Abstract
Dienes can undergo olefin metathesis reactions of two types: (i) intermolecular, and (ii) intramolecular. Intramolecular metathesis (RCM) reactions occur with great readiness henever the product is a 6-membered ring. They are also often favoured for the production of 5-, 7-, and 8-membered rings, depending on the nature, number and location of any substituents. Intermolecular metathesis reactions lead eventually to high polymers and proceed very cleanly when initiated by metal carbene complexes; these are known as ADMET (acyclic diene metathesis) polymerizations (Figure 1). This class of polymerization reactions has been well established and comprehensively studied by Wagener and his group [1–6]. ADMET polymerization has been also a convenient route to linear polymers containing inorganic elements and functional groups for the preparation of new materials [7].
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Lindmark-Hamberg, M., Wagener, K.B. (1987) Macromolecules 24, 2649.
Wagener, K.B., Boncella, J.M., Nel J.G., Duttweiler R.P., Hillmyer, M.A. (1990) Macromol. Chem. 191, 365.
Wagener, K.B., Nel, J.G., Konzelman, J., Boncella, J.M. (1990) Macromolecules 23, 5155.
Wagener, K.B., Boncella, J.M., Nel, J.G. (1991) Macromolecules 24, 2649.
Konzelman, J., Wagener, K.B. (1996) Macromolecules 29,7657.
Wagener, K.B., Brzezinska, K., Anderson, J.D., Dilocker, S.J. (1997) Polym. Sci. A35, 3441.
Wagener, K.B. Formation of Hydrocarbon and Functionalized Polymers by ADMET Polymerization. In Metathesis Polymerization of Olefins and Polymerization of Alkynes, Imamoğlu Y (ed.). (1998) NATO ASI Series C506, Kluwer Academic Publishers: Dordrecht, 277–296.
Gilet, M., Mortreux, A., Nicole, J., Petit, F. (1979) J. Chem. Soc. Chem. Commun. 521.
Gilet, M., Mortreux, A., Folest, J.C., Petit, F. (1983) J. Am. Chem. Soc. 105, 3876.
Dereli, O., Düz, B., Zümreoğlu-Karan, B. and Imamoğlu, Y. (2003) Appl. Organometal. Chem. 17, 23–27.
Çetinkaya, S., Düz, B. and Imamoğlu, Y. (2003) Appl. Organometal. Chem. 17, 232–235.
Uchida, A., Hamano, Y., Mukai, Y. and Masuda, S. (1971) Ind. Eng. Chem. Prod. Res. Develop. 10, 372.
Calderon, N., Ofstead, E.A., Ward, J.P., Judy, W.A. and Scott, K.W. (1968) J. Am. Chem. Soc. 90, 4133.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2003 Springer Science+Business Media Dordrecht
About this paper
Cite this paper
Derelİ, O., Düz, B., İmamoğlu, Y. (2003). Acyclic Diene Metathesis (ADMET) Polymerization by Electrochemically Generated Tungsten-Based Active Catalyst System: Optimization of Reaction Conditions. In: Imamoglu, Y., Bencze, L. (eds) Novel Metathesis Chemistry: Well-Defined Initiator Systems for Specialty Chemical Synthesis, Tailored Polymers and Advanced Material Applications. NATO Science Series, vol 122. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0066-6_20
Download citation
DOI: https://doi.org/10.1007/978-94-010-0066-6_20
Publisher Name: Springer, Dordrecht
Print ISBN: 978-1-4020-1571-7
Online ISBN: 978-94-010-0066-6
eBook Packages: Springer Book Archive