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On Green’s Function Methods for the Study of Ionic States in Atoms and Molecules

  • W. von Niessen
  • L. S. Cederbaum
  • W. Domcke
Chapter
Part of the NATO Advanced Study Institutes Series book series (ASIC, volume 46)

Abstract

Photoelectron spectroscopy is concerned with the study of ionic states in atoms, molecules and solids. It has developed to become a very useful tool for the understanding of the electronic structure of the system. Actually it is not just a single type of spectroscopy but represents rather a spectrum of spectroscopies. The incident radiation may be varied both in type and energy. The most frequent excitation sources are UV radiation (HeI line at 21.21eV, HeII line at 40.8eV, X-rays of various energies and nowadays also synchroton radiation as well as electrons ((e,2e)-spectroscopy) or excited atoms (Penning ionization). The electrons and/or ions formed in the process can be spectro-scopically examined. There also exists the possibility of coincidence measurements which may supply additional data. The photoelectron spectrum (PES) contains a lot of information. There are the different electronic states, each ionization process giving rise to a band. These bands show vibrational and rotational structure in the case of molecules.

Keywords

Ionic State Vibrational Structure Dyson Equation Satellite Line Pole Strength 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© D. Reidel Publishing Company, Dordrecht, Holland 1978

Authors and Affiliations

  • W. von Niessen
    • 1
  • L. S. Cederbaum
    • 2
  • W. Domcke
    • 2
  1. 1.Theoretische Chemie, Institut für Physikalische ChemieTechnische Universität BraunschweigD-33 BraunschweigW.-Germany
  2. 2.Fakultät für PhysikUniversität FreiburgD-78 FreiburgW.-Germany

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