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Chemistry of Organic Conductors: A Review of Strategies

Part of the NATO Advance Study Institutes Series book series (ASIC, volume 56)

Abstract

The purpose of this lecture is to present a review of the strategies which have evolved over approximately the past six years in the design of organic materials which will be metallic over a long temperature range. Known organic conductors exhibit a plethora of solid state transitions as a function of temperature. These transitions are usually accompanied by dramatic (or subtle) changes in structural, electric and magnetic properties. It is these variations as a function of temperature which have captivated a large segment of the population of solid state physicists (but a considerably smaller fraction of chemists) and kept their attention over a period of approximately five years (1973–1978). Even with the small number of chemists involved, a symbiosis between physicists and chemists has almost always led to the discovery of novel materials and/or properties. Design must therefore have input from both groups. With that in mind, this lecture would not have been possible without input from and collaboration with A. N. Bloch, F. J. DiSalvo, W. E. Geiger, R. C. Haddon, M. L. Kaplan, D. Nalewajek, D. Moncton, S. G. Soos, G. A. Thomas, W. M. Walsh and E. T. Zellers.

Keywords

Interchain Interaction Organic Conductor Solid State Property Solid State Polymerization Solid State Transition 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    L. I. Buranov, O. N. Eremenko, R. B. Lyubovskii, L. P. Rozenberg, M. L. Khidekel, R. P. Shibaeva, I. F. Shchegolev, and E. B. Yagubskii, J E T P Lett, 20, 208 (1974).Google Scholar
  2. 2.
    F. Wudl, D. E. Schäfer, B. Miller, J. Amer. Chem. Soc., 98, 252 (1976).CrossRefGoogle Scholar
  3. 3.
    W. E. Geiger, Jr., J. Phys. Chem. 77, 1862 (1973).CrossRefGoogle Scholar
  4. 4.
    M. Mizuno, M. P. Cava, A. F. Garito, J. Org. Chem., 41, 1484 (1976).CrossRefGoogle Scholar
  5. 5.
    W. E. Parham, H. Wynberg, W. R. Hasek, P. A. Howell, R. M. Curtis, W. L. Lipscomb, J. Amer. Chem. Soc., 76, 4957 (1954).CrossRefGoogle Scholar
  6. 6.
    L. K. Hausen, A. Hordvik, J. Chem. Soc. Chem. Commun., 800 (1974).Google Scholar
  7. 7.
    F. Wudl, R. C. Haddon, E. T. Zellers, and F. B. Bramwell, J. Org. Chem., 44, 2491 (1979).CrossRefGoogle Scholar
  8. 8.
    J. Meinwald, D. Dauplaise, F. Wudl, J. J. Hauser, J. Amer. Chem. Soc., 99, 255 (1977).CrossRefGoogle Scholar
  9. 9.
    A. W. Addison, N. S. Dalal, Y. Hoyano, S. Huizinga, and L. Weiler, Can. J. Chem., 55., 4191 (1977)CrossRefGoogle Scholar
  10. 10.
    F. Wudl, M. L. Kaplan, B. K. Teo, and J. H. Marshall, J. Org. Chem., 42, 1665 (1977).Google Scholar
  11. 11.
    L. Weiler, Abstracts, ACS/CSJ CHEMICAL CONGRES, PHYSICAL CHEMISTRY, April 2–6 (1979), D. O. Cowan, private communication.Google Scholar
  12. 12.
    F. Wudl, A. A. Kruger, M. L. Kaplan, R. S. Hutton, J, Org. Chem., 42, 768 (1977).CrossRefGoogle Scholar
  13. M. P. Cava and M. V. Lakshmikantham, PROC. N. Y. ACAD. SCI. USA, 313, 355 (1978).CrossRefGoogle Scholar
  14. D. C. Green, Ibid., 313, 361 (1978) and references therein.Google Scholar
  15. 13.
    E. M. Engler, R. A. Craven, Y. Tomkiewicz, B. A. Scott, K. Bechgaard, and J. R. Andersen, J. Chem Soc. Chem. Commun., 337 (1976).Google Scholar
  16. 14.
    V. Y. Lee, R. R. Schumaker, Abstracts, ACS/CSJ CHEMICAL CONGRESS, HONOLULU, HAWAII, April 1979, ORGN 424.Google Scholar
  17. 15.
    M. L. Kaplan, R. C. Haddon, and F. Wudl, J. Chem. Soc. Chem. Commun. 388 (1977).Google Scholar
  18. 16.
    E. M. Engler, R. R. Schumaker, and F. B. Kaufman, in MOLECULAR METALS, W. E. Hatfield, Ed., NATO Conference Series VI, Plenum Press, N. Y. 1979, pp. 31–34.Google Scholar
  19. 17.
    B. K. Teo, F. Wudl, J. J. Hauser, and A. A. Kruger, J. Amer. Chem. Soc., 99, 4862 (1977).CrossRefGoogle Scholar
  20. 18.
    R. C. Haddon, F. Wudl, M. L. Kaplan, J. H. Marshall, R. E. Cais, and F. B. Bramwell, J. Amer. Chem. Soc., 100, 7629 (1978).CrossRefGoogle Scholar
  21. 19.
    J. Kuyper and G. B. Street, J. Amer. Chem. Soc., 99, 7848 (1977).CrossRefGoogle Scholar
  22. 20.
    G. Wolmerhäuser, G. R. Brulet, and G. B. Street, Inorg. Chem., 17, 3586 (1978).CrossRefGoogle Scholar
  23. 21.
    F. Wudl, A. A. Kruger, and G. A. Thomas, PROC. N. Y. ACAD. SCI. USA, 313, 79 (1978).CrossRefGoogle Scholar
  24. 22.
    F. Wudl, Abstracts, ACS/CSJ CHEMICAL CONGRESS, HONOLULU, HAWAII, April 1979.Google Scholar
  25. 23._Not fully characterized (CS)n and (CSy)n were reported: R. Steudel, Angew Chem. Int. Ed. Engl., 6, 635 (1967).Google Scholar
  26. B. Krebs, G. Gattow, Z. Anorg, Allg. Chem., 338, 225 (1965).CrossRefGoogle Scholar
  27. 24.
    N. Jacobsen, P. De Mayo, A. C. Weedon, Nouv. J. Chim., 2, 331 (1978).Google Scholar
  28. 25.
    N. F. Haley, J. Chem. Soc. Chem. Commun., 207 (1977).Google Scholar
  29. 26.
    D. J. Sandman, A. P. Fisher, III, T. J. Holmes, and A. J. Epstein, Chem. Commun., 687 (1977).Google Scholar
  30. 27.
    T. Fukunaga, N. D. Gordon, P. J. Krusic, J. Amer. Chem. Soc., 98, 611 (1976).CrossRefGoogle Scholar
  31. 28.
    R. H. Baughman, SYMPOSIUM ON THE STRUCTURE AND PROPERTIES OF HIGHLY CONDUCTING POLYMERS AND GRAPHITE, SAN JOSE, CALIF. March 29–30, 1979.Google Scholar
  32. 29.
    D. Bloor, C. L. Hubble, and D. J. Ando, in MOLECULAR METALS, W. F. Hatfield, Ed., NATO Conference Series VI, Plenum Press, N. Y. 1979 pp. 243–247.Google Scholar
  33. 30.
    D. J. Berets, D. J. Smith, Trans. Faraday Soc., 64, 823 (1968).CrossRefGoogle Scholar

Copyright information

© D. Reidel Publishing Company, Dordrecht, Holland 1980

Authors and Affiliations

  • F. Wudl
    • 1
  1. 1.Bell LaboratoriesMurray HillUSA

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