Abstract
New catalytic routes for synthesis of vinylene-siloxylene-alkenylene copolymers via ADMET copolymerization of divinyltetraethoxydisiloxane with dienes (e.g., 1,9-decadiene, dihexenyl- ether and 1,4-divinylbenzene) and via tandem ROM/CM polymerization of cyclooctene with divinyltetraethoxydisiloxane as well as via silylative coupling (SC) polycondensation of divinyldisiloxanes with dienes (e.g. divinylbenzene) has been overviewed. Monovinyl(trialkoxy- and trisiloxy)silanes undergo (in the presence of Grubbs catalyst) cross-metathesis with 1,9-decadiene and/or tandem ROM/CM with cyclooctene to give, in excess of olefin, bis(silyl)dienes.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Marciniec, B. and Pietraszuk, C. Curr. Org. Chem. (2003) (in press).
Schrock, R.R., DePue, R.T., Feldman, J., Scheverin, C.J., Dewan, S.C. and Liu, A.H. (1988) J. Am. Chem. Soc. 110, 1423.
Marciniec, B. In Ring Opening Metathesis and Related Chemistry. Khosravi, E. and Szymanska-Buzar, T. Eds.; Kluwer Acad. Publ: Dordrecht, (2002) p.331–340
Wakatsuki, Y., Yamazaki, H., Nakano, M. and Yamamoto, Y. (1991) J. Chem. Soc. Chem. Commun. 703
Marciniec, B. and Pietraszuk, C. (1997) Organometallics. 16, 4320
Marciniec, B. (2000) Molecular Crystal & Liquid Crystals. 353–354, 173
Marciniec, B. and Lewandowski, M. (1996) J. Polym. Sci. Part A, Polym. Chem. 34, 1443
Marciniec, B. and Lewandowski, M. (1995) J. Inorg. & Organometal. Polym. 15, 115
Marciniec, B. and Malecka, E. (1999) Macromolecular Rapid Commun. 20, 475
Marciniec, B., Lewandowski, M., Bijpost, E., Malecka, E., Kubicki, M. and Walczuk-Gusciora, E. (1999) Organometallics. 18, 3968
Marciniec, B. and Malecka, E. Macromolecules. (submitted for publication)
Marciniec, B., Malecka, E., Majchrzak, M. and Itami, Y. (2001) Macromol. Symp. 174, 137.
Mise, T., Takaguchi, Y., Umemiya, T., Shimizu, S. and Wakatsuki, Y. (1998) Chem. Commun. 699.
Alkene Metathesis in Organic Synthesis, Fürstner, A. Ed., Springer: Berlin, 1998
Ivin, K.J.; Mol. J.C. Olefin Metathesis and Metathesis Polymerization, Academic Press: San Diego, 1997
Fürstner, A. (2000) Angew. Chem., 112, 3140; Angew. Chem., Int. Ed. 2000, 39, 3012.
Chang, S. and Grubbs, R.H. (1997) Tetrahedron Lett. 38, 4757.
Denmark, S.E. and Yang, S.M. (2001) Org. Lett. 3, 1749.
Pietraszuk, C., Marciniec, B. and Jankowska, M. (2002) Adv. Synth. Catal. 344, 789.
Pietraszuk, C., Marciniec, B. and Fischer, H. (2000) Organometallics. 19, 913
Majchrzak, M., Itami, Y., Marciniec, B. and Pawluc, P. (2000) Tetrahedron Lett. 41, 10303.
Malecka, E., Marciniec, B., Pietraszuk, C., Church, A.C. and Wagener, K. (2002) J. Mol. Catal. 190, 27.
Wagener, K.B. and Smith, Jr. D.W. (1991) Macromolecules. 24, 6073.
Malecka, E., Pawluc, P. and Marciniec, B. (unpublished results).
Marciniec, B. and Majchrzak, M. J. Organometal. Chem. (submitted for publication).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2003 Springer Science+Business Media Dordrecht
About this paper
Cite this paper
Marciniec, B. (2003). Metathetical Conversion and Silylative Coupling of Alkadienes and Cycloalkenes with Mono- and Divinylsilicon Compounds. In: Imamoglu, Y., Bencze, L. (eds) Novel Metathesis Chemistry: Well-Defined Initiator Systems for Specialty Chemical Synthesis, Tailored Polymers and Advanced Material Applications. NATO Science Series, vol 122. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0066-6_3
Download citation
DOI: https://doi.org/10.1007/978-94-010-0066-6_3
Publisher Name: Springer, Dordrecht
Print ISBN: 978-1-4020-1571-7
Online ISBN: 978-94-010-0066-6
eBook Packages: Springer Book Archive