Skip to main content
SpringerLink
Log in

The First Row Transition Metal Intercalation Complexes of Some Metallic Group VA Transition Metal Dichalcogenides

  • Chapter
Book cover Intercalated Layered Materials

Part of the book series: Physics and Chemistry of Materials with Layered Structures ((PCMA,volume 6))

Abstract

Materials with layer structures, for which the bonding between the layers is of the weak van der Waals type, offer a unique opportunity for obtaining information about their electronic properties and energy band structures via experiments involving the process of intercalation. ‘Intercalation’ means insertion or interpositioning of foreign ions, atoms or molecules between the layers of these materials, a process only made possible by the weakness of the interlayer bonding. The size of the inter-layer gap may either increase or decrease upon intercalation, depending upon the size of the intercalated system and the nature of any bonding mechanism between this system and the host layers. The intercalate may display either random distribution or ordered occupation with respect to the available interlayer lattice sites.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. F. R. Gamble, J. H. Osiecki, M. Cais, R. Pisharody, F. J. di Salvo and T. H. Geballe Science 174 (1971) 493.

    Article  CAS  Google Scholar 

  2. F. J. di Salvo, R. Schwall, T. H. Geballe, F. R. Gamble and J. H. Osiecki, Phys. Rev. Lett. 27 (1971)

    Article  Google Scholar 

  3. W. B. Clark, J. Phys. C; Solid St. Phys. 9 (1976) L 693.

    Article  Google Scholar 

  4. R. F. Frindt, Phys. Rev. Lett. 28 (1972) 299

    Article  CAS  Google Scholar 

  5. V. L. Ginzburg and D. A. Kirzhmtz, Sov. Phys. JETP 19 (1964) 269;

    Google Scholar 

  6. J. V. Acrivos, W. Y. Liang, J. A. Wilson and A. D. Yoffe, J. Phys. C; Solid St. Phys. 4 (1971) L18.

    Article  CAS  Google Scholar 

  7. R. E. Grim, Clay Mineralogy, McGraw Hill, New York (1968).

    Google Scholar 

  8. L. C. F. Blackman, J. F. Mathews and A. R. Ubbelohde, Proc. Roy. Soc. 256A (1959) 15.

    Google Scholar 

  9. D. E. Nixon and G. S. Parry, J. Phys. D; Applied Phys. 1 (1968) 291.

    Article  CAS  Google Scholar 

  10. N. B. Hannay, T. H. Geballe, B. T. Matthias, K. Andres, P. Schmidt and D. MacNair, Phys. Rev. Lett. 14 (1965) 225.

    Article  CAS  Google Scholar 

  11. J. J. Murray and A. R. Ubbelohde, Proc. Roy. Soc. 312A (1969) 371.

    Article  CAS  Google Scholar 

  12. G. R. Henning, J. Chem. Phys. 43 (1965) 1201.

    Google Scholar 

  13. F. R. Gamble, J. H. Osiecki and F. J. di Salvo, J. Chem. Phys. 55 (1971) 3525.

    Article  CAS  Google Scholar 

  14. T. H. Geballe, A. Menth, F. J. di Salvo and F. R. Gamble, Phys. Rev. Lett. 27 (1971) 314.

    Article  CAS  Google Scholar 

  15. F. R. Gamble, F. J. di Salvo, R. A. Klemm and T. H. Geballe, Science 168 (1970) 568.

    Article  CAS  Google Scholar 

  16. R. B. Somoano and A. Rembaum, Phys. Rev. Lett. 27 (1971) 402.

    Article  CAS  Google Scholar 

  17. R. B. Somoano, V. Hadek and A. Rembaum, J. Chem. Phys. 58 (1973) 697.

    Article  CAS  Google Scholar 

  18. H. E. Barz, A. S. Cooper, E. Corenzwit, M. Marezio, B. T. Matthias and P. H. Schmidt, Science 175 (1972) 884.

    Article  CAS  Google Scholar 

  19. G. V. Subba Rao, M. W. Schafer, S. Kawarazaki and A. M. Toxen, J. Sol. St. Chem. 9 (1974) 323.

    Article  Google Scholar 

  20. R. B. Somoano, V. Hadek, A. Rembaum, S. Samson and J. A. Woollam, J. Chem. Phys. 62 (1975) 1068.

    Article  CAS  Google Scholar 

  21. W. B. Clark and P. M. Williams, Phil. Mag. 35 (1977) 883.

    Article  CAS  Google Scholar 

  22. A. H. Thompson, F. R. Gamble and R. F. Koehler, Phys. Rev. B5 (1972) 2811.

    Article  Google Scholar 

  23. K. Selte and A. Kjekshus, Acta Chem. Scand. 18 (1964) 697.

    Article  CAS  Google Scholar 

  24. F. Kadijk and F. Jellinek, Thesis, Gronigen, Netherlands.

    Google Scholar 

  25. G. Lucovsky, R. M. White, W. Y. Liang and J. C. Mikkelsen, Phil. Mag. 33 (1976) 907.

    Article  Google Scholar 

  26. M. H. van Maaren and G. M. Schaeffer, Phys. Lett. 20 (1966) 131; 24A (1967) 645.

    Google Scholar 

  27. J. A. Wilson and A. D. Yoffe, Adv. in Phys. 18 (1969) 193.

    Article  CAS  Google Scholar 

  28. R. M. White and G. Lucovsky, Solid St. Commun. 11 (1972) 1369.

    Article  CAS  Google Scholar 

  29. L. F. Mattheiss, Phys. Rev. B 8 (1973) 3719.

    Article  Google Scholar 

  30. R. V. Kasowski, Phys. Rev. Lett. 30 (1973) 1175.

    Google Scholar 

  31. P. M. Williams and F. R. Shepherd, J. Phys. C; Solid St. Phys. 6 (1973) L36.

    Article  CAS  Google Scholar 

  32. G. Wexler and A. M. Woolley, J. Phys. C; Solid St. Phys. 9 (1976) 1185.

    Article  CAS  Google Scholar 

  33. M. G. Bell and W. Y. Liang, Adv. in Phys. 25 (1976) 53.

    Article  CAS  Google Scholar 

  34. W. P. F. A. M. Omloo and F. Jellinek, J. Less Common Metals 20 (1970) 121.

    Article  Google Scholar 

  35. A. R. Beal, W. Y. Liang and J. B. Pethica, Phil. Mag. 33 (1976) 591.

    Article  CAS  Google Scholar 

  36. J. M. van den Berg and P. Cossee, Inorg. Chim. Acta 2 (1968) 143.

    Article  Google Scholar 

  37. K. Anzenhofer, J. M. van den Berg, P. Cossee and J. N. Helle, J. Phys. Chem. Solids 31 (1970) 1057.

    Article  CAS  Google Scholar 

  38. J. Rouxel, A. Le Blanc and A. Royer, Bull. Soc. Chim. Fr. 6 (1971) 2019.

    Google Scholar 

  39. F. Kadijk and F. Jellinek, J. Less Common Metals 19 (1969) 421.

    Article  CAS  Google Scholar 

  40. B. van Laar, H. M. Rietveld and D. J. W. Ijdo, J. Sol. St. Chem. 3 (1971) 154.

    Article  Google Scholar 

  41. S. K. Dickinson, Air Force Cambridge Research Labs., Phys. Sci. Research Paper 439 (1970).

    Google Scholar 

  42. A. Royer, A. Le Blanc-Soreau and J. Rouxel, C. R. Acad. Sc. Paris 276 (1973) 1021.

    CAS  Google Scholar 

  43. A. R. Beal and W. Y. Liang, Phil. Mag. 33 (1976) 121.

    Article  CAS  Google Scholar 

  44. A. Le Blanc-Soreau, J. Rouxel, M. F. Gardette and O. Gorochov, Mat. Res. Bull. 11 (1976) 1061.

    Article  Google Scholar 

  45. A. Meerschaut, Doctorat de Spécialité, Nantes (1971).

    Google Scholar 

  46. J. M. Voorhoeve and M. Robbins, J. Sol. St. Chem. 1 (1970) 134.

    Article  CAS  Google Scholar 

  47. A. Meerschaut and J. Rouxel, C.R. Acad. Sc. Paris 277 (1973) 163.

    CAS  Google Scholar 

  48. B. van Laar and D. J. W. Ijdo, Acta. Cryst. B 25 (1969) 993.

    Article  Google Scholar 

  49. F. Hulliger and E. Pobitschka, J. Sol. St. Chem. 1 (1970) 117.

    Article  CAS  Google Scholar 

  50. J. A. Benda, C. N. King, K. R. Pisharody and W. A. Phillips, Low Temp. Phys. LT 13, 4 (1972) 423.

    Google Scholar 

  51. J. A. Benda, Phys. Rev. B 10 (1974) 1409.

    Google Scholar 

  52. R. H. Friend, A. R. Beal and A. D.Yoffe, Phil. Mag. 35 (1977) 1269.

    Google Scholar 

  53. M. Eibschiitz, F. J. di Salvo, G. W. Hull and S. Mahajan, Appl. Phys. Lett. 21 (1975) 464.

    Article  Google Scholar 

  54. D. A. Whitney, R. M. Fleming and R. V. Coleman, Solid St. Commun. 18 (1976) 309.

    Article  CAS  Google Scholar 

  55. R. C. Morris, B. W. Young and R. V. Coleman, AIP Conf. Proc. No. 18 (1973) 292.

    Google Scholar 

  56. L. J. van der Pauw, Philips Res. Repts. 16 (1961) 187.

    Google Scholar 

  57. N. V. Volkenstein, V. P. Dyakina and V. E. Startsev, Phys. Stat. Sol. (b) 57 (1973) 9.

    Article  Google Scholar 

  58. H. N. S. Lee, M. Garcia, H. McKinzie and A. Wold, J. Sol. St. Chem. 1 (1970) 190.

    Article  CAS  Google Scholar 

  59. J. J. Hauser, M. Robbins and F. J. Di Salvo, Phys. Rev. B 8 (1973) 1038.

    Article  CAS  Google Scholar 

  60. B. van Laar, H. M. Rietveld and D. J. W. Ijdo, III Int. Conf. on Solid Compounds of Transition Elements, Oslo (1969) Abstracts p. 79.

    Google Scholar 

  61. L. Corliss, N. Elliott and J. Hastings, Phys. Rev. 104 (1956) 924.

    Article  CAS  Google Scholar 

  62. J. M. Voorhoeve and R. C. Sherwood, J. Phys. Chem. Solids 32 (1971) 167.

    Article  Google Scholar 

  63. K. G. Verhoeven, PhD. Thesis, Leiden University, Netherlands (1971).

    Google Scholar 

  64. A. M. Clogston, B. T. Matthias, M. Peter, H. J. Williams, E. Corenzwit and R. C. Sherwood, Phys. Rev. 125 (1962) 541.

    Article  CAS  Google Scholar 

  65. J. M. Ziman, Principles of the Theory of Solids, C.U. Press (1963).

    Google Scholar 

  66. P. M. Williams, Phys. and Chem. of Materials with Layered Structures, 2 (1976) 51, Reidel, Holland.

    Google Scholar 

  67. A. R. Beal, PhD Thesis, University of Cambridge (1973).

    Google Scholar 

  68. D. J. Bradley, Y. Katayama and B. L. Evans, Sol. St. Commun. 11 (1972) 1695. 305

    Google Scholar 

  69. W. Y. Liang, J. Phys. C; Sol. St. Phys. 6 (1973) 551.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Physics and Chemistry of Solids, Cavendish Laboratory, Madingley Road, Cambridge, England

    A. R. Beal

Authors
  1. A. R. Beal
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Laboratoire de Physique Appliquée, EPF, Lausanne, Switzerland

    F. Lévy

Rights and permissions

Reprints and permissions

Copyright information

© 1979 D. Reidel Publishing Company, Dordrecht, Holland

About this chapter

Cite this chapter

Beal, A.R. (1979). The First Row Transition Metal Intercalation Complexes of Some Metallic Group VA Transition Metal Dichalcogenides. In: Lévy, F. (eds) Intercalated Layered Materials. Physics and Chemistry of Materials with Layered Structures, vol 6. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-9415-7_5

Download citation

  • DOI: https://doi.org/10.1007/978-94-009-9415-7_5

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-009-9417-1

  • Online ISBN: 978-94-009-9415-7

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation