Abstract
The “Continuous Flow Method with Integrating Observation”, CFMIO, is described, which uses a very fast jet mixer and incorporates this mixing chamber into the observation tube. To increase the detection path length up to some cm and to bring the mixing area into the detection region, the steady state of reaction is followed in the direction of flow. The mixing process is examined and integrated rate equations are given to determine the rate constants of first and second order reversible, as well as irreversible, reactions. The time resolution of the CFMIO is demonstrated by measuring half lives of very fast electron transfer reactions as low as 5 × 10-6s.
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Holzwarth, J.F. (1979). Fast Continuous Flow. In: Gettins, W.J., Wyn-Jones, E. (eds) Techniques and Applications of Fast Reactions in Solution. NATO Advanced Study Institutes Series, vol 50. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-9490-4_2
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DOI: https://doi.org/10.1007/978-94-009-9490-4_2
Publisher Name: Springer, Dordrecht
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