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Part of the book series: NATO Advanced Study Institutes Series ((ASIC,volume 87))

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Abstract

Dissolution morphologies, in particular the apparition of curved surfaces, are discussed, both for the dissolution of spheres and of cavities. The theory of LACMANN, HEIMANN and FRANKE, based on hypotheses of the dissolution mechanisms on a molecular level is discussed, together with its experimental confirmations.

Crystal imperfections have a greater influence on dissolution than on growth kinetics. The preferential negative nucleation at edge dislocations is probably at the origin of etch pits.

Even for crystals with high solubilities, the dissolution kinetics are probably not perfectly bulk diffusion limited. The influence of impurities is described with emphasis on the importance of adsorption kinetics.

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© 1982 D. Reidel Publishing Company

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Simon, B. (1982). Dissolution Phenomena. In: Mutaftschiev, B. (eds) Interfacial Aspects of Phase Transformations. NATO Advanced Study Institutes Series, vol 87. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-7870-6_25

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  • DOI: https://doi.org/10.1007/978-94-009-7870-6_25

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-009-7872-0

  • Online ISBN: 978-94-009-7870-6

  • eBook Packages: Springer Book Archive

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