Abstract
The principal utility of Mössbauer Effect spectroscopy in the study of mixed-valence materials is its ability (through measurement of the chemical isomer shift) to distinguish between different oxidation states of the same element in similar chemical environments. By using Mössbauer Effect spectroscopy it is possible to distinguish between trapped and delocalized valence states in mixed-valence compounds. In addition, the rather long lifetime of the Mössbauer experiment, as compared to other forms of spectroscopy, permits evaluation of the rate of intervalence electron exchange in mixed-valence materials.
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General References on the Mössbauer Effect
N. N. Greenwood and T. C. Gibb, “Mossbauer Spectrocopy,” Chapman and Hall, London (1971).
T. C. Gibb, “Principles of Mossbauer Spectroscopy,” Chapman and Hall, London (1976).
C. V. I. Goldanskii and E. F. Makarov, “Fundamentals of Gamma- Resonance Spectroscopy,” Chapter 1 in “Chemical Applications of Mössbauer Spectroscopy,” V. I. Goldanskii and R. H. Herber, Eds.; Academic Press, New York (1968).
R. L. Cohen, “Elements of Mössbauer Spectroscopy,” Chapter 1 in “Applications of Mossbauer Spectroscopy,” Vol. 1, R. L. Cohen, Ed.; Academic Press, New York (1976).
G. M. Bancroft, “Mössbauer Spectroscopy An Introduction for Inorganic Chemists and Geochemists,” John Wiley and Sons, New York (1973).
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Brown, D.B., Wrobleski, J.T. (1980). Applications of the Mössbauer Effect to the Study of Mixed-Valence Compounds. In: Brown, D.B. (eds) Mixed-Valence Compounds. NATO Advanced Study Institutes Series, vol 58. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-9076-0_8
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DOI: https://doi.org/10.1007/978-94-009-9076-0_8
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