media Dordrecht 2002

Authors and Affiliations

  • L. Ouahab
    • 1
  • I. Dasna
    • 1
    • 3
  • S. Golhen
    • 1
  • N. Daro
    • 2
  • J.-P. Sutter
    • 2
  1. 1.Laboratoire de Chimie du Solide et Inorganique Moléculaire, UMR 6511 CNRSInstitut de Chimie de RennesRennes cedexFrance
  2. 2.Laboratoire des Sciences MoléculairesICMCBPessacFrance
  3. 3.Jurusan Kimia, FMIPAUniversitas Negeri MalangMalangIndonesia

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