Skip to main content

Part of the book series: NATO Science Series ((NAIV,volume 27))

Abstract

Absorption spectra of pure CO2 have been recorded in the vicinity of the 2675 cm-1 Fermi triad for temperatures between 211 K and 296 K. The 2ν 1, ν 1 + 2ν 2 , 2ν 2 collision-induced components have been extracted from the measured spectra, including for the low frequency band at 2547 cm-1, which is strongly masked by the v 3 wing absorption. Dimeric features are clearly seen on top of the structureless profiles. Integrated intensities of the Fermi-triad components are deter- mined as a function of temperature.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Mannyk, L. and Stryland, J. C. (1972) The ν 1 band of carbon dioxide in pressure-induced absorption. II. Density and temperature dependence of the in-tensity; Critical phenomena, Can. J. Phys., 50, 1355–1362.

    Google Scholar 

  2. Baranov, Y. I. and Vigasin, A. A. (1999) Collision-induced absorption by CO2 in the region of ν1, 2ν2 J. Molec. Spectrosc., 193, 319–325.

    Article  Google Scholar 

  3. Vigasin, A. A., Baranov, Y. I., and Chlenova, G. V. (2002) Temperature variations of the interaction induced absorption of CO2 in the ν1, 2ν2 region: FTIR measurements and dimer contribution, J. Molec. Spectrosc., 213, 51–56.

    Article  Google Scholar 

  4. Rothman, L. S., Rinsland, C. P., Goldman, A., Massie, S. T., Edwards, D. P., Flaud, J.-M., Perrin, A., Camy-Peyret, C, Dana, V., Mandin, J.-Y., Schroeder, J., Mccann, A., Gamache, R. R., Wattson, R. B., Yoshino, K., Chance, K.V., Jucks, K.W., Brown, L.R., Nemtchinov, V., and Varanasi, P. (1998) The HITRAN molecular spectroscopic database and HAWKS (HITRAN Atmospheric Workstation): 1996 Edition, JQSRT, 60, 665–710.

    Article  Google Scholar 

  5. Thomas, M. E. and Linevsky, M. J. (1989) Integrated intensities of N2, CO2, and SF6 vibrational bands from 1800 to 5000 cm-1 as a function of density and temperature, JQSRT, 42, 465–476.

    Article  Google Scholar 

  6. Adiks, T. G. (1982) Experimental Study of the CO2 IR Absorption Spectra as Applied to the Windows of Transparency of Venusian Atmosphere. Ph. D. Thesis, Institute of Atmospheric Physics, USSR Academy of Sciences, Moscow (in Russian).

    Google Scholar 

  7. Bouanich, J.-P. (1992) Site-site Lennard—Jones potential parameters for N2, O2, H2, CO, and CO2, JQSRT, 47, 243–250.

    Article  Google Scholar 

  8. Vigasin, A. A. (1996) On the nature of collision-induced absorption in gaseous homonuclear diatomics, JQSRT, 56, 409–422.

    Article  Google Scholar 

  9. Vigasin, A. A. (2000) Collision-induced absorption in the region of the O2 fundamental: Bandshapes and dimeric features, J. Molec. Spectrosc., 202, 59–66.

    Article  Google Scholar 

  10. Vigasin, A. A. (2003) Bimolecular absorption in atmospheric gases, this volume, pp. 23–47.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2003 Springer Science+Business Media Dordrecht

About this paper

Cite this paper

Baranov, Y.I., Fraser, G.T., Lafferty, W.J., Vigasin, A.A. (2003). Collision-Induced Absorption in The CO2 Fermi Triad for Temperatures from 211K to 296 K. In: Camy-Peyret, C., Vigasin, A.A. (eds) Weakly Interacting Molecular Pairs: Unconventional Absorbers of Radiation in the Atmosphere. NATO Science Series, vol 27. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0025-3_12

Download citation

  • DOI: https://doi.org/10.1007/978-94-010-0025-3_12

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-1-4020-1596-0

  • Online ISBN: 978-94-010-0025-3

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics