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Possible Role of Phosphine in Chemical Evolution

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Origin of Life

Abstract

Experiments simulating the formation of organic molecules in model reducing atmospheres including phosphine show that a variety of organic molecules can be synthesized. From the experiments using UV light as an energy source, it appears that the presence of phosphine drastically increases the yield of photolysis of methane and, thus, the yield of the formation of organic matter. The presence of phosphine enhances the formation of organophosphorous compounds, such as methyl and dimethylphosphine.

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References

  1. Ridgway S.T., Bull. Amer. Astron. Soc. 6 376 (1974); Ridgway S.T., Wallace L. and Smith G.R., Astrophys. J., 207 1002 (1976).

    Google Scholar 

  2. Larson H.P., Treffers R.R. and Fink A., Astrophys. J., 211 972 (1977).

    Article  Google Scholar 

  3. Tokunaga A.T., Knacke R.F., Ridgway S.T. and Wallace L., Astrophys. J. 232 603 (1979).

    Article  Google Scholar 

  4. Hanel R., Conrath B., Flasar M., Kunde V., Lowman P., Maguire W., Pearl J., Pirraglia J., Samuelson R., Gautier D., Gierasch P., Kumar S., and Ponnamperuma C., Science 204 974 (1979)

    Article  Google Scholar 

  5. Beer R. and Taylor F.W., Icarus 40 189 (1979)

    Article  Google Scholar 

  6. Rabinowitz J., Woeller F., Flores J, and Krebsbach R., Nature 224 796 (1969), Rabinowitz J., Helv. Chem. Acta 53 53 (1970)

    Article  Google Scholar 

  7. Vera Ruiz H.G. and Rowland F.S., Geophys. Res, Lett. 5 407 (1978)

    Article  Google Scholar 

  8. Lee J.H., Michael J.V., Payne W.A., Whytock D.A. and Stief L.J., J. Chem. Phys. 65 3280 (1976).

    Article  Google Scholar 

  9. Howland G.R., Harteck P. and Reeves Jr R.R., Icarus 37 301 (1979).

    Article  Google Scholar 

  10. Ferris J.P. and Benson R., Nature, in press (1980).

    Google Scholar 

  11. Raulin F., Abeyagunawardene S.I,, Le Mercier I. and Ponnamperuma C., American Chemical Society Meeting (Section: Organic Chemistry - Identification: 258 ), Washington D.C. (1979); Raulin F., Abeyagunawardene S.I,, Lee A., Le Mercier I., Ponnamperuma C. and Hanel R., to be published.

    Google Scholar 

  12. Yamada M. and Ponnamperuma C., L.C.E, report, University of Maryland (1978).

    Google Scholar 

  13. Okabe M., “Photochemistry of Small Molecules” John Wiley, N.Y, (1978)

    Google Scholar 

  14. See for instance. Hong K.Y., Hong J.H. and Becker R.S., Science, 984 (1974).

    Google Scholar 

  15. Toupance G., Bossard A. and Raulin F., Origins of Life 8 259 (1977); Bossard A., Thèse de 3ème cycle, spécialité chimie physique, Université Paris VI (1979),

    Article  Google Scholar 

  16. Rabenovets M., Raulin F. and Ponnamperuma C., L.C.E. Report, University of Maryland (1979).

    Google Scholar 

  17. Halmann M., in “The Origin of Life and Evolutionary Biochemistry”, Dose K., Fox S.W., Pavlovskaya T.E., and Deborin G. A., Eds, Plenum Press, N.Y,, 169 (1974).

    Google Scholar 

  18. Griffith E., Ponnamperuma C., and Gabel N., Origins of Life, 8 71 (1977),

    Article  Google Scholar 

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© 1981 D. Reidel Publishing Company

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Raulin, F., Ponnamperuma, C. (1981). Possible Role of Phosphine in Chemical Evolution. In: Wolman, Y. (eds) Origin of Life. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-8420-2_14

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  • DOI: https://doi.org/10.1007/978-94-009-8420-2_14

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-009-8422-6

  • Online ISBN: 978-94-009-8420-2

  • eBook Packages: Springer Book Archive

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