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Organometallics of the f-Elements pp 467–496Cite as

Vibrational Spectroscopy of Some Organometallic Compounds of Actinides

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Part of the book series: NATO Advanced Study Institutes Series ((ASIC,volume 44))

Abstract

Although vibrational spectroscopy ranks as a secondary method for precise structural studies1, it is still very useful because of its convenience and its wide applicability. In reality, there are practically no limitationsto the utilization of infrared spectroscopy and only a few limitations to Raman spectroscopy; experimental difficulties are caused by the fluorescence and the color of some samples. Both methods can be applied to liquids, solutions, gases, solids (crystals or powder) and independently of the magnetic characteristics of the actinide element present in the compound. For radiochemists, it is very easy to avoid contamination during the preparation of the samples when radioactive materials are handled and the majority of the measurements can be made in a small box with optical windows without risk of contamination of the spectrometer.

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Authors and Affiliations

  1. Laboratory of Radiochemistry, University of Liège Sart Tilman, B-4000, Liège, Belgium

    Jean Goffart

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  1. Jean Goffart
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Editors and Affiliations

  1. Department of Chemistry, Northwestern University, Evanston, Illinois, 60201, USA

    Tobin J. Marks

  2. Institut für Anorganische und Angewandte Chemie, Universität Hamburg, Martin-Luther-King Platz 6, D-2000, Hamburg 13, West Germany

    R. Dieter Fischer

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© 1979 D. Reidel Publishing Company, Dordrecht, Holland

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Goffart, J. (1979). Vibrational Spectroscopy of Some Organometallic Compounds of Actinides. In: Marks, T.J., Fischer, R.D. (eds) Organometallics of the f-Elements. NATO Advanced Study Institutes Series, vol 44. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-9454-6_15

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  • DOI: https://doi.org/10.1007/978-94-009-9454-6_15

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