High-Resolution Temperature-Jump Measurements Using Cooling-Correction

  • Carl-Roland Rabl
Conference paper
Part of the NATO Advanced Study Institutes Series book series (ASIC, volume 50)

Abstract

Cooling of the sample after a temperature-jump results in a methodic error of the temperature-jump method in the ms- and sec-time range, especially when studying multiple relaxation phenomena and using micro or semi-micro sample cells. The cooling process has been studied both theoretically and experimentally using HV-conductivity heating and detection of optical absorption and fluorescence. An electronic signal correction circuit has been developed.

Keywords

Convection Tungsten Choline Convolution Acetylcholine 

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References

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    F.Kohlrausch, Praktische Physik, Vol.3, 22.ed. Stuttgart 1968Google Scholar
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    H.S.Carslaw and J.C.Jaeger, Conduction of Heat in Solids, 2.ed., Clarendon Press, Oxford 1973Google Scholar
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    C.R.Rabl, Lecture at 1.Meeting on “Fast Reactions in Solution” Cranfield/U.K. September 1977Google Scholar
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    R.Rigler, C.R.Rabl, and T.Jovin, Rev.Sci.Instr. 45 (1974), 580CrossRefGoogle Scholar
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Copyright information

© D. Reidel Publishing Company 1979

Authors and Affiliations

  • Carl-Roland Rabl
    • 1
  1. 1.Max-Planck-Institut für BiochemieMartinsried/MunichW.-Germany

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