Abstract
The historical development of interferometry and Fourier transform infrared spectroscopy has been presented earlier in this volume; however, it should be noted that the first chemical applications of FT-IR spectroscopy were made in the far infrared region of the spectrum (~400 to 10 cm-1) because the instrumentation required to study this region was much simpler than that needed for the mid or near infrared regions. The instrumental advantages in the far infrared region included a lower tolerance for the mirror drive of a Michelson interferometer, a smaller dynamic range of the interferogram, and a longer sampling time which resulted in a reduced number of data points. However, far infrared spectroscopy also had its inherent difficulties such as low-energy sources, poor detectors, a lack of suitable optical materials, and spectral interference of water. Researchers in this area have overcome most of these difficulties and therefore investigations in the far infrared spectral region have become widespread. In the following sections, some of the applications of Fourier transform far infrared spectroscopy will be examined and, when applicable, they will be compared with the more conventional grating spectrometers. It seems appropriate to begin the discussion with a brief outline of some of the initial applications of far infrared interferometry.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
R. T. Hall and J. M. Dowling, J. Mol. Spectrosc., 19, 108 (1966).
R. T. Hall and J. M. Dowling, J. Chem. Phys., 45, 1899 (1966).
K. D. Möller, V. P. Tomaselli, L. R. Skube, and B. K. McKenna, J. Opt. Soc. Amer., 35, 1233 (1965).
R. B. Barnes, Phys. Rev., 47, 658 (1935).
N. Wright and H. M. Randall, Phys. Rev., 44, 391 (1933).
P. R. Griffiths and H. W. Thompson, Spectrochim. Acta, 24A, 1325 (1968).
P. R. Griffiths, Chemical Infrared Fourier Transform Spectroscopy, Wiley ( Interscience ), New York, (1975) p. 229.
J. R. Durig and A. W. Cox, in Fourier Transform Infrared Spectroscopy, Vol. 1, J. R. Ferraro and L. J. Basile, editors, New York, Academic Press (1978).
K. D. Moller and W. G. Rothschild, Far-Infrared Spectroscopy, Wiley ( Interscience ), New York (1971).
R. T. Hall, D. Vrabec, and J. M. Dowling, Appl. Opt., 5, 1149 (1966).
H. Yoshinaga, S. Fujitz, S. Minami, A. Mitsuishi, R. A. Oetjen, and Y. Yamada, J. Opt. Soc. Amer., 48, 315 (1958).
D. W. Robinson, J. Opt. Soc. Amer., 49, 966 (1959).
H. A. Gebbie, N. W. B. Stone, G. Topping, E. K. Gora,S. A. Clough, and F. X. Kneizys, J. Mol. Spectrosc., 19, 7 (1966).
A. J. Sievers and M. Tinkham, Phys. Rev., 129, 1995 (1963).
J. R. Durig, S. M. Craven, and J. Bragin, J. Chem. Phys., 52, 2046 (1970).
J. R. Durig, S. M. Craven, and W. C. Harris in Vibrational Spectra and Structure, Vol. 1, J. R. Durig, editor, Marcel Dekker, Inc. (1972), p. 147.
J. E. Kilpatrick and K. S. Pitzer, J. Chem. Phys., 17, 1064 (1949).
D. R. Herschbach, J. Chem. Phys, 31, 91 (1959).
W. G. Fateley and F. A. Miller, Spectrochim. Acta, 17, 857 (1961).
W. G. Fateley and F. A. Miller, Spectrochim. Acta, 18, 977 (1962).
W. G. Fateley and F. A. Miller, Spectrochim. Acta, 19, 611 (1963).
S. Weiss and G. E. Leroi, J. Chem. Phys., 48, 962 (1968).
G. Sage and W. Klemperer, J. Chem. Phys., 39, 371 (1963).
J. R. Durig, W. E. Bucy, L. A. Carreira, and C. J. Wurrey, J. Chem. Phys., 60, 1754 (1974).
J. R. Durig, P. Groner, and M. G. Griffin, J. Chem. Phys., 66, 3061 (1977).
D. R. Herschbach, J. Chem. Phys., 25, 359 (1956).
J. R. Durig, W. E. Bucy, and C, J. Wurrey, J. Chem. Phys., 60, 3293 (1974).
J. R. Durig, S. M. Craven, and J. Bragin, J. Chem. Phys., 53, 38 (1970).
J. R. Durig, W. E. Bucy, and C. J. Wurrey, J. Chem. Phys., 63, 5498 (1975).
J. R. Durig, S. M. Craven, and J. Bragin, J. Chem. Phys., 52, 2046 (1970).
R. P. Bell, Proc. Roy, Soc. London, A183, 328 (1945).
R. M. Irwin, J. M. Cooke, and J. Laane, J. Amer. Chem. Soc., 99, 3273 (1977).
J. M. R. Stone and I. M. Mills, Mol. Phys., 18, 631 (1970).
J. Laane and R. C, Lord, J. Chem. Phys0, 48, 1508 (1968).
T. R. Borgers and H. L. Strauss, J. Chem, Phys., 45, 947 (1966).
J. R. Durig, A. C. Shing, L. A Carreira, and Y. S. Li, J. Chem. Phys., 57, 4398 (1972).
S. I. Chan, T. R. Borgers, J. W. Russell, H. L. Strauss, and W. D„ Gwinn, J. Chem. Phys., 44, 1103 (1966).
A. B. Harvey, J. R. Durig, and A. C. Morrissey, J. Chem. Phys., 50, 4949 (1969).
J. Laane and R. C. Lord, J. Chem. Phys., 47, 4941 (1967).
J. Laane, J. Chem. Phys., 50, 1946 (1969).
J. Laane, Quant. Rev., 25, 533 (1971).
C. S. Blackwell and R. C. Lord, Vibrational Spectra and Structure, Vel. 1, J. R. Durig, editor, Marcel Dekker, Inc., New York (1972) pp. 1–24.
C. J. Wurrey, J. R. Durig and L. A. Carreira, Vibrational Spectra and Structure, Vol. 5, J. R. Durig, editor, Elsevier Scientific Publishing Co., Amsterdam (1976) pp. 176–221.
J. E. Kilpatrick, K. S. Pitzer and R. Spitzer, J. Amer. Chem. Soc., 69, 2483 (1947).
L. A. Carreira, I. M. Mills, and W. B. Person, J. Chem. Phys., 56, 1444 (1972).
T. Ikeda, R. C. Lord, T. B. Malloy, Jr., and T. Ueda, J. Chem. Phys., 56, 1434 (1972).
G. G. Engerholm, A. C. Luntz, W. D. Gwinn, and D. O. Harris, J. Chem. Phys., 50, 2446 (1969).
J. A. Greenhouse and H. L. Strauss, J. Chem. Phys., 50, 124 (1969).
D. W. Wertz, J. Chem. Phys., 51, 2133 (1969).
L. A. Carreira, G. J. Jiang, W. B. Person, and J. N. Willis, Jr., J. Chem. Phys., 56, 1440 (1972).
J. R. Durig, W. J. Natter, and V. F. Kalasinsky, J. Chem. Phys., 67, 4756 (1977).
J. R. Durig, Y. S. Li, and L. A. Carreira, J. Chem. Phys., 58, 2393 (1973).
J. R. Durig and W. J. Natter, J. Chem. Phys., 69, 3714 (1978).
T. Ikeda and R. C. Lord, J. Chem. Phys., 56, 4450 (1972).
L. A. Carreira, R. C. Lord and T. M. Malloy, Jr., Topics in Current Chemistry, Vol. 82, Springer-Verlag, Berlin (1979) pp. 1–95.
T. C. Rounds and H. L. Strauss, in Vibrational Spectra and Structure, Vol. 7, J. R. Durig, editor, Elsevier Scientific Publishing Co., Amsterdam (1978) pp. 238–268.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1980 D. Reidel Publishing Company
About this paper
Cite this paper
Durig, J.R., Sullivan, J.F. (1980). Current Research in Far Infrared Interferometry. In: Durig, J.R. (eds) Analytical Applications of FT-IR to Molecular and Biological Systems. NATO Advanced Study Institutes Series, vol 57. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-9070-8_20
Download citation
DOI: https://doi.org/10.1007/978-94-009-9070-8_20
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-009-9072-2
Online ISBN: 978-94-009-9070-8
eBook Packages: Springer Book Archive