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Part of the book series: Space Sciences Series of ISSI ((SSSI,volume 16))

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Abstract

Deuterated molecules are detected both in interstellar translucent clouds and in cold dark clouds, as well as in star forming regions. We review the recent observational studies of deuterated molecules ranging from the VUV to the millimeter wavelength range. We outline some sources of uncertainties on the deuterium fractionation and on the subsequent derivation of the elemental deuterium to hydrogen ratio. Steady state versus time dependent models are discussed and the role of initial conditions is emphasized.

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References

  • Bell, M.B., Avery, L.W., Matthews, H.E., Feldman, P.A., Watson, J.K.G., Madden, S.C., and Irvine, W.M.: 1988, ‘A Study of C3HD in Cold Interstellar Clouds’, Astrophys. J. 326, 924–930.

    Article  ADS  Google Scholar 

  • Bertoldi, F., Timmermann, R., Rosenthal, D., Drapatz, S., and Wright, C.M.: 1999, ‘Detection of HD in the Orion Molecular Outflow’, Astron. Astrophys. 346, 267–277.

    ADS  Google Scholar 

  • Brogan, C.L., and Troland, T.H.: 2001, ‘Very large array H I Zeeman observations toward the W49 complex’, Astrophys. J. 550, 799–816.

    Article  ADS  Google Scholar 

  • Butner, H.M., Lada, E.A., and Loren, R.B.: 1995, ‘Physical Properties of Dense Cores: DCO+ Observations’, Astrophys. J. 448, 207–225.

    Article  ADS  Google Scholar 

  • Caselli, P., Walmsley, C.M., Zucconi, A., Tafalla, M., Dore, L., and Myers, P.C.: 2002, ‘Molecular Ions in L1544. II. The Ionization Degree’, Astrophys. J. 565, 344–358.

    Article  ADS  Google Scholar 

  • Caux, E., Ceccarelli, C., Pagani, L., Maret, S., Castets, A., and Pardo, J.R.: 2002, ‘HD 112 m in Absorption and Extreme CO Depletion in a Cold Molecular Cloud’, Astron. Astrophys. 383, L9–L13.

    Article  ADS  Google Scholar 

  • Gerin, M., Wootten, H.A., Combes, F., Boulanger, F., Peters, W.L. III, Kuiper, T.B.H., Encrenaz, P.J. Bogey, M.: 1987, ‘Deuterated C3H2 as a Clue to Deuterium Chemistry’, Astron. Astrophys. 173, L1–L4.

    ADS  Google Scholar 

  • Gerin, M., Combes, F., Wlodarczak, G., Encrenaz, P., and Laurent, C.: 1992a ‘Interstellar Detection of Deuterated Methyl Acetylene’, Astron. Astrophys. 253, L29–L33.

    ADS  Google Scholar 

  • Gerin, M., Combes, F., Wlodarczak, G., Jacq, T., Guélin, M., Encrenaz, P., and Laurent, C.: 1992b, ‘Interstellar Detection of Deuterated Methyl Cyanide’, Astron. Astrophys. 259, L35–L38.

    ADS  Google Scholar 

  • Gerin, M., Pearson, J.C., Roueff, E., Falgarone, E., and Phillips, T.G.: 2001, ‘Determination of the Hyperfine Structure of N2D+’, Astrophys. J. 551, L193–L197.

    Article  ADS  Google Scholar 

  • Gordy, W., and Cook, R.L.:1984, Microwave Molecular Spectra, 3rd Edition, John Wiley and Sons publisher.

    Google Scholar 

  • Hatchell, J., Roberts, H., and Millar, T.J.: 1999, ‘Limits on HDS/H2S Abundance Ratios in Hot Molecular Cores’, Astron. Astrophys. 346, 227–232.

    ADS  Google Scholar 

  • Helmich, F.P., van Dishoeck, E.F., and Jansen, D.J.: 1996, ‘The Excitation and Abundance of HDO Toward W3(OH)/(H2O)’, Astron. Astrophys. 313, 657–663.

    ADS  Google Scholar 

  • Herbst, E., and Leung, C.M.: 1989, ‘Gas-phase Production of Complex Hydrocarbons, Cyanopolyynes, and Related Compounds in Dense Interstellar Clouds’, Astrophys. J. Suppl. 69, 271–300.

    Article  ADS  Google Scholar 

  • Herbst, E.: 2003, ‘Isotopic Fractionation by Ion-molecule Reactions’, Space Sci. Rev this volume.

    Google Scholar 

  • Hirota, T., Yamamoto, S., Mikami, H., and Ohishi, M.: 1998, ‘Abundances of HCN and HNC in Dark Cloud Cores’, Astrophys. J. 503, 717–728.

    Article  ADS  Google Scholar 

  • Hirota, T., Ikeda, M., and Yamamoto, S.: 2001, ‘Observations of DNC and HN13C in Dark Clouds’, Astrophys. J. 547, 814–828.

    Article  ADS  Google Scholar 

  • Jacq, T., Walmsley, C.M., Mauersberger, R., Anderson, T., Herbst, E., and de Lucia, F.C.: 1993, ‘Detection of Interstellar CH2DOH’, Astron. Astrophys. 271, 276–281.

    ADS  Google Scholar 

  • Le Bourlot, J., Pineau des Forêts, G., Roueff, E., and Schilke, P.: 1993, ‘Bistability in Dark Cloud Chemistry’, Astrophys. J 416, L87–L90.

    Article  ADS  Google Scholar 

  • Le Petit, F., Roueff, E., and Le Bourlot, J.: 2002, ‘D/HD transition in Photo-dominated Regions (PDR)’, Astron. Astrophys. 390, 369–381.

    Article  ADS  Google Scholar 

  • Le Teuff, Y.H., Millar, T.J., and Markwick, A.J.: 2000, ‘The UMIST Database for Astrochemistry 1999’, Astron. Astrophys. Suppl. 146, 157–168.

    Article  ADS  Google Scholar 

  • Lis, D.C., Gerin, M., Phillips, T.G., and Motte, F.: 2002a, ‘The Role of Outflows and C Shocks in the Strong Deuteration of L1689N’, Astrophys. J 569, 322–333.

    Article  ADS  Google Scholar 

  • Lis, D., Roueff, E., Gerin, M., Phillips, T.G., Coudert, van der Tak, F.F.S., and Schilke, P.: 2002, ‘Detection of Triply Deuterated Ammonia in the Barnard 1 Cloud’, Astrophys. J 571, L55–L58.

    Article  ADS  Google Scholar 

  • Loinard, L., Castets, A., Ceccarelli, C., Caux, E., and Tielens, A.G.G.M.: 2001, ‘The Enormous Abundance of D2CO in IRAS 16293–2422’, Astrophys. J. 552, 16293–2422.

    Article  ADS  Google Scholar 

  • Loinard, L., Castets, A., Ceccarelli, C., Tielens, A.G.G.M., Faure, A., Caux, E., and Duvert, G.: 2000, ‘Doubly Deuterated Molecular Species in Protostellar Environments’, Astron. Astrophys. 359, 1169–1174.

    ADS  Google Scholar 

  • McLeod, J.M., Avery, L.W., and Broten, N.W.: 1981, ‘Detection of Deuterated Cyanodiacetylene DC5N in Taurus Molecular Cloud 1’Astrophys. J. 251L33–L36.

    Article  ADS  Google Scholar 

  • Maucrsberger, R., Henkel, C., Jacq, T., and Walmsley, C.M.: 1988, ‘Deuterated Methanol in Orion’, Astron. Astrophys. 194, L1–L4.

    ADS  Google Scholar 

  • Minowa, H., Satake, M., Hirota, T., Yamamoto, S., Ohishi, M., and Kaifu, N.: 1997, ‘Laboratory Microwave Spectroscopy of HDCS and Its Astronomical Detection Toward TMC-1’, Astrophys. J. 491, L63–L66.

    Article  ADS  Google Scholar 

  • Morton, D.C.: 1975, ‘Interstellar Absorption Lines in the Spectrum of Zeta Ophiuchii’, Astrophys. J. 221, 85–115.

    Article  ADS  Google Scholar 

  • Petitjean, P., Srianand, R., and Ledoux, C.: 2000, ‘Molecular Hydrogen and the Nature of Damped Lyman-α Systems’, Astron. Astrophys. 364, L26–L30.

    ADS  Google Scholar 

  • Rachford, B.L., Snow, T.P., Tumlinson, J., Shull, J.M., Roueff, E., Andre, M., Desert, J.-M., Ferlet, R., Vidal-Madjar, A., and York, D.G.: 2000, ‘Far Ultraviolet Spectroscopic Explorer Observations of Molecular Hydrogen in Translucent Interstellar Clouds. II. The Line of Sight Toward HD 110432’, Astrophys. J. 555, 839–849.

    Article  ADS  Google Scholar 

  • Roberts, H., Fuller, G.A., Millar, T.J., Hatchell, J., and Buckle, J.V.: 2002, ‘A Survey of [HDCO]/[H2CO] and [DCN]/[HCN] Ratios Towards Low-mass Protostellar Cores’, Astron. Astrophys. 381, 1026–1038.

    Article  ADS  Google Scholar 

  • Roueff, E., Tiné, S., Coudert, L.H., Pineau des Forêts, G., Falgarone, E., and Gerin, M.: 2000, ‘Detection of Doubly Deuterated Ammonia in L134N’, Astron. Astrophys. 354, L63–L66.

    ADS  Google Scholar 

  • Roueff, E., et al.: 2002, ‘The Chemistry of Triply Deuterated Ammonia’, Astron. Astrophys. in preparation.

    Google Scholar 

  • Saito, S., Ozeki, H., Ohishi, M., and Yamamoto, S.: 2000, ‘Observations of NH2D Toward Dark Molecular Clouds’, Astrophys. J. 535, 227–230.

    Article  ADS  Google Scholar 

  • Schloerb, F.P., Snell, R.L., Young, J.S., and Langer, W.D.: 1981, ‘Detection of Deuteriocyanobutadiyne, DC5N, in the Interstellar Cloud TMC-1’, Astrophys. J 251, L37–L41.

    Article  ADS  Google Scholar 

  • Shah, R.Y., and Wootten, A.: 2001, ‘Deuterated Ammonia in Galactic Protostellar Cores’, Astrophys. J. 554, 933–947.

    Article  ADS  Google Scholar 

  • Stark, R., van der Tak, F.F.S., and van Dishoeck, E.F.: 1999, ‘Detection of Interstellar H2D+ Emission’, Astrophys. J. 521, L67–L70.

    Article  ADS  Google Scholar 

  • Tiné, S., Roueff, E., Falgarone, E., Gerin, M., and Pineau des Forêts, G.: 2000, ‘Deuterium Fractionation in Dense Ammonia Cores’, Astron. Astrophys. 356, 1039–1049.

    ADS  Google Scholar 

  • Turner, B.E.: 2001, ‘Deuterated Molecules in Translucent and Dark Clouds’, Astrophys. J. Suppl. 136, 579–629.

    Article  ADS  Google Scholar 

  • Turner, B.E.: 1990, ‘Detection of Doubly Deuterated Interstellar Formaldehyde (D2 CO) - an Indicator of Active Grain Surface Chemistry’, Astrophys. J. Lett. 347, L29–L33.

    Article  ADS  Google Scholar 

  • Turner, B.E.: 1989, ‘Detection of Interstellar C4D - Implications for Ion-molecule Chemistry’, Astrophys. J 347, L39–L42.

    Article  ADS  Google Scholar 

  • van Dishoeck, E.F., Blake, G.A., Jansen, J., and Groesbeck, T.D,: 1995, ‘HD Molecular Lines in an Absorption System at Redshift z=2.3377’, Astrophys. J 136, 579–629.

    Google Scholar 

  • van der Tak, F.F.S, Schilke, P., Müller, H.S.P., Lis, D.C., and Phillips T.G.: 2002, ‘Triply Deuterated Ammonia in NGC 1333’, Astron. Astrophys. in press.

    Google Scholar 

  • Varshalovich, D.A., Ivanchik, A.V., Petitjean, P., Srianand, R., and Ledoux, C.: 2001, ‘Molecular Abundances and Low-Mass Star Formation. II. Organic and Deuterated Species Toward IRAS 16293–2422’, Astronomy Let. 27, 16293–2422.

    Article  ADS  Google Scholar 

  • Wright, E.L., and Morton, D.C.: 1979, ‘Rotationally Excited HD Toward Zeta Ophiuchii’, Astrophys. J. 227, 483–488.

    Article  ADS  Google Scholar 

  • Wright, C.M., van Dishoeck, E.F., Cox, P., Sidher, S.D., and Kessler, M.F.: 1999, ‘Infrared Space Observatory-Long Wavelength Spectrometer Detection of the 112 Micron HD J = 1→0 Line Toward the Orion Bar’, Astrophys. J. 515, L29–L33.

    Article  ADS  Google Scholar 

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Roueff, E., Gerin, M. (2003). Deuterium in Molecules of the Interstellar Medium. In: Kallenbach, R., Encrenaz, T., Geiss, J., Mauersberger, K., Owen, T.C., Robert, F. (eds) Solar System History from Isotopic Signatures of Volatile Elements. Space Sciences Series of ISSI, vol 16. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0145-8_5

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  • DOI: https://doi.org/10.1007/978-94-010-0145-8_5

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-3970-3

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