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Magnetic Polyoxometalates

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Polyoxometalate Molecular Science

Part of the book series: NATO Science Series ((NAII,volume 98))

Abstract

Most of the known polyoxometalates (POMs) only contain diamagnetic transition metal ions (d0) and therefore are not interesting in magnetism. However these molecular metal-oxides are currently receiving much attention in molecular magnetism due to two important properties: (a) they can act as ligands coordinating groups of paramagnetic ions, like Co(II), Mn(II), Ni(II), Fe(II), Fe(III) and Cu(II); and (b) they can be reversibly reduced to mixed-valence species by injection of variable number of electrons. From this point of view they have shown to provide model systems to study exchange interactions and electron transfer processes at the molecular level. Recent reviews accounting for the state-of-the-art in this area can be found in [1] and [2].

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Authors and Affiliations

  1. Instituto de Ciencia Molecular (ICMol), Universidad de Valencia, C/Dr. Moliner, 50. Edificio F, 3a P, 46100, Burjassot, Spain

    J. M. Clemente-Juan, E. Coronado & A. Gaitaariño

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  1. J. M. Clemente-Juan
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  2. E. Coronado
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  3. A. Gaitaariño
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Editors and Affiliations

  1. Institute of Molecular Science (ICMol), University of Valencia, Burjassot, Spain

    Juan J. Borrás-Almenar  & Eugenio Coronado  & 

  2. Department of Chemistry, University of Bielefeld, Bielefeld, Germany

    Achim Müller

  3. Department of Chemistry, Georgetown University, Washington, DC, USA

    Michael Pope

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Clemente-Juan, J.M., Coronado, E., Gaitaariño, A. (2003). Magnetic Polyoxometalates. In: Borrás-Almenar, J.J., Coronado, E., Müller, A., Pope, M. (eds) Polyoxometalate Molecular Science. NATO Science Series, vol 98. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0091-8_9

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  • DOI: https://doi.org/10.1007/978-94-010-0091-8_9

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