Skip to main content

Part of the book series: NATO Science Series ((NAII,volume 102))

Abstract

In the present work, composite metal containing silicate thin coatings (Me=Ag, Cu) were prepared on glass substrates by the sol-gel route. The preparation process included hydrolysis and subsequent polycondensation of corresponding alkoxide under refluxing and addition of soluble salt of antibacterial metal to the resulting sol. The coatings deposited by dipping process, were thermally treated in oxidative and reductive conditions up to 500°C for metal nanoparticles formation. The coating structure and the nanoparticles formation were studied by X-ray Diffraction, AFM, UV-VIS and Heavy Ion Rutherford Backscattering (HIRBS) Spectroscopies. The antibacterial activity against Escherichia Coli was examined by the so-called antibacterial-drop test. The possible correlation between the layer interdiffusion after the thermal treatment and the antibacterial activity, was considered and analyzed. The coatings exhibited a high antibacterial activity, which was enhanced with the increase of the metal concentration and was decreased with the increase of temperature of thermal treatment and metal nanoparticles formation.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Modak S. M., Fox C.L. J., (1973) Biochem Pharmacol. 22, 2391.

    Article  CAS  Google Scholar 

  2. Berger T. J., Spadaro J. A., Chapin S. E., Becker R. O., (1976) Agents Chemother. 9, 357.

    Article  CAS  Google Scholar 

  3. Williams R. L., Doherty P. J., Vince D. G., Grashoff G. J., Williams D. F., (1989) Crit. Rev. Biocompat 5, 221.

    CAS  Google Scholar 

  4. Yoshinari T., Uchida M., (1994) J. Kor. Ceram. Month. Feb., 119.

    Google Scholar 

  5. Oloffs A., Grosse-Siestrup C., Bisson S., Rinck M., Rudolph R., Gross U., (1994) Biomaterials 15, 753.

    Article  CAS  Google Scholar 

  6. Kawashita M., Tsuneyama S., Miyaji F., Kokubo T., Kozuka H., Yamamoto K., (2000) Biomaterials 21, 393.

    Article  CAS  Google Scholar 

  7. Mitrikas G., Trapalis C. C., Deligiannakis Y., Boukos N. and Koreas G., (1998) J. of Sol-Gel Sci. and Tech. 13,1/3, 503.

    Article  Google Scholar 

  8. Aslanoglou X., Assimakopoulos P. A., Trapalis C. C., Kordas G., Karakassides M. A., Pilakouta M., (1996)Nucl. Instr. And Meth. B 118, 630.

    Google Scholar 

  9. lnnocenzi P., Kozuka H., (1994) J. Sol-Gel Sci. Tech. 3, 229.

    Article  Google Scholar 

  10. Hinsch A., Zastrow A., J. Non-Cryst. Solids, (1992) 147–148, 579.

    Google Scholar 

  11. Breitscheidel B., Zieder J., Schubert U., (1991) Chem. Mater. 3, 559

    Article  CAS  Google Scholar 

  12. Brusilovsky D., Eyal M., Reisfekd R., (1988) Chem. Phys. Lett. 9, 203.

    Article  Google Scholar 

  13. Tamahashi I., Yoshida M., Manabe Y., T. Tohda, (1995) J. Mater. Res. 10, 362.

    Article  Google Scholar 

  14. Trapalis C.C., Karakassides M.A., Kordas G., Aslanoglou X., (1995) Materials Letters, 25, 265.

    Article  CAS  Google Scholar 

  15. Samuneva B.I., Trapalis C.C., Kozhukharov V.S., Kranold R., (1993) Journal of Materials Science 29, 2353.

    Article  Google Scholar 

  16. Trapalis C.C., Kozhukharov V.S., Samuneva B.I., Stefanov P., (1993) Journal of Materials Science, 28, 1276.

    Article  CAS  Google Scholar 

  17. Kozhukharov V.S., Trapalis C.C., Samuneva B.I., (1993) Journal of Materials Science, 28, 1283

    Article  CAS  Google Scholar 

  18. Kokkoris M., Trapalis C.C., Kossionidis S., Vlastou R., Nsouli B., Grotzschel R., Spartalis S., Kordas G. and Paradelis Th., (2002) Nucl. Instr. and Meth. B, 188, no. 1, 67.

    Article  CAS  Google Scholar 

  19. Doolittle L.R., (1985) Nucl. Instr. And Meth B 9, 344.

    Article  Google Scholar 

  20. Zhao Z., Hasebe K., Sakagami Y., Osaka T., (1997) Bul. Chem. Soc. Jpn. 1631.

    Google Scholar 

  21. Mazoldi P., Arnold G.W., Battaglin G., Bertoncello R. and Gonella F., (1994) Nucl. Instr. Meth. B, 91, 478.

    Article  Google Scholar 

  22. Kundu D., Honna I., Osawa T., and Komiyama H., (1944) J Ceram Soc., 77, 1110.

    Article  Google Scholar 

  23. Mennmg M., Schmitt M., Kutsch B., Schmidt H., (1994) Sol-Gel Optics III, SPIE 2288, 120.

    Article  Google Scholar 

  24. Doremus R., Kao S., and Garcia R., (1992) Appl Opt., 31, 5773.

    Article  CAS  Google Scholar 

  25. Nogami M., Abe Y., and Nakamura A., (1995) J. Mater. Res. 10, 2648.

    Article  CAS  Google Scholar 

  26. De G., Epifani M., Licciulli A., (1996) J. Non-Crystalline Solids, 201, 250.

    Article  CAS  Google Scholar 

  27. Maeda H., Iwasaki M., Yasumori A. and Yamane M., (1990) J. Non-Cryst. Solids 121, 61.

    Article  CAS  Google Scholar 

  28. Ghandour W., Hubbard A., Deinstung J., Hughes M., and Poole R., (1988) Appl. Microbiol. Biotechnol., 28, 559.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to C. C. Trapalis .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2003 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

Trapalis, C.C., Vaimakis, T., Kharlamov, A., Kokkoris, M., Kordas, G. (2003). Nanostructured MeSiO2 (Me=Ag, Cu) Coatings with Antibacterial Activity. In: Gogotsi, Y.G., Uvarova, I.V. (eds) Nanostructured Materials and Coatings for Biomedical and Sensor Applications. NATO Science Series, vol 102. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0157-1_4

Download citation

  • DOI: https://doi.org/10.1007/978-94-010-0157-1_4

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-1-4020-1321-8

  • Online ISBN: 978-94-010-0157-1

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics