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Pulse Techniques and Nuclear Spin Relaxation

  • Conference paper
ESR and NMR of Paramagnetic Species in Biological and Related Systems

Part of the book series: Nato Advanced Study Institutes Series ((ASIC,volume 52))

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Abstract

This chapter is intended to familiarize the reader with the basics of nuclear spin relaxation in liquids from a dynamic, mechanistic and experimental point of view. Besides a treatment of the various mechanisms inducing relaxation, it shall be shown how the latter are separated and interpreted. Some consideration will also be given to the implications of exchange processes on relaxation rates. Additionally, some of the more elaborate pulse techniques related to relaxation, including selective excitation and two-dimensional resolved spectroscopy are presented.

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References

  1. See for example Lyerla, J.R., and Grant, D.M.: in “International Review of Science,Phys. Chem. Series”, Mc Dowell, C.A., Ed., Vol. 4, Chap. 5, Medical and Technical Publ. Comp., 1972; Lyerla, J.R. Jr., and Levy G.C., in “Topics in Carbon-13 NMR Spectroscopy”, Levy, G.C., Ed., Chap. 3, Wiley Interscience, 1974.

    Google Scholar 

  2. Abragam, A.: “The Principles of Nuclear Magnetism” Chap.8, Oxford, 1961.

    Google Scholar 

  3. Noggle, J.H., and Schirmer, R.E.: “The Nuclear Overhauser Effect”, Chaps. 1 and 6, Academic Press, 1971.

    Google Scholar 

  4. Allerhand, A., Doddrell, D., and Komoroski, R.: 1971, J. Chem. Phys. 55, pp. 189.

    Article  CAS  Google Scholar 

  5. Lyerla, J.R., Jr., Grant, D.M., and Harris, R.K., 1971: J. Phys. Chem. 75, 585.

    Article  Google Scholar 

  6. Alger, T.D., Grant, D.M., and Lyerla, J.R.,Jr.: J. Phys. Chem. 75, 2539.

    Google Scholar 

  7. Deslauriers, R., Smith, I.C.P., and Walter, R., 1974: J. Amer. Chem. Soc. 96, 2289.

    Article  CAS  Google Scholar 

  8. Wehrli, F.W., 1976: J. Magn. Res. 23, 181.

    CAS  Google Scholar 

  9. Spiess, H.W., Schweitzer, D., Haeberlen, U., and Hausser, K.H., 1971: J. Magn. Res. 5, 101.

    CAS  Google Scholar 

  10. Levy, G.C., Cargioli, J.D., and Anet, F.A.L., 1973: J. Amer. Chem. Soc. 95, 1527.

    Article  CAS  Google Scholar 

  11. Wehrli, F.W., 1979: J. Magn. Res. 32, 451.

    Google Scholar 

  12. Tarasov, V.P., Privalov, V.I., and Buslaev, Yu. A., 1977: Dokl. Akad. Nauk SSSR 234, 636.

    CAS  Google Scholar 

  13. See for example Lindman, B., and Forsén, S., “Chlorine, Bromine and Iodine NMR, Physico-chemical and Biological Applications” in “NMR, Basic Principles and Progress”, Diehl P., Fluck, E., and Kosfeld R., Eds., Springer, 1976.

    Google Scholar 

  14. Mann, B.K., and Harris, R.K., “NMR and the Periodic Table” Chap. 6, Academic Press, 1978.

    Google Scholar 

  15. Shchori, E., Jagur-Grodzinski, J., and Shporer, M., 1973: J. Amer. Chem. Soc. 95, 3842.

    Article  CAS  Google Scholar 

  16. Vold, R.L., Waugh, J.S., Klein, M.P., and Phelps, D.E., 1968: J. Chem. Phys. 48, 3831.

    Article  CAS  Google Scholar 

  17. Freeman R. & Hill H.D.W., 1971: J. Chem. Phys. 54, 3367.

    Article  CAS  Google Scholar 

  18. Canet, D., Levy, G.C., and Peat, I.R., 1975: J. Magn. Res. 18, 199.

    CAS  Google Scholar 

  19. McDonald, G.C., and Leigh, J.S.Jr., 1973: J. Magn. Res. 9, 358.

    CAS  Google Scholar 

  20. S. Patt, priv. commun.

    Google Scholar 

  21. Freeman, R., and Hill, H.D.W., in “Dynamic Nuclear Magnetic Resonance”, Cotton, F.A., and Jackiran, L.M., Eds., Chap. 5, Academic Press 1975.

    Google Scholar 

  22. Carr, H.Y., and Purcell, E.M., 1954: Phys. Rev. 94, 630.

    Article  CAS  Google Scholar 

  23. Freeman, R., Hill, H.D.W., and Kaptein, R., 1972: J. Magn. Res. 7, 327.

    CAS  Google Scholar 

  24. Canet, D., 1976: J. Magn. Res. 23, 361.

    CAS  Google Scholar 

  25. Opella, S.J., Nelson, D.J., and Jardetzky, O., 1976: J. Chem. Phys. 64, 2533.

    Article  CAS  Google Scholar 

  26. Hall, L.D., and Hill, H.D.W., 1976: J. Amer. Chem. Soc. 98, 1269.

    Article  CAS  Google Scholar 

  27. Hall, L.D,, and Hull, W.E., private carrmun.

    Google Scholar 

  28. Tbmlinson, B.L., and Hill, H.D.W., 1973: J. Chem. Phys. 59, 1775.

    Article  Google Scholar 

  29. Freeman, F., Hill, H.D.W., Tomlinson, B.L., and Hall, L.D., 1974: J. Chem. Phys. 61, 4466.

    Article  CAS  Google Scholar 

  30. Morris, G.A., and Freeman, R., 1978: J. Magn. Res. 29, 433.

    CAS  Google Scholar 

  31. Forsén, S., and Hoffmann, R.A., 1963: J. Chem. Phys. 39, 2892.

    Article  Google Scholar 

  32. Aue, W.P., Bartholdi, E., and Ernst, R.R., 1976: J. Chem. Phys. 64, 2229.

    Article  CAS  Google Scholar 

  33. Jeener, J., Ampère International Summer School II, Basko Polje, 1971.

    Google Scholar 

  34. Freeman, R., and Hill, H.D.W., 1971: J. Chem. Phys. 54, 301 (1971).

    Article  CAS  Google Scholar 

  35. Bartholdi, E., 1979: Private communication.

    Google Scholar 

  36. Nagayama, K., Wüthrich, K., Bachmann, P., and Ernst, R.R., 1977: Biochem. Biophys. Res. Commun. 78, 99.

    Article  CAS  Google Scholar 

  37. Nagayama, K., Bachmann, P., Wüthrich, K., and Ernst, R.R., 1978: J. Magn. Res. 31, 133.

    CAS  Google Scholar 

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Author information

Authors and Affiliations

  1. Bruker Instruments, Inc., Manning Park, Billerica, Mass., 01821, USA

    Felix W. Wehrli

Authors
  1. Felix W. Wehrli
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Editor information

Editors and Affiliations

  1. Istituto di Chimica Generale ed Inorganica della, Facoltà di Farmacia, Università di Firenze, Via Gino Capponi, 7 Firenze, Italy

    Ivano Bertini

  2. School of Chemical Sciences, University of Illinois at Urbana-Champaign, Urbana, Illinois, 61801, USA

    Russell S. Drago

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© 1980 D. Reidel Publishing Company, Dordrecht, Holland

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Wehrli, F.W. (1980). Pulse Techniques and Nuclear Spin Relaxation. In: Bertini, I., Drago, R.S. (eds) ESR and NMR of Paramagnetic Species in Biological and Related Systems. Nato Advanced Study Institutes Series, vol 52. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-9524-6_1

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  • DOI: https://doi.org/10.1007/978-94-009-9524-6_1

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-009-9526-0

  • Online ISBN: 978-94-009-9524-6

  • eBook Packages: Springer Book Archive

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