Abstract
Chemical relaxations have been shown to be responsible for the excess sound absorption observed in ocean propagation measurements. Although a great number of processes occur in sea water, only two account for most of the absorption in the frequency range of interest. These involve MgSO4 (relaxation frequency fr~100 kHz) and B(OH)3 (fr~1 kHz). Investigations by the resonator method have revealed a third relaxation involving MgCO3 (fr~10 kHz) which accounts for a small absorption anomaly observed in the mid-frequency region. The B(OH)3 and the MgC03 components both increase exponentially with pH in the sea water range (7.7–8.3). A semi-empirical model for pH and temperature dependence of the absorption spectrum appear to be consistent with both the ocean data and resonator measurements in artificial sea water.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Urick, R.J., “Principles of Underwater Sound for Engineers” (McGraw-Hill, 1967) Chapter 5 and 6; pp. 82–159.
Wilson, O.B. and Leonard, R.W., “Measurements of Sound Absorption in Aqueous Salt Solutions by the Resonator Method”, J. Acoust. Soc. Am. 26, pp. 228–229 (1954).
Eigen, M. and Tamm, K. “Sound Absorption in Electrolytic Solutions due to Chemical Relaxation”, Scripps Institute of Oceanography Document 68–41 (1968).
Schulkin, M. and Marsh, H.W., “Sound Absorption in Sea Water”, J. Acoust. Soc. Am. 35, pp. 864–865 (1962).
Thorp, W.H., “Deep Sound Attenuation in the Sub and Low Kilocycle-per-second Range”, J. Acoust. Soc. Am. 38, pp. 648– 654 (1965).
Yeager, E., Fisher, F.H., Miceli, J. and Bressel, R., “Origin of Low Frequency Sound Absorption in Sea Water”, J. Acoust. Soc. Am. 53, pp. 1705–1707 (1973).
Fisher, F.H. and Simmons, V.P., “Sound Absorption in Sea Water”, J. Acoust. Soc. Am. 62, pp. 558–564 (1977).
Mellen, R.H. and Browning, D.G., “Variability of Low-Fre-quency Sound Absorption in the Ocean: pH Dependence”, J. Acoust. Soc. Am. 61 pp. 704–706 (1977).
Mellen, R.H., Simmons, V.P. and Browning, D.G., “Low-Fre-quency Sound Absorption in Sea Water: a Borate-complex Relaxation”, J. Acoust. Soc. Am. 67, pp. 341–342 (1980).
Mellen, R.H., Simmons, V.P. and Browning, D.G., “Sound Absorption in Sea Water: a Third Chemical Relaxation”, J. Acoust. Soc. Am. 65, pp. 923–925 (1979).
Jones, E.N., Browning, D.G., Thorp, W.H. and Mellen, R.H., “Sound Attenuation in the Red Sea”, NUSC Technical Report 4101 (1971).
Morris, G.B., “Low Frequency Sound Attenuation in the Northeast Pacific Ocean”, J. Acoust. Soc. Am. 59S, 44 (1976).
Lovett, J.R., “Northeastern Pacific Sound Attenuation using Low Frequency CW Sources”, J. Acoust. Soc. Am. 58, pp. 620- 625 (1976).
Leroy, C.C., “Sound Propagation in the Mediterranean Sea”, in Underwater Acoustics, ed. V.M. Albers (Plenum, 1967 ) Vol. 2, pp. 203 – 241.
Browning, D.G. (unpublished data). 78
Mellen, R.H. and Browning, D.G., “Attenuation in Surface Ducts”, J. Acoust. Soc. Am. 63, pp. 1624–1626 (1978).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1981 D. Reidel Publishing Company
About this paper
Cite this paper
Mellen, R.H. (1981). Chemical Sound Absorption in the Sea. In: Bjørnø, L. (eds) Underwater Acoustics and Signal Processing. NATO Advanced Study Institutes Series, vol 66. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-8447-9_4
Download citation
DOI: https://doi.org/10.1007/978-94-009-8447-9_4
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-009-8449-3
Online ISBN: 978-94-009-8447-9
eBook Packages: Springer Book Archive