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Mixed-Valence Compounds pp 387–411Cite as

Linear Chain Mixed-Valence Systems with Direct Metal- Metal Interactions

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Part of the book series: NATO Advanced Study Institutes Series ((ASIC,volume 58))

Abstract

This article describes the preparation and structural chemistry of a very restricted class of solid transition metal compounds. Onlymixed valence solids containinginfinite linear arrays of nonbridged transition metal ions will be discussed. The paper is limited to these materials, because high and anisotropic conductivities in linear molecular solids can only be expected fromdirectly interacting systems (1d metals).

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Literature

  1. Robin, M.B., and Day, P.: 3.967, Adv. Inorg. Chem. Radiochem. 10, pp. 247 - 463.

    Google Scholar 

  2. Allen, G.C., and Hush, N.S.: 1967, Progr.Inorg. Chem. 8, pp. 357 - 389.

    Article  CAS  Google Scholar 

  3. Hush, N.S.: 1967, Progr.Inorg.Chem. 8, pp. 391 - 444

    Article  CAS  Google Scholar 

  4. Krogmann, K.: 1969, Angew.Chem. 81, pp. 10 ff., 1969, Int.Ed.Engl. 8, pp.35 ff.

    Google Scholar 

  5. “Extended Interactions between Metal Ions in Transition Metal Complexes”, ACS Symposium Series, Vol. 5, 1974, ed. L. V. Interrante, Washington, D.C.

    Google Scholar 

  6. “Low-dimensional Cooperative Phenomena”, NATO-ASI Series B, Vol. 7, 1975, ed. H.J.Keller, Plenum Press, N.Y.

    Google Scholar 

  7. “One-dimensional Conductors”, 1975, Lecture Notes in Physics, Vol. 34, Springer Verlag, ed. H.G. S chuster.

    Google Scholar 

  8. “Chemistry and Physics of One-dimensional Metals”, 1977, NATO-ASI Series B, Vol. 25, Plenum Press, N.Y., ed. H.J.Keller

    Google Scholar 

  9. Miller, J.S., and Epstein, A.J.: 1976, Prog.Inorg. Chem. 20, pp. 1 ff.

    Article  CAS  Google Scholar 

  10. “Inorganic Compounds with Unusual Properties”, 1976, Adv. in Chem. Series 150, ed. R.B.King

    Google Scholar 

  11. “Synthesis and Properties of Low-dimensional Materials”, 1 978, Ann.N.Y.Acad.Sci. 313, ed. J.S. Miller and A.J.Epstein.

    Google Scholar 

  12. “Molecular Metals”, NATO-Conference Series VI, Vol. 1, Plenum Press, N.Y., 1979, ed.W.A.Hatfield

    Google Scholar 

  13. Thomas, T.W., and Underhill, A.E.: 1972, Chem. Soc.Rev. 1, pp. 99 ff.

    Article  CAS  Google Scholar 

  14. Underhill, A.E. in ref. (6), pp. 287-297

    Google Scholar 

  15. See for example: Campbell, J.A.: 1970,Chemical Systems, Energetics, Dynamics, Structure

    Google Scholar 

  16. a) Petersen, J.L., Schramm,C.S.,Stojakovic,D.R., Hoffman,B.M., and Marks,T.J.: 1977, J.Amer. Chem.Soc., 99, pp. 286 b) Marks,T.J., in ref. (11), pp. 609-614.

    Article  CAS  Google Scholar 

  17. a) Petersen, J.L., Schramm,C.S.,Stojakovic,D.R., Hoffman,B.M., and Marks,T.J.: 1977, J.Amer. Chem.Soc., 99, pp. 286 b) Marks,T.J., in ref. (11), pp. 609-614.

    Google Scholar 

  18. Bekaroglu, Ö, Sarisaban, S. Koray, A.R., and Ziegler, M.L.: 1977, Z.Naturforsch. 32b, pp. 387- 392

    Google Scholar 

  19. Endres, H., Keller, H.J., Lehmann, R., Poveda, A., Rupp, H.H., van de Sand, H.: 1977, Z.Naturforsch. 32b, pp. 516 ff.

    Google Scholar 

  20. Dart, J.W., Lloyd, M.K., Mason, R., and McCleverty, J.A.: 1 973, J.Chem.Soc.Dalton, pp. 2046 ff.

    Google Scholar 

  21. Gordon II, J.G., Williams, R., Hsu, C.H., Cuellar, E., and Somoano, R.: 1978, ref. (11), pp. 580

    Google Scholar 

  22. Miskowski, V.M., Nobinger, G.L., Kliger, D.S., Hammond, G.S., Lewis, N.S., Mann, K.R., and Gray, H.B.: 1978, J.Amer.Chem.Soc. 100, pp. 485 ff.

    Article  CAS  Google Scholar 

  23. a) Balch, A.L., and Olmstead, M.M.: 1976, J.Amer. Chem.Soc. 98, pp. 2354 b)Balch, A.L., and Olmstead, M.M.: 1979, J.Amer. Chem.Soc. 101, pp. 3128

    Google Scholar 

  24. a)Balch, A.L., and Olmstead, M.M.: 1976, J.Amer. Chem.Soc. 98, pp. 2354 b) Balch, A.L., and Olmstead, M.M.: 1979, J.Amer. Chem.Soc. 101, pp. 3128

    Google Scholar 

  25. Endres, H., Gottstein, N., Keller, H.J., Martin, R., Rodemer, W., and Steiger, W.: 1979, Z.Naturforsch. 34b, pp. 827 - 833

    Google Scholar 

  26. Bonati, F., and Ugo, R.: 1 967, J.Organometal. Chem. 7, pp. 167 - 180

    Google Scholar 

  27. Ugo, R., La Monica, G., Cenini, S., and Bonati, F.: 1968, J.Organometal.Chem. 11, pp. 159

    Article  CAS  Google Scholar 

  28. Cozens, R.J., Murray, K.S., and West, B.O.: 1971, J.Organometal.Chem. 27, pp. 399 - 407

    Article  CAS  Google Scholar 

  29. Bailey, N.A., Coates, E., Robertson, G.B., Bonati, I., and Ugo, R.: 1967, J.Chem.Soc.Chem.Commun. pp. 1041 b) Hug, F., and Skapski, A.C.: 1974, J.Cryst. Molec.Struct. 4, pp. 411

    Google Scholar 

  30. Bailey, N.A., Coates, E., Robertson, G.B., Bonati, I., and Ugo, R.: 1967, J.Chem.Soc.Chem.Commun. pp. 1041 b) Hug, F., and Skapski, A.C.: 1974, J.Cryst. Molec.Struct. 4, pp. 411

    Google Scholar 

  31. De Haven, P.W., and Goedken, V.L.: 1979, Inorg. Chem. 18, pp. 827

    Article  Google Scholar 

  32. Malatesta, L., and Angoletta, M.: 1958, J.Inorg. Nucl.Chem. 8, pp. 273

    CAS  Google Scholar 

  33. Malatesta, L., and Canziani, F.,: 1961, J.Inorg. Nucl.Chem. 19, pp. 81 - 93

    Article  CAS  Google Scholar 

  34. a)Chernyaev, I.I., and Novozhenyuk, Z.M.: 1966, Russ.J.Inorg.Chem. 11, pp. 1398. b)Forster, D.: 1969, Inorg.Nucl.Chem.Letters, 3, pp. 433 - 436.

    Google Scholar 

  35. Cleare, M.J., and Griffith, W.B.: 1969, J.Chem. Soc. A1 9 6 9, pp. 372-380 and 1 970, J.Chem.Soc. A 1970, pp. 2788 - 2794.

    Google Scholar 

  36. Ginsberg, A.P., Koepke, J.W., Cohen, R.L., and West, K.W.: 1976, Chem.Phys.Letters, 38, pp. 310

    Article  CAS  Google Scholar 

  37. Krogmann, K.: 1977, in ref. (8), pp. 229.

    Google Scholar 

  38. Rosencwaig, A., Ginsberg, A.P., and Koepke, J.W.: 1976, Inorg.Chem. 15, pp. 2540 and references cited therein.

    Article  CAS  Google Scholar 

  39. Hieber, Wand Lagally, H.: 1940, Z.Anorg.Allg. Chem. 245, pp. 321.

    Article  CAS  Google Scholar 

  40. Hieber,, W Lagally, H., and Mayr, H.: 1941, Z.Anorg.Allg.Chem. 246, pp. 138

    Article  CAS  Google Scholar 

  41. Fischer, E.O., and Brenner, K.S.: 1962, Z.Naturforsch. 17b, pp. 774.

    Google Scholar 

  42. Krogmann, K., Binder, W., and Hausen, H.D.: 1 968, Angew. Chem. 8o, p. 844 and 1968, Angew.Chem. Int.Ed. 7, p. 812.

    Google Scholar 

  43. Ginsberg, A.P., Cohen, R.L., DiSalvo, F.J., and West, K.W.: 1974, J.Chem.Phys. 60, pp. 2657.

    Article  CAS  Google Scholar 

  44. Gitzel, W., Keller, H.J., Lorentz, R., and Rupp, H.H.: 1973, Z.Naturforsch. 28b, pp. 161 - 163.

    CAS  Google Scholar 

  45. a) Keller, H.J.: 1975, in ref. (6), pp. 315 b) Endres, H., Keller, H.J., Lehmann, R., van de Sand, H., Vu, D., and Poveda, A., in ref. (11), pp. 627-632

    Google Scholar 

  46. a) Keller, H.J.: 1975, in ref. (6), pp. 315 b) Endres, H., Keller, H.J., Lehmann, R., van de Sand, H., Vu, D., and Poveda, A., in ref. (11), pp. 627-632

    Google Scholar 

  47. a) Reis, A.H., jr., Hagley, V.S., Peterson, S.W.: 1977, J.Amer.Chem.Soc. 99, pp. 4184. b) Reis, A.H., jr., and Peterson, S.W., in ref. (11), pp. 571-578.

    Article  CAS  Google Scholar 

  48. a) Reis, A.H., jr., Hagley, V.S., Peterson, S.W.: 1977, J.Amer.Chem.Soc. 99, pp. 4184. b) Reis, A.H., jr., and Peterson, S.W., in ref. (11), pp. 571-578.

    Google Scholar 

  49. Edelman, L.E.: 1950, J.Amer.Chem.Soc. 72, pp. 5765.

    Article  CAS  Google Scholar 

  50. Simek, M.: 1962, Collection Czech.Chem.Commun. 27, pp. 337.

    CAS  Google Scholar 

  51. Foust, A.S., and Soderberg, R.H.: 1967, J.Amer. Chem.Soc., 89, pp. 5507.

    Article  CAS  Google Scholar 

  52. Keller, H.J., and Seibold, K.: 1971, J.Amer.Chem. Soc., 93, pp. 1309.

    Article  CAS  Google Scholar 

  53. Teitelbaum, R.C., Ruby, S.L., and Marks, T.J.: 1978, J.Amer.Chem.Soc. 100, pp. 3215 and ref. cited therein.

    Google Scholar 

  54. Gleizes, A., Marks, T.J., and Ibers, J.A.: 1975, J.Amer.Chem.Soc. 97, pp. 3545.

    Article  CAS  Google Scholar 

  55. Miller, J.S., and Griffiths, C.H.: 1977, J.Amer. Chem.Soc. 99, pp. 749.

    Article  CAS  Google Scholar 

  56. Cowie, M., Gleizes, A., Grynkewich, G.W., Webster Kalina, D., Mc.Clure, M.S., Scaringe, R.P., Teitelbaum, R.C., Ruby, S.L., Ibers, J.A., Kannewurf, C.R., and Marks, T.J.: 1979, J.Amer.Chem. Soc. 101, pp. 2921.

    Article  CAS  Google Scholar 

  57. Miller, J.S.: 1977, Inorg.Chem. 16, pp. 957.

    Article  CAS  Google Scholar 

  58. Keller, H.J., and Lehmann, R.: 1979, Z.Naturforsch. 34b, pp. 245 and references cited therein.

    Google Scholar 

  59. Moroni, W., and Nöthe, D.: 1974, Inorg.Nuc1. Chem. Letters, 10, pp. 467.

    Google Scholar 

  60. Endres, H., Keller, H.J., Moroni, W., and Weiß, J.: 1975, Acta Cryst., B31, pp. 2357.

    Article  Google Scholar 

  61. Endres, H., Keller, H.J., Mégnamisi-Bélombé, M., Moroni, W., Pritzkow, H., Weiß, J., and Comès, R.: 1976, Acta Cryst., A 32, pp. 954.

    Article  Google Scholar 

  62. Marks, T.J., Webster, D.F., Ruby, S.L., and Schultz, S.: 1976, J.Chem.Soc.Chem.Commun., pp.444.

    Google Scholar 

  63. Brown, L.D., Webster Kalina, D., McClure, M.S., Schultz, S., Ruby, S.L., Ibers, J.A., Kannewurf, C.R., and Marks, T.J.: 1979, J.Amer.Chem.Soc., 101, pp. 2 93 7.

    Google Scholar 

  64. Hoffman, B.M., Phillips, T.E., Schramm, C.J., and Wright, S.K., in ref. (12), pp. 393 and references cited therein.

    Google Scholar 

  65. Schramm, C.J., Stojakovic, D.R., Hoffman, B.M., and Marks, T.J.: 1978, Science, 200, pp. 47.

    Article  CAS  Google Scholar 

  66. Phillips, T.E., and Hoffman, B.M.: 1977, J.Amer. Chem.Soc., 99, pp. 7734.

    Article  Google Scholar 

  67. Endres, H., Keller, H.J., and Lehmann, R.: 1975, Inorg.Nucl.Chem.Letters, 11, pp. 769.

    Article  CAS  Google Scholar 

  68. Endres, H., Keller, H.J., Lehmann, R., and WeiB, J.: 1976, Acta Cryst., B32, pp. 627.

    Google Scholar 

  69. Stucky, G.D., Schultz, A.J., and Williams, J.M.: 1 977, Ann.Rev.Mater.Sci., 7, pp. 301.

    Google Scholar 

  70. Williams, J.M., and Schultz, A.J., in ref. (12), pp. 337-368.

    Google Scholar 

  71. Knop, W., and Schnedermann, G.: 1846, J.prakt. Chem., 37, pp. 462.

    Article  Google Scholar 

  72. Hadow, E.A.: 1861, Quart.J.Chem.Soc., 14, pp. 104.

    Google Scholar 

  73. Wilm, Th.: 1888, Ber.dtsch.chem.Ges., 21, pp. 1436.

    Article  Google Scholar 

  74. Levy, L.A.: 1912, J.Chem.Soc.(London), pp. 1081.

    Google Scholar 

  75. Werner, A: 1896, Z. Anorg. Chem., 12, pp. 46

    Article  CAS  Google Scholar 

  76. Krogmann, K.: 1968, Z.Anorg.Allg.Chem., 358, pp. 67.

    Article  CAS  Google Scholar 

  77. Williams, J.M., Petersen, J.L., Gerdes, H.M., and Peterson, S.W.: 1974, Phys.Rev.Letters, 33, pp. 1079.

    Article  CAS  Google Scholar 

  78. Zeller, H.R.: 1973, Adv.Solid State Phys., 13, pp. 31.

    Article  CAS  Google Scholar 

  79. Brown, R.K., and Williams, J.M.: 1979, Inorg. Chem., 18, pp. 1922 and references cited therein.

    Google Scholar 

  80. Soderbaum, H.G.: 1886, Bui1.Soc.Chim.France, 45, pp. 188.

    Google Scholar 

  81. Werner, A.: 1899, Z.Anorg.Allg.Chem., 21, pp. 377.

    CAS  Google Scholar 

  82. Krogmann, K., and Dodel, P.: 1966, Chem. Ber., 99, pp. 3402, pp. 3408.

    Article  Google Scholar 

  83. Krogmann, K.: 1968, Z.Anorg.Allg.Chem., 358, pp. 97.

    Article  CAS  Google Scholar 

  84. Reis, A.H., jr., Peterson, S.W., and Lin, S.C.: 1976, J.Amer.Chem.Soc., 98, pp. 7839 and in ref. (11), pp. 566.

    Article  CAS  Google Scholar 

  85. Kobayashi, H., Shirotani, I., Kobayashi, A., and Sasaki, Y.: 1977, Solid State Commun., 23, pp. 409.

    Article  CAS  Google Scholar 

  86. a) Schultz, A.J., Underhill, A.E., and Williams, J.M.: 1978, Inorg.Chem., 17, pp. 1313. b) Underhill, A.E., and Wood, D.J., in ref. (12), pp. 377.

    Article  CAS  Google Scholar 

  87. Miller, J.S.: 1976, Inorg.Chem., 15, pp. 2357.

    Article  CAS  Google Scholar 

  88. a) Reis, A.H., jr.: 1977, Inorg.Nuc1.Chem.Letters, 13, pp. 231. b) Reis, A.H., and Peterson, S.W., in ref. (11), pp. 560.

    Article  CAS  Google Scholar 

  89. a) Reis, A.H., jr.: 1977, Inorg.Nuc1.Chem.Letters, 13, pp. 231. b) Reis, A.H., and Peterson, S.W., in ref. (11), pp. 560.

    Google Scholar 

  90. Gitzel, W., Keller, H.J., Rupp, H.H., and Seibold, K.: 1972, Z.Naturforsch., 27b, pp. 365.

    CAS  Google Scholar 

  91. Atoji, M., Richardson, J.W., and Rundle, R.E.: 1957, J.Amer.Chem.Soc., 79, pp. 3017.

    Article  CAS  Google Scholar 

  92. Buse, K.D., Keller, H.J., and Nothe, D.: 1976, Z.Naturforsch., 31b, pp. 194.

    Google Scholar 

  93. Tsujikawa, I., Kubota, R., Enoki, T., Miyajima, S., and Kobayashi, H.: 1977, J.Phys.Soc.Japan, 43, pp. 1459.

    Article  CAS  Google Scholar 

  94. Soos, Z.G., and Keller, H.J., in ref. (8), pp. 391-412.

    Google Scholar 

  95. Papavassiliou, G.C., and Theophanides, T.: 1979, Z.Naturforsch., 34b, pp. 986.

    Google Scholar 

  96. Endres, H., Keller, H.J., van de Sand, H., and Vu Dong: 1978, Z.Naturforsch., 33b, pp. 843.

    Google Scholar 

  97. Bartkowski, R.R., and Morosin, B.: 1972, Phys.Rev., B 6, pp. 4209.

    Article  CAS  Google Scholar 

  98. Terauchi, H., Sakamoto, N., and Shirotani, I.: 1975, J.Phys.Soc.Japan, 38, pp. 595.

    Article  Google Scholar 

  99. Lawton, S.L., Rohrbaugh, W.J., and Kokotailo, G.T.: 1972, Inorg.Chem., 11, pp. 2227.

    Article  CAS  Google Scholar 

  100. Hesse, R., and Jennische, P.: 1972, Acta Chem. Scand., 26, pp. 3855.

    Article  CAS  Google Scholar 

  101. Rundle, R.E.: 1954, J.Amer.Chem.Soc., 76, pp. 3101.

    Article  CAS  Google Scholar 

  102. Miller, J.S.: 1974, J.Amer.Chem.Soc., 96, pp. 7131.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Anorganisch-Chemisches Institut, der Universität Heidelberg, D-6900, Heidelberg, 1,/GFR Im Neuenheimer Feld 270, Germany

    H. J. Keller

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  1. Department of Chemistry, The University of Vermont, Cook Physical Science Building, Burlington, Vermont, USA

    David B. Brown

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Keller, H.J. (1980). Linear Chain Mixed-Valence Systems with Direct Metal- Metal Interactions. In: Brown, D.B. (eds) Mixed-Valence Compounds. NATO Advanced Study Institutes Series, vol 58. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-9076-0_13

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