Abstract
A majority of the chemical reactions generally associated with clay minerals, metal oxides, and other soil-related minerals occur at the interfaces between the minerals and their surroundings. Two of these interfaces occur at the gas/solid, and liquid/solid reaction sites with the common component being the solid mineral surface. Few reactions related to soil environments involve chemical reactions generated at atom sites in a mineral’s bulk. Therefore, much useful chemical insight can be achieved by examining the chemistry of atoms and reaction products associated with the surface region of these minerals.
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References
Adams, I., J.M. Thomas, and G.M. Bancroft, 1972. An ESCA study of silicate minerals. Earth Planet. Sci. Lett. 16: 429–432.
Adams, J.M., S. Evans, P.I. Reid, J.M. Thomas, and J.M. Walters, 1977. Quantitative analysis of aluminosilicates and other solids by x-ray photoelectron spectroscopy. Anal. Chem. 49: 2001–2007.
Adams, J.M. and S. Evans. 1979. Exchange and selective surface uptake of cations by layer silicates using x-ray photoelectron spectroscopy (XPS). Clays Clay Miner. 27: 248 252.
Alvarez, R., C.S. Fadley, J.A. Silva, and G. Uehara. 1976. A study of silicate adsorption on gibbsite (AI(OH)3) by x-ray photoelectron spectroscopy (XPS). Soil Sci. Soc. Amer. J. 40: 615–617.
Anderson, P.R. and W.E. Swartz, Jr. 1974. X-ray photoelectron spectroscopy of some aluminosilicates. Inorg. Chem. 13: 2293–2294.
Baird, R.J., C.S. Fadley, S.K. Kawamoto, M. Mehta, R. Alvarez, and J.A. Silva. 1976. Concentration profiles for irregular surfaces from x-ray photoelectron angular distributions. Anal. Chem. 48: 843–846.
Bancroft, G.M., J.R. Brown, and W.S. Fyfe. 1977a. Quantitative x-ray photoelectron spectroscopy (ESCA): Studies of Ba2+ sorption on calcite. Chem. Geol. 19: 131–144.
Bancroft, G.M., J.R. Brown, and W.S. Fyfe. 1977b. Calibration studies for quantitative x-ray photoelectron spectroscopy of ions. Anal. Chem. 49: 1044–1048.
Bancroft, G.M., J.R. Brown, and W.S. Fyfe. 1979. Advances in, and applications of, x-ray photoelectron spectroscopy (ESCA) in mineralogy and geochemistry. Chem. Geol. 25: 227–243.
Betteridge, D., J.C. Carver, and D.M. Hercules. 1973. Devaluation of the gold standard in x-ray photoelectron spectroscopy. J. Electron Spectrosc. Relat. Phenom. 2: 327–334.
Burness, J.H., J.G. Dillard, and L.T. Taylor. 1975. An x-ray photoelectron spectroscopic study of cobalt (II) schiff base complexes and their oxygenation products. J. Amer. Chem. Soc. 97: 6080–6088.
Carriere, B. and J.P. Deville. 1977. X-ray photoelectron study of some silicon- oxygen compounds. J. Electron Spectrosc. Relat. Phenom. 10: 85–91.
Castle, J.E., L.B. Hazell, and R.H. West. 1979. Chemical shifts in Al-Si compounds by Zr La photoelectron spectrometry. J. Electron Spectrosc. Relat. Phenom. 16: 97–106.
Counts, M.E., J.S.C. Jen, and J.P. Wightman. 1973. An electron spectroscopy for chemical analysis study of lead adsorbed on montmorillonite. J. Phys. Chem. 77: 1924–1925.
Defosse, C., P. Canesson, P.G. Rouxhet, and B. Delmon. 1978. Surface characterization of silica-aluminas by photoelectron spectroscopy. J. Catal. 51: 269–277.
Dianis, W.P., and J.E. Lester. 1973. External standards in x-ray photoelectron spectroscopy. Anal. Chem. 45: 1416–1420.
Errerson, A.B. 1979. An XPS investigation of the effect of pH on chromium and cobalt adsorption on clay minerals. M.S. thesis, VPI & SU, Blacksburg, Va., USA.
Hercules, D.M. 1974. Electron spectroscopy for chemical analysis. J. Electron Spectrosc. Relat. Phenom. 5: 811–826.
Huntress, W.T., Jr., and L. Wilson. 1972. An ESCA study of lunar and terrestrial materials. Earth Planet. Sci. Lett. 15: 59–64.
Jaegle, A., A. Kalt, G. Nanse, and J.C. Peruchetti. 1978. Contribution a I’etude de l’effet de charge sur échantillon isolant en spectroscopie de photoelectrons (XPS). J. Electron Spectrosc. Relat. Phenom. 13: 175–186.
Koppelman, M.H. 1976. An x-ray photoelectron spectroscopic investigation of the adsorption of metal ions on marine clay minerals. Ph.D. thesis, VPI & SU, Blacksburg, Va., USA. 251 pp.
Koppelman, M.H. and J.G. Dillard. 1975. An ESCA study of sorbed metal ions on clay minerals. In: T.M. Church (ed.). Marine chemistry in the coastal environment, ACS Symposium Ser. #18, pp. 186–201.
Koppelman, M.H., and J.G. Dillard. 1977a. Unpublished data.
Koppelman, M.H., and J.G. Dillard. 1977b. A study of the adsorption of Ni(II) and Cu(II) by clay minerals. Clays Clay Miner. 25: 457–462.
Koppelman, M.H., and J.G. Dillard. 1978. An x-ray photoelectron spectroscopic (XPS) study of cobalt adsorbed on the clay mineral chlorite. J. Colloid Interface Sci. 66: 345–351.
Koppelman, M.H., and J.G. Dillard. 1979. The application of x-ray photoelectron spectroscopy (XPS or ESCA) to the study of mineral surface chemistry. Proc. Int. Clay Conf. 1978 (Pub. 1979): 153–164.
Koppelman, M.H., and J.G. Dillard. 1980. Adsorption of Cr(NH3)63+ and Cr(en)j3+ on clay minerals. Characterization of chromium using x-ray photo- electron spectroscopy. Clays Clay Miner. 28: 000.
Koppelman, M.H., J.G. Dillard, A.B. Emerson, and J.R. Furey. 1979. Unpublished data.
Koppelman, M.H., A.B. Emerson, and J.G. Dillard. 1980. On the nature of adsorbed Cr(III) on chlorite and kaolinite: An x-ray photoelectron spectroscopic study. Clays Clay Miner. 28: 119–124.
Lagaly, G. and A. Weiss. 1969. Determination of the layer charge in mica-type layer silicates. Proc. Int. Clay Conf. 1969 1: 61–80.
Lindsay, J.R., H.J. Rose, W.E. Swartz Jr., P.H. Watts Jr., and K.A. Rayburn. 1973. X-ray photoelectron spectra of aluminum oxides: structural effects on the chemical shift. Appt. Spectros. 27: 1–4.
Lunsford, J.H., P.J. Hutta, M.J. Lin, and K.A. Whitehorst. 1978. Cobalt nitrosyl complexes in zeolites A, X, and Y. Inorg. Chem. 17: 606–610.
Murray, J.W. and J.G. Dillard. 1979. The oxidation of cobalt (II) adsorbed on manganese dioxide. Geochim. Cosmochim. Acta 43: 781–787.
Nicholls, C.J., D.S. Urch, and A.N.L. Kay. 1972. Determination of coordination number in some compounds of magnesium and aluminum: a comparison of x-ray photoelectron (ESCA) and x-ray emission spectroscopies. J.C.S. Chem. Comm. 1972: 1198–1199.
Petrovic, R., R.A. Berner, and M.B. Goldhabcr. 1976. Rate control in dissolution of alkali feldspars - I. Study of residual grains by x-ray photoelectron spectroscopy. Geochim. Cosmochim. Acta 40: 537–548.
Schultz, H.D., C.J. Vesely, and D.W. Langer. 1974. Electron binding energies for silicon materials occurring in respirable coal dust. Appt. Spectrosc. 28: 374–375.
Seals, R.D., R. Alexander, L.T. Taylor, and J.G. Dillard. 1973. Core electron binding energy study of group lib-Vila compounds. Inorg. Chem. 12: 2485–2487.
Siegbahn, K., C. Nordling, A. Fahlman, R. Nordberg, K. Hamrin, J. Hedman, G. Johansson, T. Bergmark, S.E. Karlsson, I. Lindgren, and B. Kindbert. 1967. ESCA, Atomic, Molecular and Solid State Structure Studied by Means of Electron Spectroscopy, Almqvist and Wiksells, Uppsala, p. 276.
Stucki, J.W. and C.B. Roth. 1977. Oxidation-reduction mechanism for structural iron in nontronite. Soi/ Sci. Soc. Amer. J. 41: 808–814.
Stucki, J.W., C.B. Roth, and W.E. Baitinger. 1976. Analysis of iron-bearing clay minerals by electron spectroscopy for chemical analysis (ESCA). Clays Clay Miner. 24: 289–292.
Swartz, W.E. Jr., P.H. Watts Jr., J.C. Watts, J.W. Brasch, and E.R. Lippincott. 1972. Comparison of internal mixing and vacuum deposition procedures for calibrating ESCA spectra. Anal. Chem. 44: 2001–2005.
Tewari, P.H., and W.J. Lee. 1975. Adsorption of Co(II) at the oxide-water interface. J. Colloid Interface Sci. 52: 77–88.
Tewari, P.H. and N.S. Mclntyre. 1975. Characterization of adsorbed cobalt at the oxide-water interface. A/ChE. Symposium Ser. 71: 134–137.
Thomassin, J.H., J. Goni, P. Baillif, and J.C. Touray. 1976. Étude par spectrometry ESCA des premiers stades de la lixiviation du chrysotile en milieu acide organique. C.R. Acad. Sci., Paris, Sèr. D 283: 131–134.
Thomassin, J.H., J. Goni, P. Baillif, J.C. Touray, and M.C. Jaurand. 1977. An XPS study of the dissolution kinetics of chrysotile in 0.1 N oxalic acid at different temperatures. Phys. Chem. Miner. 1: 385–398.
Thomassin, J.H., J.C. Touray, and J. Tricket. 1976. Étude par spectrometry ESCA des premiers stades d’altération d’une obsidienne: le compostement relatif de l’aluminium et du silicium. C.R. Acad. Sci., Paris, Sér. D 282: 1229–1232.
Urch, D.S. and S. Murphy. 1974. The relationship between bond lengths and orbital ionization energies for a series of aluminosilicates. J. Electron Spec- trosc. Relat. Phenom. 5: 167–171.
Vin, L.I., S. Ghose, and I. Adler. 1971. Core electron binding energy difference between bridging and non-bridging oxygen atoms in a silicate chain. Science 173: 633–635.
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Koppelman, M.H. (1980). Application of X-ray Photoelectron Spectroscopy to the Study of Mineral Surface Chemistry. In: Stucki, J.W., Banwart, W.L. (eds) Advanced Chemical Methods for Soil and Clay Minerals Research. NATO Advanced Study Institutes Series, vol 63. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-9094-4_4
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DOI: https://doi.org/10.1007/978-94-009-9094-4_4
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