Abstract
Cooling of the sample after a temperature-jump results in a methodic error of the temperature-jump method in the ms- and sec-time range, especially when studying multiple relaxation phenomena and using micro or semi-micro sample cells. The cooling process has been studied both theoretically and experimentally using HV-conductivity heating and detection of optical absorption and fluorescence. An electronic signal correction circuit has been developed.
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References
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© 1979 D. Reidel Publishing Company
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Rabl, CR. (1979). High-Resolution Temperature-Jump Measurements Using Cooling-Correction. In: Gettins, W.J., Wyn-Jones, E. (eds) Techniques and Applications of Fast Reactions in Solution. NATO Advanced Study Institutes Series, vol 50. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-9490-4_10
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DOI: https://doi.org/10.1007/978-94-009-9490-4_10
Publisher Name: Springer, Dordrecht
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