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Small Angle Neutron Scattering from Styrene-Isoprene Block Copolymers

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Static and Dynamic Properties of the Polymeric Solid State

Part of the book series: NATO Advanced Study Institutes Series ((ASIC,volume 94))

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Abstract

A variety of styrene-isoprene block copolymers, covering a wide range in composition, have been investigated using small angle neutron scattering (SANS). Investigations of hydrogenous copolymers enabled the domain separation and packing to be obtained, it was found that spherical domains form a face centred cubic structure and cylindrical domains a hexagonally close packed arrangement. The relation between interdomain spacing and copolymer molecular weight is,

$${{d}_{{spheres}}}{\text{ }}\alpha {\text{ }}{{M}^{{O.48}}}{{d}_{{cylinders}}}{\text{ }}\alpha {\text{ }}{{M}^{{O.7}}}{{d}_{{lamellar}}}{\text{ }}\alpha {\text{ }}{{M}^{{O.52}}}{\text{ }}$$

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References

  1. Helfand, E. and Vasserman, Z.R. in “Developments in Block Copolymers” editor L. Goodman. To be published by Applied Science Publishers.

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  2. Ruland, W., J.App.Cryst. (1971), 4, 70.

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  3. Meier, D.J., Polym.Prepr. (1974), 15, 171.

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Author information

Authors and Affiliations

  1. Department of Pure & Applied Chemistry, University of Strathclyde, Glasgow, G1 1XL, UK

    R. W. Richards & J. L. Thomason

Authors
  1. R. W. Richards
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  2. J. L. Thomason
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Editor information

Editors and Affiliations

  1. University of Strathclyde, Glasgow, UK

    R. A. Pethrick  & R. W. Richards  & 

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© 1982 D. Reidel Publishing Company, Dordrecht, Holland

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Richards, R.W., Thomason, J.L. (1982). Small Angle Neutron Scattering from Styrene-Isoprene Block Copolymers. In: Pethrick, R.A., Richards, R.W. (eds) Static and Dynamic Properties of the Polymeric Solid State. NATO Advanced Study Institutes Series, vol 94. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-7915-4_19

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  • DOI: https://doi.org/10.1007/978-94-009-7915-4_19

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-009-7917-8

  • Online ISBN: 978-94-009-7915-4

  • eBook Packages: Springer Book Archive

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