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Novel Metathesis Chemistry: Well-Defined Initiator Systems for Specialty Chemical Synthesis, Tailored Polymers and Advanced Material Applications pp 179–189Cite as

The Incorporation of Amino Acids into Polymers ADMET

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Part of the book series: NATO Science Series ((NAII,volume 122))

Abstract

Amino acid based polymers are of interest for a variety of biomaterial applications including drug delivery, proteomics, and tissue engineering. A new class of polymers bearing amino acids has been prepared using acyclic diene metathesis (ADMET) to create copolymers of polyethylene with linear amino alcohol, branched amino acid, or branched dipeptide substituents. The synthesis of the monomers and the polymerization using the second generation Grubbs’ ruthenium catalyst is discussed. The resulting highly functionalized polymers are strong, film-forming materials (moduli up to 220 mPa with up to 260 % elongation) with molecular weights typical of polycondensation polymers, i.e. Nylon and PET.

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Author information

Authors and Affiliations

  1. Dept of Chemistry, University of Florida, P.O. Box 117200, Gainesville, Fl, 32611-7200, USA

    Timothy E. Hopkins, Joshua M. Priebe & Kenneth B. Wagener

Authors
  1. Timothy E. Hopkins
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  2. Joshua M. Priebe
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  3. Kenneth B. Wagener
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Editor information

Editors and Affiliations

  1. Department of Chemistry, Hacettepe University Beytepe, Ankara, Turkey

    Y. Imamoglu

  2. Department of Organic Chemistry, University of Veszprem, Veszprem, Hungary

    L. Bencze

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© 2003 Springer Science+Business Media Dordrecht

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Hopkins, T.E., Priebe, J.M., Wagener, K.B. (2003). The Incorporation of Amino Acids into Polymers ADMET. In: Imamoglu, Y., Bencze, L. (eds) Novel Metathesis Chemistry: Well-Defined Initiator Systems for Specialty Chemical Synthesis, Tailored Polymers and Advanced Material Applications. NATO Science Series, vol 122. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0066-6_14

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  • DOI: https://doi.org/10.1007/978-94-010-0066-6_14

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-1-4020-1571-7

  • Online ISBN: 978-94-010-0066-6

  • eBook Packages: Springer Book Archive

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