Abstract
The main objective of this article is to provide an up-to-date presentation of the structural models of inorganic glasses. First of all, a glass will be defined from the glass transition temperature and the main elements of the glass classification will be shown. Then, characterization of a disordered structure as glass, will be divided, depending on the range order, in two parts: the short-range order, constituted of basic structural units and, the medium-range order, constituted of superstructural units in a scale ranging from the dimension of the basic structural unit to scales of at least 2-5 nm. Almost all types of used techniques will be mentioned to illustrate selective information which can be obtained on different composition of glasses. In addition recent advances in optical glasses will also be provided.
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References
Zarzycki, J. (1991) Glasses and the vitreous state, Cambridge university Press, Cambridge.
Zarzycki, J, Prassas, M., and Phalippou J. (1982) J. Mater. Sci. 17, 3371.
Mackenzie, J. (1960) (1962) (1964) Modern aspects of the vitreous state, I,II,III, Butterworth, London.
Sun, K. (1947) J. Am.Cer.Soc. 30, 277.
Sen, S. (2000) Atomic environment of high-field strength Nd and Al cations as dopants and major components in silicate glasses: a Nd LIII-edge and Al K-edge X-ray absorption spectroscopic study, J. Non. Cryst. Solids 261, 226–236.
Becker, P.C., Olsson, N.A., and Simpson, J.R., (1999) Erbium-Doped Fiber Amplifiers, Academic Press, New York.
Petit, L., Cardinal, T., Videau, J., Le Flem, G., Guyot, Y., Boulon, G., Couzi, M. and Buffeteau T. (2002) Effect of the introduction of Na2B4O7 on erbium luminescence in tellurite glasses, J. Non. Cryst. Solids 298, 76–88.
Durville, F., Champagnon, B., Duval, E., Boulon, G., Gaume, F., Wrihgt, A., Fitch, A. (1984) Nuclation induced in a cordierite glass by Cr3+:a study by small angle neutron scattering, EPR, and laser spectroscopy, Physics and Chemistry of Glasses 25, 126.
Durville, F., Champagnon, B., Duval, E., Boulon, G. (1985) Laser specroscopy of spinel micro-crystallites in a Cr3+-doped silicate glass, J.Phys.Chem.Solids 46, 701–707.
Poncon, V., Kalisky, Y., Boulon, G., Reisfeld, R. (1897) Transparent glass-ceramics doped with Cr3+:low temperature time-resolved spectra and characterization of gahnite and virgilite crystaline phases, Chemcal Physics Letters 133
Nie, W., Boulon, G., Mai, C., Esnouf, C., Xu, R., and Zarzycki, J. (1990) Nucleation induced in gahnite-like glasses and xerogels by chromium:a study by laser spectroscopy, J. Non, Cryst. Solids 121, 282–287.
Nie, W., Boulon, G., Mai, C., Esnouf, C., Xu, R., and Zarzycki, J. (1992) Crystallization behavior of xerogels in a Cr2O3-doped SiO2-Al2O3-ZnO system, Chemistry of Materials 4
Schaller, T., Jonathan, F., Wilding, S., and Wilding, M. (1999) Cation clustering and formation of free oxide ions in sodium and potassium lanthanum silicate glasses: nuclear magnetic resonance and Raman spectroscopic findings, J. Non. Cryst. Solid, 243 146–157.
Brecher, C., and Riseberg, L.A., (1976) Laser-induced fluorescence line narrowing in Eu glass: A spectroscopic analysis of coordination structure, Phys. Rev. B 13, 81.
Concas, G., Congiua, F., Spanoa, G., Speghinib, A. and Gattererc, K. (1998) Mössbauer investigation of rare earth sites in europium containing glasses, J. Non. Cryst. Solids 232-234, 341–345.
Ollier, N, Panczer, G.,. Champagnon, B, Boulon, G. and Jollivet, P. (2001) Europium as a luminescent probe of an aluminoborosilicate nuclear glass and its weathering gels, J. of Luminescence 94-95, 197–201.
Rocca, F., Ferrari, M., Kuzmin, A., Daldosso, N., Duverger, C., and Monti, F. (2001), EXAFS studies of the local structure of Er3+ ions in silica xerogels co-doped with aluminium, J. Non. Cryst. Solids 293-295, 112.
Lochhead, M.J., and Bray, K.L. (1995) High-pressure fluorescence line narrowing of Eu(III)-doped sodium disilicate glass, Phys. Rev. B 52, 15763–15775.
Monteil, A., Bernard, C., Chaussedent, S., Ferrari, M., Balu, N. and Obriot J. (2000) Pressure effect on the structure and the luminescence of rare-earth ions doped glasses: an investigation by molecular dynamics simulation, J. of Luminescence 87-89, 691–693.
Elliott, S.R. (1984).Physics of Amorphous Materials, Longman, New York.
A. Fontana, G. Viliani (Eds.), (1999) Seventh International Workshop on Disordered Systems (special issue), Phil. Mag. B 79(11/12), Andalo
Duval, E., Boukenter, A., Achibat, T. (1990) J. Phys.: Condens. Matter 2, 10227–10234.
Obaton, A. F., Duval, E., and Boulon, G. unpublished results.
Obaton, A.F., Paren, C., Le Flem, G., Thony, P., Brenier, A., and Boulon, G. (2000) Yb3+-Er3+-codoped LaLiP4Ol2 glass: a new eye-safe laser at 1535 nm, Journal of Alloys and Compounds 300-301, 123–130.
D’Angelo, G., Tripodo, G., Bartolotta, A., Carini, G., Fontana, A., Montagna M., Rossi, F., Ferrari, M. and Terki, F. (2001) Low-temperature specific heats of porous silica xerogels of low densities, J. Non. Cryst. Solids 280, 222–227.
Macfarlane, R.M, and Shelby, R.M., (1987) in: A.A. Kaplyanskii, R.M. Macfarlane (Eds.), Spectroscopy of Solids Containing Rare Earth Ions, 21, North-Holland, Amsterdam.
Schmidt, Th., Baak, J., Van de Straat, D., Brom, H., and Volker, S., (1994) Temperature dependence of optical line and specific heat of rare earth-doped silicate glasses, J.of Luminescence 58, 180–183.
Fujita, K., and Hirao, K. (2002) Temperature dependence of homogeneous line width of Eu3+ in sodium aluminosilicate glasses, J. of Luminescence 98, 295–300.
Nogami, M., Umehara, N.; and Hayakawa, T. (1998) Effect of hydroxyl bonds on persistent spectral hole burning in Eu3+-doped BaO-P2O5 glasses, Physical Review B 58, 6166–6171.
Song, H., and Nogami M. (2002) Room-temperature hole-burning and sublinear hole-growth dynamics in an Sm2+-doped aluminosilicate glass, J. Non. Cryst. Solids 297, 113–119.
Pellé, F., and Auzel, F. (2000) Saturation effect on multiphonon relaxation rates of rare earth ions in glasses at high excitation power, Journal of Alloys and Compounds 300-301, 131–140.
Tanabe, S., Sugimoto, N., Ito S., and Hanada T. (2000) Broad-band 1.5 μm emission of Er3+ ions in bismuth-based oxide glasses for potential WDM amplifier, J. of Luminescence 87-89, 670-672.
Campbell, H., and. Suratwala, T. I (2000) Nd-doped phosphate glasses for high-energy/high-peak-power lasers, J. Non. Cryst. Solids 263-264, 318–341.
Felice, V., Dussardier, B.,, Jones, J. K., Monnom, G., and Ostrowsky, D. B. (2001) Chromium-doped silica optical fibers: influence of the core composition on the Cr oxidation states and crystal field, Optical Materials 16, 269–277.
Fernandez, J., Mendioroza, A., García, A. J., Balda, R., Adam J. L. and Arriandiagac M. A. (2001) On the origin of anti-Stokes laser-induced cooling of Yb3+-doped glass, Optical Materials 16, 173–179.
Joubert, M.F. (1999) Photon avalanche upconversion in rare earth laser materials, Optical Materials 11 181–203.
Martin I., Rodriguez V., Guyot Y., Guy S, Boulon G., and Joubert, M-F (2000) Room temperature photon avalanche upconversion in Tm3+-doped fluoroindate glasses, J. Phys.: Condens. Matter 12 1507–1516.
Goldner, P., Schaudel B., Prassas and Auzel F. (2000) Influence of the host structure and doping precursors on rare earth clustering in phosphate glasses analysed by co-operative luminescence, Journal of Luminescence 87-89, 688–690.
Auzel, F. and Goldner, P. (2001) Towards rare-earth clustering control in doped glasses Optical Materials 16, 93–103.
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Boulon, G. (2003). Structures and Models of Glasses. In: Di Bartolo, B. (eds) Spectroscopy of Systems with Spatially Confined Structures. NATO Science Series, vol 90. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0287-5_16
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DOI: https://doi.org/10.1007/978-94-010-0287-5_16
Publisher Name: Springer, Dordrecht
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