Abstract
Absorption spectra of pure CO2 have been recorded in the vicinity of the 2675 cm-1 Fermi triad for temperatures between 211 K and 296 K. The 2ν 1, ν 1 + 2ν 2 , 2ν 2 collision-induced components have been extracted from the measured spectra, including for the low frequency band at 2547 cm-1, which is strongly masked by the v 3 wing absorption. Dimeric features are clearly seen on top of the structureless profiles. Integrated intensities of the Fermi-triad components are deter- mined as a function of temperature.
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References
Mannyk, L. and Stryland, J. C. (1972) The ν 1 band of carbon dioxide in pressure-induced absorption. II. Density and temperature dependence of the in-tensity; Critical phenomena, Can. J. Phys., 50, 1355–1362.
Baranov, Y. I. and Vigasin, A. A. (1999) Collision-induced absorption by CO2 in the region of ν1, 2ν2 J. Molec. Spectrosc., 193, 319–325.
Vigasin, A. A., Baranov, Y. I., and Chlenova, G. V. (2002) Temperature variations of the interaction induced absorption of CO2 in the ν1, 2ν2 region: FTIR measurements and dimer contribution, J. Molec. Spectrosc., 213, 51–56.
Rothman, L. S., Rinsland, C. P., Goldman, A., Massie, S. T., Edwards, D. P., Flaud, J.-M., Perrin, A., Camy-Peyret, C, Dana, V., Mandin, J.-Y., Schroeder, J., Mccann, A., Gamache, R. R., Wattson, R. B., Yoshino, K., Chance, K.V., Jucks, K.W., Brown, L.R., Nemtchinov, V., and Varanasi, P. (1998) The HITRAN molecular spectroscopic database and HAWKS (HITRAN Atmospheric Workstation): 1996 Edition, JQSRT, 60, 665–710.
Thomas, M. E. and Linevsky, M. J. (1989) Integrated intensities of N2, CO2, and SF6 vibrational bands from 1800 to 5000 cm-1 as a function of density and temperature, JQSRT, 42, 465–476.
Adiks, T. G. (1982) Experimental Study of the CO2 IR Absorption Spectra as Applied to the Windows of Transparency of Venusian Atmosphere. Ph. D. Thesis, Institute of Atmospheric Physics, USSR Academy of Sciences, Moscow (in Russian).
Bouanich, J.-P. (1992) Site-site Lennard—Jones potential parameters for N2, O2, H2, CO, and CO2, JQSRT, 47, 243–250.
Vigasin, A. A. (1996) On the nature of collision-induced absorption in gaseous homonuclear diatomics, JQSRT, 56, 409–422.
Vigasin, A. A. (2000) Collision-induced absorption in the region of the O2 fundamental: Bandshapes and dimeric features, J. Molec. Spectrosc., 202, 59–66.
Vigasin, A. A. (2003) Bimolecular absorption in atmospheric gases, this volume, pp. 23–47.
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Baranov, Y.I., Fraser, G.T., Lafferty, W.J., Vigasin, A.A. (2003). Collision-Induced Absorption in The CO2 Fermi Triad for Temperatures from 211K to 296 K. In: Camy-Peyret, C., Vigasin, A.A. (eds) Weakly Interacting Molecular Pairs: Unconventional Absorbers of Radiation in the Atmosphere. NATO Science Series, vol 27. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0025-3_12
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DOI: https://doi.org/10.1007/978-94-010-0025-3_12
Publisher Name: Springer, Dordrecht
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