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Lattice Modes of Molecular Crystals

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Analytical Applications of FT-IR to Molecular and Biological Systems

Part of the book series: NATO Advanced Study Institutes Series ((ASIC,volume 57))

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Abstract

The lattice vibrations of molecular crystals arise from the translational and rotational motions of the molecules, which are unhindered motions in the gas phase. They are intermolecular vibrations and are sometimes called external vibrations, while the vibrations that exist in the gas phase are intramolecular vibrations and are sometimes called internal vibrations. The lattice vibrations can be usefully thought of as translational vibrations and rotational vibrations, although the two types of motion often contribute to the same vibration. Translational and rotational vibrations are sometimes called translatory and rotatory vibrations, and rotational vibrations are frequently called librations.

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Authors and Affiliations

  1. Department of Chemistry, University of Alberta, Edmonton, Alberta, Canada

    John E. Bertie

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  1. John E. Bertie
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Editors and Affiliations

  1. College of Science and Mathematics, University of South Carolina, Columbia, South Carolina, USA

    James R. Durig

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© 1980 D. Reidel Publishing Company

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Bertie, J.E. (1980). Lattice Modes of Molecular Crystals. In: Durig, J.R. (eds) Analytical Applications of FT-IR to Molecular and Biological Systems. NATO Advanced Study Institutes Series, vol 57. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-9070-8_22

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  • DOI: https://doi.org/10.1007/978-94-009-9070-8_22

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-009-9072-2

  • Online ISBN: 978-94-009-9070-8

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