Abstract
A Mössbauer spectroscopy system has been developed which is capable of taking multiple Mössbauer spectra which are related in time. Its present design is for operation in conjunction with an in-situ electrochemical cell, such that up to 256 Mössbauer spectra can be taken in a dedicated PC. These spectra are uniformly distributed around a cyclic voltammetry loop which is continually retraced until sufficient statistics are accumulated. This system was used to acquire four spectra of a Prussian-blue-modified graphite paste electrode, while the electrode was involved in an electrochemical process. The spectra show differences due to the reduction and oxidation of the iron in Prussian blue.
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© 2002 Springer Science+Business Media Dordrecht
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Greaves, T.L., Cashion, J.D., Benci, A.L., Jaggi, N.K., Hogan, C., Bond, A.M. (2002). Multiple Mössbauer Spectra Data Acquisition with an In-situ Cyclic Voltammetry System. In: Thomas, M.F., Williams, J.M., Gibb, T.C. (eds) Hyperfine Interactions (C). Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0281-3_6
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DOI: https://doi.org/10.1007/978-94-010-0281-3_6
Publisher Name: Springer, Dordrecht
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