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A Novel Network Structure of Organometallic Clusters in Gas Phase

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Frontiers of Multifunctional Nanosystems

Part of the book series: NATO Science Series ((NAII,volume 57))

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Abstract

Synthesis of organometallic compounds in gas phase presents a novel guideline to preparative chemists because they can be prepared without solvent and oxidation in air. Especially, the application of the laser vaporization to the gas-phase synthesis of organometallic compounds enables us to prepare the constituents in considerable density in a short time because there are no interfering effects of solvents, aggregation phenomena, and counter ions. This new approach should open up an entirely different aspect of organometallic chemistry and physics, which can be studied quite nicely in the gas phase, and indeed several groups independently have succeeded in the synthesis of novel organometallic complexes.1-7 The technique used to produce and detect the gas- phase organometallic clusters involves a beam source with laser vaporization of metal rods and time-of-flight mass spectrometry whose distinct ability was well-demonstrated in the discovery of C60 8 and metallo-carbohedrene,9,10 a so-called met-car.

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Author information

Authors and Affiliations

  1. Department of Chemistry, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, 223-8522, Yokohama, Japan

    Atsushi Nakajima

  2. Institute for Molecular Science, 444-8585, Myodaiji, Okazaki, Japan

    Koji Kaya

Authors
  1. Atsushi Nakajima
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  2. Koji Kaya
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Editor information

Editors and Affiliations

  1. Kyiv National Taras Shevchenko University, Ukraine

    Eugenia Buzaneva

  2. TU Ilmenau, Institut für Physik/Fachgebiet Chemie, Germany

    Peter Scharff

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Nakajima, A., Kaya, K. (2002). A Novel Network Structure of Organometallic Clusters in Gas Phase. In: Buzaneva, E., Scharff, P. (eds) Frontiers of Multifunctional Nanosystems. NATO Science Series, vol 57. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0341-4_13

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  • DOI: https://doi.org/10.1007/978-94-010-0341-4_13

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-1-4020-0561-9

  • Online ISBN: 978-94-010-0341-4

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