Abstract
A clarification of correlation between chemical structure of polymers and their gas transport parameters is an important task in membrane science, because it promises to solve the problem of directional construction of materials having high gas permeability and selectivity. In this respect ROMP of silylnorbornenes is a suitable subject of investigation. It allows preparing series of polymers bearing regularly changed substituents located at the desired places in the polymer backbones of a different microstructure.
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Rogan, J.V., Gringolts, M.L., Ushakov, N.V., Yampolskii, Y.P., Finkelshtein, E.S. (2003). Directional Synthesis of Membrane Materials by ROMP of Silyl-Substituted Norbornadienes and Norbornenes. In: Imamoglu, Y., Bencze, L. (eds) Novel Metathesis Chemistry: Well-Defined Initiator Systems for Specialty Chemical Synthesis, Tailored Polymers and Advanced Material Applications. NATO Science Series, vol 122. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0066-6_31
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DOI: https://doi.org/10.1007/978-94-010-0066-6_31
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