Intramolecular Trapping of Strained Bicyclic Allene in Carbon Atom Reactions

  • Fatma Sevİn
  • Bülent Düz
Conference paper
Part of the NATO Science Series book series (NAII, volume 122)

Abstract

We report here the intermolecular trapping of endo-bicyclo[3.2.1]octa-2,3-dien-6-ol generated by reacting C with endo-bicyclo[2.2.1]hept-5-en-2-ol. The fragmentation reaction through endo-bicyclo[3.2.1]octa-2,3-dien-6-ol favours product (5Z)-octa-1,5dien-7-yn-3-ol rather than the intramolecular trapping product 2-oxatricyclo [4.2.1.03,8] non-4-ene. We also describe this reaction theoretically by means of the AM1 semiempirical method.

Keywords

Graphite Chloroform Aldehyde Turkey Carbene 

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Copyright information

© Springer Science+Business Media Dordrecht 2003

Authors and Affiliations

  • Fatma Sevİn
    • 1
  • Bülent Düz
    • 1
  1. 1.Department of ChemistryHacettepe UniversityBeytepe-AnkaraTurkey

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