Skip to main content

Theory of Wetting and Surface Critical Phenomena

  • Chapter
Computer Simulations of Surfaces and Interfaces

Part of the book series: NATO Science Series ((NAII,volume 114))

  • 529 Accesses

Abstract

Surfaces and interfaces exhibit a rich variety of phase transitions. While some of these phase transitions also occur in the bulk, others involve coupling between surface and bulk degrees of freedom; consequently the surface phase diagram may be rather complex even for simple Ising like systems. In these lectures I will introduce the generic 4-dimensional surface phase diagram (bulk and surface couplings, bulk and surface fields) of Ising like systems and discuss bulk vs. surface criticality. I will start with a review of surface thermodynamics and scaling of interfaces with emphasis on wetting phenomena. Then Landau mean-field theory is used to calculate the global surface phase diagram. The effects of thermal fluctuations are discussed using the capillary wave Hamiltonian: The correlation functions are calculated using Ornstein-Zernike theory for systems with short and long-range forces. Finally, I will comment on the status of the renormalization group results for 3-dimensional short-range critical wetting that are at odds with the results of simulations of the Ising model and of a recent experiment.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Ball, P.: 1997, Made to Measure. Princeton: Princeton University Press.

    Google Scholar 

  2. Binder, K.: 1983. In: C. Domb and J. L. Lebowitz (eds.): Phase Transitions and Critical Phenomena, Vol. 8. London: Academic, Chapt. 1.

    Google Scholar 

  3. Binder, K., D. P. Landau, and M. Müller: 2002, ‘Monte Carlo studies of wetting, interface localization and capillary condensation’. preprint, to appear in J. Stat. Phys., available via http://sokrates.physik.uni-mainz.de.

  4. Bonn, D. and D. Ross: 2001. Rep. Prog. Phys. 64, 1085.

    Google Scholar 

  5. Cahn, J. W.: 1977. J. Chem. Phys. 66, 3667.

    Article  ADS  Google Scholar 

  6. Diehl, H. W.: 1986. In: C. Domb and J. L. Lebowitz (eds.): Phase Transitions and Critical Phenomena, Vol. 10. London: Academic, Chapt. 2.

    Google Scholar 

  7. Dietrich, S.: 1988. In: C. Domb and J. L. Lebowitz (eds.): Phase Transitions and Critical Phenomena, Vol. 12. London: Academic, Chapt. 1.

    Google Scholar 

  8. Forgacs, G., R. Lipowsky, and T. M. Nieuwenhuizen: 1991. In: C. Domb and J. L. Lebowitz (eds.): Phase Transitions and Critical Phenomena, Vol. 14. London: Academic, Cha

    Google Scholar 

  9. Jasnow, D.: 1986. In: C. Domb and J. L. Lebowitz (eds.): Phase Transitions and Critical Phenomena, Vol. 10. London: Academic, Chapt. 3.

    Google Scholar 

  10. Parry, A. O.: 1996. J. Phys. Cond. Matter 8, 10761.

    Article  ADS  Google Scholar 

  11. Ross, D., D. Bonn, and J. Meunier: 1999. Nature 400, 737.

    Article  ADS  Google Scholar 

  12. Rowlinson, J. S. and B. Widom: 1982, Molecular Theory of Capillarity. Oxford: Clarendon.

    Google Scholar 

  13. Schick, M.: 1990. In: J. Charvolin, J. F. Joanny, and J. Zinn-Justin (eds.): Liquids at Interfaces (Les Houches Session XLVIII, 1988). Amsterdam: Elsevier, p. 415.

    Google Scholar 

  14. Sullivan, D. E. and M. M. T. da Gama: 1986. In: C. A. Croxton (ed.): Fluid Interfacial Phenomena. New York: Wiley, Chap

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2003 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

da gama Telo, M.M. (2003). Theory of Wetting and Surface Critical Phenomena. In: Dünweg, B., Landau, D.P., Milchev, A.I. (eds) Computer Simulations of Surfaces and Interfaces. NATO Science Series, vol 114. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0173-1_13

Download citation

  • DOI: https://doi.org/10.1007/978-94-010-0173-1_13

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-1-4020-1464-2

  • Online ISBN: 978-94-010-0173-1

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics