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Application of EPR to Surface Chemistry: Coordination Chemistry of Paramagnetic Ions in Zeolites

  • J. H. Lunsford
Part of the NATO Advanced Study Institutes Series book series (ASIC, volume 61)

Abstract

The application of epr to transition metal complexes in zeolites is illustrated by examples which include ion migration during complex formation, the formation of fully coordinated complexes, the determination of spin state, spin-spin interactions, unusual oxidation states and redox reactions. Problems involved in the determination of coordination number and symmetry from epr data are discussed.

Keywords

Transition Metal Complex Sodalite Cage Sodalite Cavity Unusual Oxidation State Dehydrate Zeolite 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    Flentge, D. R., Lunsford, J. H., Jacobs, P. A. and Uytterhoeven, J. B., J. Phys. Chem., 79, 354 (1975).CrossRefGoogle Scholar
  2. 2.
    Leith, J. R. and Leach, H. F., Proc. Roy. Soc. Lond. A, 330, 247 (1972).CrossRefGoogle Scholar
  3. 3.
    Naccache, C. and Ben Taarit, Y., Chem. Phys. Lett., 11, 11 (1971).CrossRefGoogle Scholar
  4. 4.
    Vansant, E. F. and Lunsford, J. H., J. Phys. Chem., 76, 2860 (1972).CrossRefGoogle Scholar
  5. 5.
    Turkevich, J., Ono, Y. and Soria, J., J. Catal., 25, 44 (1972).CrossRefGoogle Scholar
  6. 6.
    Vedrine, J. C., Derouane, E. G. and Ben Taarit, Y., J. Phys. Chem., 78, 531 (1974).CrossRefGoogle Scholar
  7. 7.
    Peigneur, P., Lunsford, J. H., DeWilde, W. and Schoonheydt, R. A., J. Phys. Chem., 81, 1179 (1977).CrossRefGoogle Scholar
  8. 8.
    Dai, P. S. and Lunsford, J. H., Inorg. Chem., (in press).Google Scholar
  9. 9.
    DeWilde, W. and Lunsford, J. H., Inorg. Chim. Acta, 34, L229 (1979).CrossRefGoogle Scholar
  10. 10.
    Herman, R., Inorg. Chem., 18, 995 (1979).CrossRefGoogle Scholar
  11. 11.
    Chao, C. C. and Lunsford, J. H., J. Phys. Chem., 76, 1546 (1972).CrossRefGoogle Scholar
  12. 12.
    Naccache, C., Che, M. and Ben Taarit, Y., Chem. Phys. Lett., 13, 109 (1972).CrossRefGoogle Scholar
  13. 13.
    Naccache, C. and Ben Taarit, Y., JCS Faraday Trans. I, 69, 1475 (1973).CrossRefGoogle Scholar
  14. 14.
    Kasai, P. H. and Bishop, R. J., J. Amer. Chem. Soc., 94, 5560 (1972).CrossRefGoogle Scholar
  15. 15.
    Jermyn, J. W., Johnson, T. J., Vansant, E. F. and Lunsford, J. H., J. Phys. Chem., 77, 2964 (1973).CrossRefGoogle Scholar
  16. 16.
    Chao, C. C. and Lunsford, J. H., J. Phys. Chem., 78, 1174 (1974).CrossRefGoogle Scholar
  17. 17.
    Vansant, E. F. and Lunsford, J. H., Adv. in Chem. Series, 121, 441 (1973).Google Scholar
  18. 18.
    Howe, R. F. and Lunsford, J. H., J. Amer. Chem. Soc., 97, 5156 (1975).CrossRefGoogle Scholar
  19. 19.
    Howe, R. F. and Lunsford, J. H., J. Amer. Chem. Soc., 79, 1836 (1975).Google Scholar
  20. 20.
    Naccache, C., Ben Taarit, Y. and Boudart, M., in “Molecular Sieves-II” (J. R. Katzer, ed.), ACS Symposium Series, No. 40, 156 (1977).Google Scholar
  21. 21.
    Lunsford, J. H., Catal. Rev., 12, 137 (1975).CrossRefGoogle Scholar
  22. 22.
    Kellerman, R. and Klier, K., in “Surface and Defect Properties of Solids”, Vol. 4, The Chemical Society Burlington House, London, pp. 1–33.Google Scholar
  23. 23.
    Lunsford, J. H., in “Molecular Sieves-II” (J. R. Katzer, ed.), ACS symposium Series, No. 40, 473 (1977).Google Scholar
  24. 24.
    Chao, C. C. and Lunsford, J. H., J. Chem. Phys., 59, 5920 (1973).CrossRefGoogle Scholar
  25. 25.
    Smith, J. V., Adv. in Chem. Series, 102, 401 (1971).Google Scholar
  26. 26.
    Gallezot, P., Ben Taarit, Y. and Imelik, B., Compt. Rend., (C), 272, 261 (1971); J. Catal., 26, 295 (1972).Google Scholar
  27. 27.
    Maes, A., Peigneur, P. and Cremers, A., JCS Faraday Trans. I, 74, 182 (1978).CrossRefGoogle Scholar
  28. 28.
    Vansant, E. F. and Lunsford, J. H., JCS Faraday Trans. II, 69, 1028 (1973).CrossRefGoogle Scholar
  29. 29.
    Griffith, J. S., Discuss. Faraday Soc., 25, 81 (1958).CrossRefGoogle Scholar
  30. 30.
    Earnshaw, A., King, E. A. and Larkworthy, L. F., J. Chem. Soc. A, 2459 (1969).Google Scholar
  31. 31.
    Chao, C. C. and Lunsford, J. H., J. Chem. Phys., 57, 2890 (1972).CrossRefGoogle Scholar
  32. 32.
    Maxwell, I. E. and deBoer, J. J., J. Phys. Chem., 79, 1874 (1975).CrossRefGoogle Scholar
  33. 33.
    Creutz, C. and Sutin, N., Proc. Nat. Acad. Sci. USA, 72, 2858 (1975).CrossRefGoogle Scholar
  34. 34.
    Quayle, W. H. and Lunsford, J. H., to be published.Google Scholar
  35. 35.
    DeSimone, R. E. and Drago, R. S., J. Amer. Chem. Soc., 92, 2343 (1970).CrossRefGoogle Scholar
  36. 36.
    Klier, K., Hutta, P. J. and Kellerman, R., in “Molecular Sieves-II” (J. R. Katzer, ed.) ACS Symposium Series, No. 40, 108 (1977).Google Scholar

Copyright information

© D. Reidel Publishing Company 1980

Authors and Affiliations

  • J. H. Lunsford
    • 1
  1. 1.Department of ChemistryTexas A&M UniversityCollege StationUSA

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