Abstract
In recent years the self-assembling processes in some materials have become very important in connection with development of the nanometer-scale molecular technology. Calyxarenes are the molecules of just such a type. The possibility of thin evaporated and Langmuir-Blodgett calyxarene films swelling under the action of solvent molecules has been demonstrated previously. Some models of separate molecules complexing were proposed and theoretical models were developed to explain the effect of structural relaxation under the influence of solvent vapor. Here we present the results of our investigation of thin thermally deposited films of some calyxarenes and their derivatives treated in solvent vapors. The efficient modern methods, such as surface plasmon resonance, atomic force microscopy and quartz crystal microbalance, were used. Dramatic changes in optical constants and film morphology were observed. The numerical data analysis was performed and physico-chemical model was proposed to explain the results obtained and predict some new effects. Our results could be used in research and development of specially timed sorbents for electronic nose - a new and very promising kind of information devices.
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References
Bekctov G.V., Shirshov Yu.M., Shinkarcnko E.V., Chcgel V.l., 1998. Surface plasmon resonance spectroscopy: prospects of superstate refractive index variation for separate extraction of molecular layer parameters. Sensors and Actuators B48,425–432.
Bidan G., 1992. Electroconducting conjugated polymers: new sensitive matrices to build up chemical or electrochemical sensors. A review. Sensors and Actuators B6,45–56.
Carotta M.C., Martinelli G., Crema L.,.Malagu, Merli M., Ghiotti G., Traversa E., 2001. Nanostructured thick-film gas sensors for atmospheric pollutant monitoring. Sensors and Actuators B 76, 336–342.
CRC Handbook of chemistry and physics, CRC Press Boca Raton, 74-th Ed. 1993-94.
Dicken F.L., Bruckdorfer Th., Feigl H. et al., 1993. Supramolecular detection of solvent vapours with QMB and SAW devices. Sensors and Actuators À 13-14, 297–301.
Dicken F.L., Halikias K., Hayden O., Piu L, Sikorski R., 2001. Sensors based on fingerprints of neutral and ionic analytes in polymeric materials. Sensors and Actuators B 76, 295–298.
DiNatale C, Paolesse R., Macagnano A., Mantini A., Man P., D’Amico A., 2000. Qualitative structure-sensitivity relationship in porphyrins base QMB chrmical sensors. Sensors and Actuators B68, 319–323.
Dodd G.H., Dartlett P.N., Gardner J.W.,1992. Odours, the stimulus for an electronic nose, in Sensors & Sensory Systems for an Electronic Nose (eds. J.W. Gardner and P.N. Bartlett). NATO AS1 Series E: Applied Science 212, pp. 1–12.
Feinman R., Leighton R., Sands M., 1963. The Feinman lectures on physics, Edison-Wesley Publishing Company. Inc, London, p. 64.
Fredriksson C, Kichiman S., Rodahl M., Kazemo B., 1998. The piezoelectric quartz crystal mass and dissipation sensor. Lengmuir 14,248–251.
Gardner J.W., Pearce T.C., Friel S. et al., 1994. A multisensor system for beer flavour monitoring using an array of conducting polymers and predictive classifiers. Sensors and Actuators B18-19, 240–243.
Goepel W., 1994. New materials and transducers for chemical sensors. Sensors and Actuators B B18-19, 1–21.
Guadarrama A., Rodrigues-Mendez M.L., de Saja J.A., Rios J.L., Olias J.V., 2000. Array of sensors based on conducted polymers for the quality control of the aroma of the virgin olive oil. Sensors and Actuators B 69, 276–282.
Gutsche C.,D. In: J.F. toddart (Ed.), 1989. Calixarenes: Monographs in supramolecular chemistry, Royal Sosiety of Chemistry, Cambridge, pp.90–97.
Hartmann J., Hauptmann P., Levi, S, Dalcanale E., 1996. Chemical sensing with cavitands: influence of cavity shape and dimensions on the detection of solvent vapors. Sens. Actuators B35, 154–157.
Hatfield J.F., Neaves P., Hiks P.J. et al., 1994. Towards an integrated electronic nose using conducting polymer sensors. Sensors and Actuators B18-19, 221–228.
Hawkins T.M., Travers P.J.,1999. Counter-ion influence on the response of conducting polymer gas sensors. Proceedings of 6-th International Symposium ISOEN99, Tuebingen, pp.113–116.
Hsuing CM., Munoz B., Li J., Vicie M, Köper O., 1999. Relationship between the physical structure of a polymer composite based electronic nose and its response. Proceedings of 6-th International Symposium ISOEN99, Tuebingen, pp.150–153.
Janshoff A., Steinern C, Michalke A., Henke C, Galla H.-J., 2000. Monofunctionalized b-cyclodextrins as sensor elements for detection of small molecules. Sensors and Actuators B70, 243–253.
Kostioukevich S.A., Shirshov Yu.M., Matsas E.P., Stronski A.V., Subbota Yu.V. Chegel V.l., Shepelyavi P.E., 1995. Application of surface plasmon resonance for the invesyigation of ultrathin metal films. Proc.SPIE v.2648, pp. 144–151.
Kriz D., Ramstrom O., Mosbach K., 1997 (June). Molecular imprinting: new possibilities for sensor technology. Anal.Chem.News&Features, pp.345a–349a.
Krummel Ch., Krage R., Reicht D., Gauglitz G., 1999. VOC detection by means a new polymer-based optical transducer. Proc.of 9-th Intern. Trade Fair and Conference for Sensors, Transducers and Systems, Nürnberg vol.1 pp. 139–143.
Kukla AL., Shirshov Yu.M., Piletsky S.A., 1996. Ammonia sensors based on sensitive polyaniline films. Sensors and Actuators B37, 135–140.
Kunsagi-Mate S., Nagy G., Kollar L., 2001. Calculation of energy compexes host-guest Investigation of calixarene (host) and neutral benzotrifluoride (guest). Sensors and Actuators B76, 545–550.
Lucklum R., Hauptmann P., 2000. Response of quartz-crystal microbalance: mass sensitivity, viscoelacticity and acousctic amplification. Sensors and Actuators B 70, 30–36.
Malmsten M., 1994. Ellipsometry studies of protein layers adsorbed at hydrophobic surfaces. Joum. of colloid and interface science 166, 333–342.
Nabok A.V., Lavrik N.V., Kazantseva Z.I.,Nesterenko B.A., Markovskiy L.N., Kalchenko V.I., Shivaniuk A.N., 1995. Thin Solid Films 259, 244–247.
Nelli P., Dalcanale E., Faglia G. et al., 1993. Cavitends as selective materials for QMB sensors for nitrobenzene and other aromatic vapours. Sensors and Actuators B13-14, 302–304.
O’Sullivan C.K., Guilbault G.G., 1999. Commercial quartz crystal microbalances-theory and application. Biosensors and Bioelectronics 14, 663–670.
Rengevych O.V., Shirshov Yu.M., Ushenin Yu.V., Beketov A.G., 1999. Separate determination of thickness and optical parameters by surface plasmon resonance: accuracy consideration Semiconductor Physics, Quantum Electronics & Optoelectronocs 2, 28–35.
Schlupp M., Heil C., Koch A., Mullcr-Albrecht J., Schramm U., Bargon J., 2000. Metal colloids as sensor-active materials for the detection of valatilc compounds and solvents. Sensors and Actuators B71, 9–12.
Shih J.-S., Chao Y.-Ch., Sung M.-F., Gau G.-J., Chiou Ch.-S., 2001. Piezoelectric crystal mnembranc chemical sensors based on fullcrcne C60. Sensors and Actuators B76, 347–353.
Shirshov Y. M., Snopok B.A., Samoylov A.V., Kiyanovskij A.P., Venger E. F., Nabok A.V., Ray A. K., 2001. Analysis of the réponse of planar polarization interferometer to molecular layer formation: fibrinogen adsorption on silicon nitride surface. Biosensors and Bioclectronics 16, 381–390.
Shirshov Yu.M., Svcchnikov S.V., Kiyanovskii A.P., Ushenin Yu.V., Venger E.F. and Merker R., 1998. A sensor based on the planar-polarization interferometer. Sensors & Actuators A68, 384–387.
Shirshov Yu.M., Gerasimcnko V.S., Kunitskij I.E., Kutichina Zh.Ya., Nazarov A.N., 1990. Thermally stimulated depolarization of phosphosilicatc glasses. Ukrainian Physical Journ. 35, 544–549.
Shirshov Yu.M., Zynio S.A., Matsas E.P., Beketov G.V.,.Prokhorovich A.V, Vtnger E.F., Markovskiy L.N., Kalchenko V.l., Soloviov A.V., Merker R. 1997. Supramol. Sci. 4, 491–494.
Slavik R., Homola J.,Tyroký J., Brynda E., 2001. Novel spectral fiber optic sensor based on surface plasmon resonance. Sensors and Actuators B: Chemical 74, 106–111.
Steiner F.-P., Hirlemann A., Cornila C, Noetzel G., Bacchtold M., Korvink J.G., Gopel W., Baltes H., 1995. Polymer coated capacitive microintegrated gas sensor. Proc.of the 8-th Int.Conf. on Solid State Sensors and Actuators, Eurosensors IX, Sockholm, pp.814–817.
Szczurek A., Szekowka P., Lichnerski B.W., 1998. Volatile organic compounds mixtures guantification with TGS sensor array. Proc.of the 12-th European Conference on Solid-State Transducers, Southhampton, pp. 841–844.
Torsi L, Dodabalapur A., Sabbatini L. and Zambonin P.G., 2000. Multi-parameter gas sensors based on organic thin-film-transistors. Sensors and Actuators B: Chemical 67, 312–316.
Varadan V.K., Gardner J.W., 1999. Smart tongues and smart noses, in Smart Structures and MEMS (ed. V.K. Varadan). Proceedings of SP1E 3673, 67–76.
Vicens, J.; Bohmer, V., 1991. Calixarenes: A Versatile Class of Macrocyclic Compounds; Kluwer, Dordrecht,. http://www.analytical-microsystems.de
Zee F., Judy J.W., 1999. Miniaturization of a carbon black/polymer array electronic nose. Proceedings of 6-th International Symposium 1SOEN99, Tuebingen,pp. 120–123.
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Shirshov, Y., Snopok, B., Rengevych, O., Kalchenko, V., Coleman, A. (2002). Relaxation of Nanostructured Molecular Materials Under The Influence of Solvent Vapors. In: Buzaneva, E., Scharff, P. (eds) Frontiers of Multifunctional Nanosystems. NATO Science Series, vol 57. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0341-4_27
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DOI: https://doi.org/10.1007/978-94-010-0341-4_27
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