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Room-Temperature Sulfur Chloride Ionic Liquids in Processes for the Isolation of Noble and other Metals

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Book cover Green Industrial Applications of Ionic Liquids

Part of the book series: NATO Science Series ((NAII,volume 92))

Abstract

A correlation of interatomic distances (d/Å), chalcogen-chlorine bond stretching frequencies (v/cm−1) and 35Cl NQR frequencies (MHz) has been performed for crystals of chalcogen chloride complexes of gold(III) and osmium(IV). A conclusion has been drawn as to the functional peculiarities of chalcogen chloride molecules being part of complexes. The state of the complexes under investigation in nonaqueous polar solvents has been studied using Raman spectroscopic and conductometric methods; the form of the species formed in solutions has been established. New ionic liquids — reagents for the comprehensive processing of raw materials containing noble metals — are proposed.

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References

  1. Glukhov, I.A., and Shalukina, L.N. (1976) Sulfur-chlorine system, Izw. AN Tadz. SSR, Department of Physico-Mathematical and Geological-Chemical Sciences, 54–57.

    Google Scholar 

  2. Ninisto, L. (1976) The reaction of disulfur dichloride with aqueous ammonia, Soumen Rem. 43, 342–343.

    Google Scholar 

  3. Funk, H., Berdt, Henze, G. et al. (1957) Über die Einwirkung von Chlorschwefel (Dichschwefel-dichlorid) auf Metalle und Metalloxide, Vfrtin-Luter-Univ.Rflle-Mtenberg-Math., Naturwiss.Reine 6, 815–822.

    CAS  Google Scholar 

  4. Koldits, L., Moya, I., Galov, U., and Darstellung (1984) Eigenschaften Struktur und Anwendung von Trichlorsulfonium-Verbindungen SC13 +A-, Z Chem. 24, 51–56.

    Article  Google Scholar 

  5. Rybakov, V.B., Aslanov, L.A., Volkov, S.V., et al. (1990) Crystal structure of the product of interaction between AuCl3 and SC12, Zh. Neorgan. Khimii 25, 2603–2609.

    Google Scholar 

  6. Rybakov, V.B., Aslanov, L.A., Volkov, S.V., et al. (1992) X-ray diffraction study of chalogen chalcogenide complexes of gold(III), Ukr. Khim. Zhurn. 58, 359–363.

    CAS  Google Scholar 

  7. Volkov, S.V., Pekhnyo, V.I., Fokina, Z.A. et al. (1996) Halogen chalcogenide complexes of osmium(IV), Polyhedron 5, 4145–4154.

    Article  Google Scholar 

  8. Beattie, I.R., and Chudzynska, H. (1967) The vibrational spectra of some chlorocomplexes of sulfur, selenium and tellurium in the (4+) oxidation state, J. Chem. Soc. A, 984–990.

    Google Scholar 

  9. Christian, B.H., Collins, M.J., and Gillespie, R.J. (1986) Preparations, Raman spectra and crystal structures of (SCl3)(SbCl6), (SeCl3)(SbCl6), (SBr1.2Cl1.8)(SbCl6), (TeCl3XAlCl4) (triclinic modification), (TeCl3XSbCl3), (TeCl3)(AsF6) and (TeF3)2(SO4), Inorg. Chem. 25, 777–778.

    Article  CAS  Google Scholar 

  10. Krebs, B., Buss, B., and Altena, D. (1971) Die Kristalstruktur von Trichlorotellur (TV) — Tetrachloraluminat TeCl3 +AlCl4 - Z. anorg. allg. Chem. 386, 257–269.

    Article  CAS  Google Scholar 

  11. Stork-Blaisse, B.A., and Romers, C. (1971) The crystal structure of AlSeCl7, Acta Cryst. 27, 386–392.

    Article  CAS  Google Scholar 

  12. Gerding, H. (1954) The application of Raman spectroscopy in the determination of structures of some complex compounds, Rec. Trav. Chim. 75, 589–593.

    Article  Google Scholar 

  13. Troyanov, S.I., Koldit, Z., and Radde, A. (1983) Die Kristallstruktur der Verbindungen [SC13][A1Cl4], Z Chem. 23, 136–137.

    Google Scholar 

  14. Doorenbos, H.E., Evans, J.C., and Kadel, R.O. (1970) Preparation, Raman and nuclear quadrupole resonance data of complex SCl3+AICl4-, J. Phys. Chem. 74, 3385–3387.

    Article  CAS  Google Scholar 

  15. Fokina, Z.A., Aslanov, L.A., Timoschenko, N.I. et al. (1988) Synthesis and structure of chlorochalcogenide complexes of platinum and palladium, Abstracts of the 1st All-Union Conference on Diffraction Methods in Chemistry, Suzdal, 197.

    Google Scholar 

  16. Alexandrova, N.G. (1991) Interpretation of vibrational spectra of chalcogenchloride complexes of platinum (IV) and osmium (IV) in crystalline state, Ukr. Khim. Zhurn. 57, 787–794.

    Google Scholar 

  17. Volkov, S.V., Pekhnyo, V.I., and Fokina, Z.A. (1981) Structure of novel chalcogen chloride complexes of Os(IV) with SeCl4 and TeCl4, Ukr. Khim. Zhurn. 47, 1020–1023.

    CAS  Google Scholar 

  18. Volkov, S.V., Pekhnyo, V.I., Fokina, Z.A. et al. (1996) Halogen chalcogenide complexes of osmium(IV), Polyhedron 5, 4145–4154.

    Article  Google Scholar 

  19. Buss, B., and Krebs, B. (1971) The crystal structure of tellurium tetrachloride, Inorg. Chem. 10, 2795–2800.

    Article  CAS  Google Scholar 

  20. Ponsioen, R., and Stufkens, D. (1971) The Raman and infrared spectra of solid TeCl4 and SeCl4, Recueil. Trav. Chim. 90, SU-528.

    Google Scholar 

  21. Kniep, R., Kozte, L., and Mootz, D. (1981) Kristall-Struktur der stabilen Modifikation von SeCl4, Z. Naturforsch. 36b, 1660–1662.

    CAS  Google Scholar 

  22. Fouerhahn, M., and Minkwitz, R. (1976) Die Infrarot-und Ramanspektren von Schwefeltetrachlorid, Z. anorg. allg. Chem. 426, 247–252.

    Article  Google Scholar 

  23. Hazell, A.C. (1966) Reinvestigation of the crystal structure of diammonium hexachlorotellurate (IV) (NH4)2TsCl6, Acta. Chem. Scand. 20, 165–169.

    Article  CAS  Google Scholar 

  24. Hendra, P.J., and Jovic, Z. (1968) The Raman spectra of some complex anions of formula [MX6]2- in the solid phase and in solution, where M = Se and Te; X = Cl, Br and I, J. Chem Soc. A., 600–602.

    Google Scholar 

  25. Abril, W. (1986) Structure of ammonium hexachloroselenate(IV), Acta Crystallogr. 42, 1113–1115.

    Google Scholar 

  26. Poulsen, F.W., and Berg, R.W. (1978) Addition compounds of sulfur, selenium or tellurium tetrachloride with niobium or tantalum pentachloride. Conductometric and Raman spectroscopy study in the molten and solid state, J. Inorg. Nucl. Chem. 40, 471–476.

    Article  CAS  Google Scholar 

  27. Poulsen, F.W. (1980) Raman study of new additional compounds of SCU, Inorg. Nucl. Chem. Lett. 16, 560–586.

    Article  Google Scholar 

  28. Gmelin (1977) Handbuch der Anorganischen Chemie, 8th Edit. Tellur 8. Auflage 2, Springer-Verlag, Berlin, pp. 67–106.

    Google Scholar 

  29. Bradley, E.B., Mathur, M.S., and Frenzel, C.A. (1967) New measurements of the infrared and the Raman spectrum of S2Cl2, J. Phys. Chem. 47, 4325–4329.

    Article  CAS  Google Scholar 

  30. Frankis, S.G., (1968) Vibrational spectra and structures of S2C12, S2Br2, Se2Cl2, J. Mol. Struct. 2, 271–279.

    Article  Google Scholar 

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Author information

Authors and Affiliations

  1. V.I. Vernadskii Institute of General and Inorganic Chemistry, Prospect Palladina 32/34, Kiev-142, 03680, Ukraine

    V. I. Pekhnyo, S. V. Volkov & N. G. Alexandrova

Authors
  1. V. I. Pekhnyo
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  2. S. V. Volkov
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  3. N. G. Alexandrova
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Editor information

Editors and Affiliations

  1. Center for Green Manufacturing, The University of Alabama, Tuscaloosa, AL, USA

    Robin D. Rogers

  2. The QUILL Research Centre, The Queen’s University of Belfast, Belfast, Northern Ireland, UK

    Kenneth R. Seddon

  3. V. Vernadsky Institute of General and Inorganic Chemistry, Ukrainian National Academy of Sciences, Kiev, Ukraine

    Sergei Volkov

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© 2003 Springer Science+Business Media Dordrecht

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Pekhnyo, V.I., Volkov, S.V., Alexandrova, N.G. (2003). Room-Temperature Sulfur Chloride Ionic Liquids in Processes for the Isolation of Noble and other Metals. In: Rogers, R.D., Seddon, K.R., Volkov, S. (eds) Green Industrial Applications of Ionic Liquids. NATO Science Series, vol 92. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0127-4_10

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  • DOI: https://doi.org/10.1007/978-94-010-0127-4_10

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-1-4020-1137-5

  • Online ISBN: 978-94-010-0127-4

  • eBook Packages: Springer Book Archive

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