Summary
The historical development of SBR including trends in manufacturing methods is outlined. Variables in micro- and macro-structure are analysed and the properties of the polymer are compared with those of natural rubber. The processability of SBR is considered in some detail and attention is given to recent methods of assessing mixability and other processing characteristics.
Compared with natural rubber SBR compounds are lacking in green strength. Recent developments using labile crosslinking systems to reduce this deficiency are described. The general vulcanisation behaviour of SBR is reviewed and the network structures of the vulcanisates are compared with those of natural rubber. Whilst the chapter is primarily concerned with emulsion SBRs, which constitute the bulk of the market, the relative merits and demerits of the newer solution polymers are considered.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
URANECK, C. A. Polymer Chemistry of Synthetic Elastomers: Part 1 J. P. Kennedy and E. G. M. Tornqvist (Eds.), Interscience, New York, 1968, Chapter 4A.
GLANVILLE, L. M. and BOWMAN, I. J. Review paper—Progress of general purpose synthetic rubbers. Progress of Rubber Technology, Vol. 40, Plastics and Rubber Institute, London, 1977, p. 21.
SALTMAN, W. M. (Ed.) The Stereo Rubbers, Wiley, New York, 1977.
BRYDSON, J. A. Rubber Chemistry, Applied Science Publishers, London, 1978.
KRAUS, G., CHILDERS, C. W. and GRUVER, J. T. J. Appl. Polym. Sci., 11, 1967, 1581.
BEACH, K. C., COMPER, L. F. and LOWERY, V. E. Rubber Age, 85, 1959, 253.
MEDER, A. and MAY, W. Rubber 146 (June), 1964, 39.
HEAL, C. J. A. Paper to Deutsche Kantschuk Gesellschaft, West Berlin, October 1960.
ASTM STANDARD, D-3346–74, July 1975.
EINHORN, S. C., Rubber World, 148(5), 1965, 40.
TOKITA, N. and PLISKIN, I. Rubber Chem. Technol., 46, 1973, 1166.
VAN BUSKIRK, P. R., TURETZKY, S. B. and GUNBERG, P. F. Rubber Chem. Technol., 48, 1975, 577.
TURETZKY, S. B., VAN BUSKIRK, P. R. and GUNBERG, P. F. Rubber Chem. Technol., 49, 1976, 1.
MILLS, W., YEO, C. D., KAY, P. J. and SMITH, B. R. Rubber Industry, 9, 1975, 25.
SMITH, B. R. Rubber Chem. Technol., 49, 1976, 278.
MILLS, W. and GIURCO, F. Rubber Chem. Technol., 49, 1976, 291.
BRYDSON, J. A. Flow Properties of Polymer Melts, 2nd edn, Godwin, London, 1981.
PALIT, K. and BAR-EL, M. Eur. Rubber J., 162(4), May 1980, 15.
BUCKLER, E. J., BRIGGS, G. J., HENDERSON, J. F. and LASIS, E. Eur. Rubber J., 159(7/8), July/August 1977, 21.
BRIGGS, G. J., HOLMES, J. M. and WEI, Y. K., Elastomerics, 111(8), August 1979, 30.
BUCKLER, E. J., BRIGGS, G. J., DUNN, J. R., LASIS, E. and WEI, Y. K. Rubber Chem. Technol., 51, 1978, 872.
SHELL CHEMICAL Co. Cariflex Technical Bulletin.
RODGER, E. R. Developments in Rubber Technology—1, A. Whelan and K. S. Lee (Eds.), Applied Science Publishers, London, 1979, Chapter 3.
CROUCH, W. and SHORT, J. N. Int. Rubber Study Group Symposium, Sao Paolo, 1967, p. 43
WILLIS, J. M. and BARBIN, W. W. Rubber Age, 100 (July), 1968, 53.
RAILSBACK, H. E. and HAWS, J. R. Rubber Plast. Age, 48, 1967, 1063.
COOPER, R. N. and NASH, L. L. Rubber Age, 104 (May), 1972, 55.
URANECK, C. A. and SHORT, J. N. J. Appl. Polym. Sci., 14, 1970, 1421.
DUCK, E. W., BOWMAN, I. J. W. and WILSON, C. A. Preprints of Int. Rubber Conf., Brighton, 1977, II 33–1.
HAWS, J. R., NASH, L. L. and WILT, M. S. Rubber Industry, 9, 1975, 107.
LIVIGNI, R. A., HARGIS, I. G. and AGGARWAL, S. L. Int. Rubber Conf., Kiev, 1978.
DAVIS, A. J. Rubber World, 181(6), March 1980, 29.
DACKER, K. De., DUNNOM, D. D. and MCCALL, C. A. Rubber Age, 96, 1969, 53.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1981 Applied Science Publishers Ltd
About this chapter
Cite this chapter
Brydson, J.A. (1981). Styrene—Butadiene Rubber. In: Whelan, A., Lee, K.S. (eds) Developments in Rubber Technology—2. The Developments Series, vol 37. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-8108-9_2
Download citation
DOI: https://doi.org/10.1007/978-94-009-8108-9_2
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-009-8110-2
Online ISBN: 978-94-009-8108-9
eBook Packages: Springer Book Archive