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Acyclic Diyne Metathesis Condensation of 3-ALKYL-2,5-DI (1-Propynyl)-Thiophenes

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Novel Metathesis Chemistry: Well-Defined Initiator Systems for Specialty Chemical Synthesis, Tailored Polymers and Advanced Material Applications

Part of the book series: NATO Science Series ((NAII,volume 122))

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Summary

The Schrock Type tungsten(VI) carbyne complex (tBuO)3W=CtBu catalyzes the Acyclic Diyne Methasesis Condensation (ADIMET) of conjugated and nonconjugated diynes. Substituted conjugated monomers formed polymers with conjugated C啡C-bonds. These products possess very interesting optical and electronic qualities. Especially the synthesis of poly(phenylene) ethynylenes (PPE) und poly(thiophenylene) ethynylenes (PTE) were studied.

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Author information

Authors and Affiliations

  1. Department of Chemistry I, University of Bayreuth, D-95440, Bayreuth, Germany

    Karin Weiss, Armin Michel & Katrin Sattler

Authors
  1. Karin Weiss
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  2. Armin Michel
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  3. Katrin Sattler
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Editor information

Editors and Affiliations

  1. Department of Chemistry, Hacettepe University Beytepe, Ankara, Turkey

    Y. Imamoglu

  2. Department of Organic Chemistry, University of Veszprem, Veszprem, Hungary

    L. Bencze

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© 2003 Springer Science+Business Media Dordrecht

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Weiss, K., Michel, A., Sattler, K. (2003). Acyclic Diyne Metathesis Condensation of 3-ALKYL-2,5-DI (1-Propynyl)-Thiophenes. In: Imamoglu, Y., Bencze, L. (eds) Novel Metathesis Chemistry: Well-Defined Initiator Systems for Specialty Chemical Synthesis, Tailored Polymers and Advanced Material Applications. NATO Science Series, vol 122. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0066-6_24

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  • DOI: https://doi.org/10.1007/978-94-010-0066-6_24

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-1-4020-1571-7

  • Online ISBN: 978-94-010-0066-6

  • eBook Packages: Springer Book Archive

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