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Hyperfine Interactions (C) pp 305–308Cite as

151Eu Mössbauer spectroscopic and XRD study on some fluorite-type solid solution systems, EuyM1−yO2−y/2 (M=Zr, Hf, Ce)

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Abstract

151Eu Mössbauer spectroscopy and powder x-ray diffractometry (XRD) have been applied to elucidate the local structure around the trivalent europium (Eu3+) in the titled three defect-fluorite systems. From this study, it has been clarified that in contrast to Eu-Ce system the stabilized cubic-fluorite phase in Eu-Zr and Eu-Hf systems has most likely a pyrochlore-type local structure (microdomain structure).

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Authors and Affiliations

  1. Department of Materials Science, Japan Atomic Energy Research Institute, Tokai-mura, 319-1195, Japan

    N. M. Masaki, H. Otobe & A. Nakamura

  2. Philippine Nuclear Research Institute, Quezon city, 1101, Philippine

    N. R. D. Guillermo

  3. Department of Chemistry, Hokkaido University, Sapporo, 060-0810, Japan

    Y. Izumiyama, D. Harada & Y. Hinatsu

Authors
  1. N. M. Masaki
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  2. H. Otobe
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  3. A. Nakamura
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  4. N. R. D. Guillermo
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  5. Y. Izumiyama
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  6. D. Harada
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  7. Y. Hinatsu
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Editor information

Editors and Affiliations

  1. Department of Physics, University of Liverpool, Liverpool, UK

    Michael F. Thomas

  2. Department of Physics, University of Sheffield, Scheffield, UK

    John M. Williams

  3. Department of Chemistry, University of Leeds, Leeds, UK

    Terence C. Gibb

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© 2002 Springer Science+Business Media Dordrecht

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Masaki, N.M. et al. (2002). 151Eu Mössbauer spectroscopic and XRD study on some fluorite-type solid solution systems, EuyM1−yO2−y/2 (M=Zr, Hf, Ce). In: Thomas, M.F., Williams, J.M., Gibb, T.C. (eds) Hyperfine Interactions (C). Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0281-3_76

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  • DOI: https://doi.org/10.1007/978-94-010-0281-3_76

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-1-4020-1087-3

  • Online ISBN: 978-94-010-0281-3

  • eBook Packages: Springer Book Archive

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